Homework Answers
For an SN1 reaction, the reactivity of alkyl halides follow the order: 3° >2 °>1° and for the SN2 reaction the reactivity of alkyl halide follows the order as 1° >2 °>3°.
Among the four alkyl halides (D) is having a 3° alkyl halide and the reactivity of this alkyl halide will be good and its reactivity will be least for an SN2 reaction.
alkyl halide A and B will be having a good reactivity towards SN2 reaction and very poor towards SN1 reaction as both the molecules bear 1° alkyl halide.
alkyl halide C will be having a good reactivity towards both SN1 and SN2 reaction as both the molecule bear 2° alkyl halide where the reactivity of both SN1 and SN2 reaction will be having same reactivity.
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2. (4 pts) Answer the following questions concerning the compounds shown below. À la B Which...
6. (9 pts) In regards to an electrophilic aromatic substitution reaction, define the 3 compounds shown...
6. (9 pts) In regards to an electrophilic aromatic substitution reaction, define the 3 compounds shown below as either: a) Activating, ortho, para director b) Deactivating, ortho para director, c) Activating, meta director, d) Deactivating, meta director. CH -ОН -N-CH3 CH3 7. Answer a-c for compounds A-F below dos a. (5 pts) Which compound(s) have an aromatic carbocation intermediate if it underwent an Snl or E1 reaction? b. (5 pts) Which compound(s) would have an anti-aromatic carbocation intermediate if it...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
2. Complete the transformation shown below. (6 pts; no partial point) ОН -ОН (not direct deprotonation)...
2. Complete the transformation shown below. (6 pts; no partial point) ОН -ОН (not direct deprotonation) DOH reagent doesn't contain halogen atoms (only product) 3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 SN 1 ноу HBr 0°C, H20 E2E1 Mechanism SN2 SN1 H2SO4 E2 E1 Mechanism SN2 Sn1 HBr rt, H20 E2 E1
2. List the trend of relative reactivity of compounds in: SN2 & SN1. Indicate which favors...
2. List the trend of relative reactivity of compounds in: SN2 & SN1. Indicate which favors 1°, 2° or 3° carbon. 3. What makes a good leaving group, or poor leaving group in a substitution reaction? List examples. 4. What makes a good nucleophile or poor nucleophile group in a substitution reaction? List examples. Be able to identify the nucleophile in a reaction. 5. What makes a good solvent for an SN2 reaction? List examples. Assign R & S to...
Question 10 10 pts A) 1-chloro-4-methylpentane B) 2-chloro-2-methylpentane C) 3-chloropentane D) 2-chloro-3-methylpentane Arrange the compounds above...
Question 10 10 pts A) 1-chloro-4-methylpentane B) 2-chloro-2-methylpentane C) 3-chloropentane D) 2-chloro-3-methylpentane Arrange the compounds above in order of greatest reactivity to least reactivity for an SN 1 reaction. Select 4 | Select) • , (Select Select)
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 20 Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH"), and transition state(s) (TS) on the above diagrams. (c) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH'), and transition state(s) (TS) on the above diagrams. (C) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy diagram...
Consider the SN2 reaction shown below and answer the following questions. Consider the SN1 reaction shown...
Consider the SN2 reaction shown below and answer the
following questions.
Consider the SN1 reaction shown below and answer the following
questions.
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br NaSCH3 SCH3 NaBr + A. Write the rate law for the reaction B. Identify the nucleophile and the electrophile in the reaction C. State how each of the following factors would affect the rate of the reaction a. Increasing the concentration of 1-bromopropane. b....
2. Complete the transformation shown below. (6 pts; no partial point) OH OH D Он (not...
2. Complete the transformation shown below. (6 pts; no partial point) OH OH D Он (not direct deprotonation) Он reagent doesn't contain halogen atoms (only product) 3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 SN1 Но HBr 0°С, Нао Е2 Е1 Mechanism Он SN2 SN1 H2SO4 A Е1 Е2 Mechanism SN2 SN1 HBr rt,H20 E2 Е1 ОН
4 (6 pts) For each of the following compounds, indicate which statement (A-E) best describes the...
4 (6 pts) For each of the following compounds, indicate which statement (A-E) best describes the reactivity of the benzene ring in electrophilic aromatic substitution reactions (e.g., nitration). A. The ortbo and para positions are activated and the meta position is deactivated. C. The ortho and para positions are deactivated and the meta position is activated. A. All positions are activated -ortho and para are more activated than meta. D. All positions are deactivated -ortbo and para are more deactivated...
6. (9 pts) In regards to an electrophilic aromatic substitution reaction, define the 3 compounds shown below as either: a) Activating, ortho, para director b) Deactivating, ortho para director, c) Activating, meta director, d) Deactivating, meta director. CH -ОН -N-CH3 CH3 7. Answer a-c for compounds A-F below dos a. (5 pts) Which compound(s) have an aromatic carbocation intermediate if it underwent an Snl or E1 reaction? b. (5 pts) Which compound(s) would have an anti-aromatic carbocation intermediate if it...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
2. Complete the transformation shown below. (6 pts; no partial point) ОН -ОН (not direct deprotonation) DOH reagent doesn't contain halogen atoms (only product) 3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 SN 1 ноу HBr 0°C, H20 E2E1 Mechanism SN2 SN1 H2SO4 E2 E1 Mechanism SN2 Sn1 HBr rt, H20 E2 E1
2. List the trend of relative reactivity of compounds in: SN2 & SN1. Indicate which favors 1°, 2° or 3° carbon. 3. What makes a good leaving group, or poor leaving group in a substitution reaction? List examples. 4. What makes a good nucleophile or poor nucleophile group in a substitution reaction? List examples. Be able to identify the nucleophile in a reaction. 5. What makes a good solvent for an SN2 reaction? List examples. Assign R & S to...
Question 10 10 pts A) 1-chloro-4-methylpentane B) 2-chloro-2-methylpentane C) 3-chloropentane D) 2-chloro-3-methylpentane Arrange the compounds above in order of greatest reactivity to least reactivity for an SN 1 reaction. Select 4 | Select) • , (Select Select)
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 20 Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH"), and transition state(s) (TS) on the above diagrams. (c) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH'), and transition state(s) (TS) on the above diagrams. (C) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy diagram...
Consider the SN2 reaction shown below and answer the
following questions.
Consider the SN1 reaction shown below and answer the following
questions.
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br NaSCH3 SCH3 NaBr + A. Write the rate law for the reaction B. Identify the nucleophile and the electrophile in the reaction C. State how each of the following factors would affect the rate of the reaction a. Increasing the concentration of 1-bromopropane. b....
2. Complete the transformation shown below. (6 pts; no partial point) OH OH D Он (not direct deprotonation) Он reagent doesn't contain halogen atoms (only product) 3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 SN1 Но HBr 0°С, Нао Е2 Е1 Mechanism Он SN2 SN1 H2SO4 A Е1 Е2 Mechanism SN2 SN1 HBr rt,H20 E2 Е1 ОН
4 (6 pts) For each of the following compounds, indicate which statement (A-E) best describes the reactivity of the benzene ring in electrophilic aromatic substitution reactions (e.g., nitration). A. The ortbo and para positions are activated and the meta position is deactivated. C. The ortho and para positions are deactivated and the meta position is activated. A. All positions are activated -ortho and para are more activated than meta. D. All positions are deactivated -ortbo and para are more deactivated...
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