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The addition of an acid to an oxirane ring is one of the more non traditional...
A. Explain why tosylates make good leaving groups. B. What is the orientation of the stereogenic...
A. Explain why tosylates make good leaving groups. B. What is the orientation of the stereogenic center after the reaction depicted in the figure? н 1. Cl-Ts, pyridine он (R) 2. SCH3, THF The addition of an acid to an oxirane ring is one of the more non traditional mechanisms in the chapter. Using the posted example, explain, in a stepwise manner, what happens in the mechanism. Be sure to comment on why we see a nucleophile add to the...
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile...
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsey's rule whereby the more substituted alkene is generally formed. In E2 elimination,...
We begin with the surmise that the nucleophilic substitution reactions can occur only by one of...
We begin with the surmise that the nucleophilic substitution reactions can occur only by one of two mechanisms: Sn1 solvolysis: three-step mechanism R-X slow, R® + to R® + ROH fast , ROM R' H. R-O + R'OH fast , ROR' + R- SN2: one-step mechanism R-X + Nuc slow, Nuc-R + x Begin by answering the three questions below. If you don't understand what's up, please ask! 1. Write out the rate law for the above Sn1 reaction and...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what type of reaction? Refer to the Figure A) Addition B) Substitution C) Elimination D) Rearrangement Question 2 For the reaction in question 1, two products are possible- a major product, and a minor product. For the minor product, what is the splitting pattern for the added hydrogen (highlighted in red) that would be observed in the molecules HINMR spectrum? Refer to the Figure HBr...
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl...
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl groups are isopropyl, isobutyl, sec-butyl, and tert-butyl. CH2CH3 CH3CH2CH2CCH2CH3 Submit Answer Retry Entire Group 9 more group attempts remaining The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Br NaOCCH, . CH3CH2CHCH 1. none h. HBr 1.H20 e. "CCH3 f. Br j. Nat 9. HOCCH3 k. "OCCH3 Which letter designates the electrophilic carbon at which substitution occurs? (If no...
need help with the boxed bullet point. writing the chemical reaction scheme for the experiment. Synthesis of an A...
need help with the boxed bullet point. writing the chemical
reaction scheme for the experiment.
Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part I Pre-lab Assignment for Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part 1 1. From The Organic Chem Lab Survival Manual ( edition) by Zubrick • Review pages 201-204: Standard Reflux. • Review pages 127-140: Extraction • Review pages 164-189: Distillation, Simple Distillation. The Distillation Example, and The Distillation Mistake. 2. Read this...
e. 18 Test Your Knowledge MULTIPLE CHOICE: Choose the one best answer. 1. Each element has...
e. 18 Test Your Knowledge MULTIPLE CHOICE: Choose the one best answer. 1. Each element has its own characteristic atom in which a. the atomic mass is constant. b. the atomic number is constant. c. the mass number is constant. d. Two of the above are correct. e. All of the above are correct. 2. Which of the following is not a trace element in the human body? a. iodine b. zinc c. iron d. calcium e. fluorine 3. A...
A. Explain why tosylates make good leaving groups. B. What is the orientation of the stereogenic center after the reaction depicted in the figure? н 1. Cl-Ts, pyridine он (R) 2. SCH3, THF The addition of an acid to an oxirane ring is one of the more non traditional mechanisms in the chapter. Using the posted example, explain, in a stepwise manner, what happens in the mechanism. Be sure to comment on why we see a nucleophile add to the...
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsey's rule whereby the more substituted alkene is generally formed. In E2 elimination,...
We begin with the surmise that the nucleophilic substitution reactions can occur only by one of two mechanisms: Sn1 solvolysis: three-step mechanism R-X slow, R® + to R® + ROH fast , ROM R' H. R-O + R'OH fast , ROR' + R- SN2: one-step mechanism R-X + Nuc slow, Nuc-R + x Begin by answering the three questions below. If you don't understand what's up, please ask! 1. Write out the rate law for the above Sn1 reaction and...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what type of reaction? Refer to the Figure A) Addition B) Substitution C) Elimination D) Rearrangement Question 2 For the reaction in question 1, two products are possible- a major product, and a minor product. For the minor product, what is the splitting pattern for the added hydrogen (highlighted in red) that would be observed in the molecules HINMR spectrum? Refer to the Figure HBr...
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl groups are isopropyl, isobutyl, sec-butyl, and tert-butyl. CH2CH3 CH3CH2CH2CCH2CH3 Submit Answer Retry Entire Group 9 more group attempts remaining The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Br NaOCCH, . CH3CH2CHCH 1. none h. HBr 1.H20 e. "CCH3 f. Br j. Nat 9. HOCCH3 k. "OCCH3 Which letter designates the electrophilic carbon at which substitution occurs? (If no...
need help with the boxed bullet point. writing the chemical
reaction scheme for the experiment.
Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part I Pre-lab Assignment for Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part 1 1. From The Organic Chem Lab Survival Manual ( edition) by Zubrick • Review pages 201-204: Standard Reflux. • Review pages 127-140: Extraction • Review pages 164-189: Distillation, Simple Distillation. The Distillation Example, and The Distillation Mistake. 2. Read this...
e. 18 Test Your Knowledge MULTIPLE CHOICE: Choose the one best answer. 1. Each element has its own characteristic atom in which a. the atomic mass is constant. b. the atomic number is constant. c. the mass number is constant. d. Two of the above are correct. e. All of the above are correct. 2. Which of the following is not a trace element in the human body? a. iodine b. zinc c. iron d. calcium e. fluorine 3. A...
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