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3. (10 points) The Antoine equation given below is frequently used to represent the temperature dependence...
3. [10 points) The Antoine equation given below is frequently used to represent the temperature dependence of vapor pressure for real liquid. InP_A_ InP - A-TEC B Note that A, B, and C are all constants. Show that the molar entropy of vaporization for such a liquid is given by 15.own = AV ) Feld te where AV = Vvap - Vigo
(References] Use the References to access important values if needed for this question. The temperature dependence of the vapor pressure is given by the equation: p=de Where: p = vapor pressure T = temperature A = pre-exponential constant A vap = enthalpy of vaporization Use the rules for logarithms and exponents to write this equation in logarithmic form. NOTE: Write A Hyn as dH (with no spaces) for the answers below. Use (caret) to enter superscripts. Inp- Submit Answer Ratry...
full explanation please thank you 2) The temperature dependence of the vapor pressure of solid and liquid mercury can be represented by: in Park = 23.912_8781K in Poud –16.85370$IK tor where T is the Kelvin temperature. Use the Clapeyron equation to calculate the enthalpies of sublimation and vaporization of mercury. In addition, use the data given to calculate Mercury's triple point.
3. (a) The schematic temperature dependence of the chemical potential of CO2 is given below. Show how the melting pint (TT) will change when increase the pressure and justify your answer. Draw the new u-T line in the following scheme. (b) If this diagram is for water, repeat the same questions in (a). Solid Liquid Chemical potential, Gas Solid stable Liquid stable Gas stable Temperature, T
15. According to the Clausius-Clapeyron equation ln va R T T P"арф) refers to the vapor pressure at temperature 1, R-2 cal/mol-K, and Ah is the heat of changc associated with the process of transitioning to the vapor (cither sublimation or vaporization depending on whether the transition is from solid to vapor or liquid to vapor) i.e., дН-H vapor-H , where X is either solid or liquid and H denotes the corresponding molar enthalpy. Use the Clausius-Clapeyron equation to solve...
unction of temperature, ponential functions Figure I shows measured vapor pressures of several volatile liquids as a function and can be considered as a small part of the overall phase diagram. Figure 1 The nonlinear plots are exponential which can be linearized to create Fimine 900- plotting the natural logarithm of vapor por In P. vs. 1/T after converting temperature, 7607 - 3457-----78.5/100.0/- Kelvin. garithm of vapor pressure, Figure 2 700-Diethyl ether Water Diethyl ether Vapor pressure (tor) Ethanol In...
Review Constants Pe Consider the following two substances and their vapor pressures at 298 K All liquids evaporate to a certain extent. The pressure exerted by the gas phase in equilibrium with the liquid is called vapor pressure. Prap. The vapor pressure of a particular substance is determined by the strength of the intermolecular forces. But for any given substance, the vapor pressure only changes with temperature. The Clausius-Clapeyron equation expresses the relationship between vapor pressure and temperature: Substance Vapor...
Use of Clausius-Clapeyron Equation 3- The vapor pressure of liquid ethanol at various temperatures is given below. Estimate the heat of vaporization of this compound at 170. oW. Pbuh (kPa) 0.6667 1.333 2.667 5.333 8.00 13.33 T (°C)12.0-2.3 8.0 19.0 26.0 34.9 Equations P (RT/V-b))-(a/(T V(V+b))) (0.42748 R2 Tc25 ) / Pc b (0.08664 R Te ) / Pe a Use of Clausius-Clapeyron Equation 3- The vapor pressure of liquid ethanol at various temperatures is given below. Estimate the heat...
Graph should be ln(p) vs 1/T Please show graph and full work for problem Will rate! Please and thank you! o.18 crm , at 95 %c.1. 3) Data for the vapor pressure of an unknown liquid are given T(C) 84 622, 1.433 694.,542 740 775 398 →5.4 40.4 01 43.4 27.0 30.1 32.8 36.5 484. .182 45.2 550,3 1O 469 The above data can be analyzed by the Clausius-Clapeyron equation According to that equation d (I/T)R where p is the...
02) Consider a hydrostatic system represented by the thermodynamic variables volume V, pressure P and temperature T. a) Consider entropy S = S(T, V) and derive the equation TdS. Tas = Cvat +T (1) dV. V Show that this equation can be written as follows BT TdS = CydT + PDV where Cv is the thermal capacity at constant volume, B is the isobaric expansiveness and K is isothermal compressibility: b) Consider a gas described by the equation of state...