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18. Consider the equilibrium When 2.000 MNOCI is placed in an empty tank at 500,0 K and allowed to come to equilibrium, the e
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Answer #1

18. Equation of reaction : Cl2 + 2 NO \rightarrow 2 NOCl

Initial conc. of NOCl = 2.00 M

Equilibrium conc. of Cl2 = 0.979 M

From the equation, [NO] = 2 * [Cl2] = 2 * 0.979 = 1.958 M

Concentration of NOCl reacted = moles of NO formed = 1.958 M

Equilibrium [NOCl] = inititial - reacted = 2.0 - 1.958 = 0.042

Writing the equation for K: K = [NOCl]2 / ([Cl2] * [NO]2] = 0.0422 / (0.979 * 1.9582) = 4.70 * 10-4 M-1

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