3. [10 points) The Antoine equation given below is frequently used to represent the temperature dependence of vapor...
3. (10 points) The Antoine equation given below is frequently used to represent the temperature dependence of vapor pressure for real liquid. In P = A-TEC Note that A, B, and C are all constants. Show that the molar entropy of vaporization for such a liquid is given by AĞcap = AV 7 DC2el1-khe) where AV = Vap - Vigo
(References] Use the References to access important values if needed for this question. The temperature dependence of the vapor pressure is given by the equation: p=de Where: p = vapor pressure T = temperature A = pre-exponential constant A vap = enthalpy of vaporization Use the rules for logarithms and exponents to write this equation in logarithmic form. NOTE: Write A Hyn as dH (with no spaces) for the answers below. Use (caret) to enter superscripts. Inp- Submit Answer Ratry...
full explanation please thank you 2) The temperature dependence of the vapor pressure of solid and liquid mercury can be represented by: in Park = 23.912_8781K in Poud –16.85370$IK tor where T is the Kelvin temperature. Use the Clapeyron equation to calculate the enthalpies of sublimation and vaporization of mercury. In addition, use the data given to calculate Mercury's triple point.
Find the vapor vapor compostion of the liquid mixture described below at a temperature of 190 C . Given: • InPsat = A - B/(T+C) (where T is in C) Compound 1 = Acetone; mole fraction = 0.05 • Antoine constants : A = 14.3145 ; B = 2756.22 ; C - 228.06 Compound 2 = nOctane; Imole fraction = 0.95 • Antoine constants: A - 13.9346; B - 3123.13 ; C - 209.635 . What is the saturation pressure,...
Use of Clausius-Clapeyron Equation 3- The vapor pressure of liquid ethanol at various temperatures is given below. Estimate the heat of vaporization of this compound at 170. oW. Pbuh (kPa) 0.6667 1.333 2.667 5.333 8.00 13.33 T (°C)12.0-2.3 8.0 19.0 26.0 34.9 Equations P (RT/V-b))-(a/(T V(V+b))) (0.42748 R2 Tc25 ) / Pc b (0.08664 R Te ) / Pe a Use of Clausius-Clapeyron Equation 3- The vapor pressure of liquid ethanol at various temperatures is given below. Estimate the heat...
15. According to the Clausius-Clapeyron equation ln va R T T P"арф) refers to the vapor pressure at temperature 1, R-2 cal/mol-K, and Ah is the heat of changc associated with the process of transitioning to the vapor (cither sublimation or vaporization depending on whether the transition is from solid to vapor or liquid to vapor) i.e., дН-H vapor-H , where X is either solid or liquid and H denotes the corresponding molar enthalpy. Use the Clausius-Clapeyron equation to solve...
Review Constants Pe Consider the following two substances and their vapor pressures at 298 K All liquids evaporate to a certain extent. The pressure exerted by the gas phase in equilibrium with the liquid is called vapor pressure. Prap. The vapor pressure of a particular substance is determined by the strength of the intermolecular forces. But for any given substance, the vapor pressure only changes with temperature. The Clausius-Clapeyron equation expresses the relationship between vapor pressure and temperature: Substance Vapor...
3. (a) The schematic temperature dependence of the chemical potential of CO2 is given below. Show how the melting pint (TT) will change when increase the pressure and justify your answer. Draw the new u-T line in the following scheme. (b) If this diagram is for water, repeat the same questions in (a). Solid Liquid Chemical potential, Gas Solid stable Liquid stable Gas stable Temperature, T
Happy Elroy-maticTM announcement: You must base your solutions for these problems equation vapor pressure correlations in the form of Antoine's on Pat Ba =Ai-T+Ci Hg 1 mm with the following parameter values: compound i A B (K) 15.9008 2788.51 -52.36 16.0137 3096.52-53.67 16.0195 3279.47-59.95 Ci (K) benzene toluene ethylbenzene 11-propylbeuzene | 16.0062 3433.84 -66.01 -butylbenzene 16.0793 3633.40-71.77 Note tlhat T is in K and Pt is in mm Hg. More data are need (just as, in real life, more data...
unction of temperature, ponential functions Figure I shows measured vapor pressures of several volatile liquids as a function and can be considered as a small part of the overall phase diagram. Figure 1 The nonlinear plots are exponential which can be linearized to create Fimine 900- plotting the natural logarithm of vapor por In P. vs. 1/T after converting temperature, 7607 - 3457-----78.5/100.0/- Kelvin. garithm of vapor pressure, Figure 2 700-Diethyl ether Water Diethyl ether Vapor pressure (tor) Ethanol In...