4th сутеплите. 3. Build the models and draw the cis and trans isomers of the following...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
draw the structures 2-Ethyl1,4-dimethylcycloheptane Cis-1,3-diethyl cyclobutane Trans-1-bromo-3-ethylcyclopentane Cis-1,2-diethyl cyclopropane Trans-1,2-diethyl cyclopropane 2-methylheptane 4-ethyl-2,2-dimethylhexane 4-ethyl-3,4-dimethyloctane 2,4,4-trimethylheptane 3,3-diethyl-2,5-dimethylnonane 4-isopropyl-3-methylheptane
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2. Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3. Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons? 4. Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...
Exercise 2: Geometric isomers. Build plastic models of cis- and trans-1,2-dibromoethene. Confirm that the two models are not superimposable. (2) For Draw a top view (atoms in plane) and side view (wedge) for each structure. Exercise 3: Cyclohexane. Build a plastic model of cyclohexane and rotate all C – C bonds into the staggered conformation. (3) Sketch the chair conformation you have constructed.
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip of both *Draw the two conformation of the cis and trans cyclohexane structures above *List the number of axial and equatorial substituents for both the cis and trans *Which isomer is more stable overall, cis or trans? Why? 2. Make a model cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane. Do a ring flip *Draw the two conformation of the cis and trans cyclohexane structures above *List the number...
7. Draw and label both cis and trans isomers of 1-ethyl-4-methylcyclohexane. (10 pt) a. For each isomer, draw the two possible chairs and indicate which of the two will be preferred and by how much (a lot or little). (5 pt) b. Which of the four is considered the most stable (label as "best") and which is least stable ("worst")? (3 pt) c. Clearly label 1,3-diaxial interactions, if present, in any of the conformations? (2 pt) Cis Trans
2. Draw the structures of the cis-trans isomers for each compound. Label them cis and trans. If no cis-trans isomers exist, write none. a. 2,3-dimethyl-2-pentene b. 1,1-dimethyl-2-ethylcyclopropane c. 1,2-dimethylcyclohexane d. 5-methyl-2-hexene e. 1,2,3-trimethylcyclopropane
Draw the most stable conformation for; a. trans-1-chloro-3-methylcyclohexane b. cis-1-ethyl-2-isopropylcyclohexane c. trans-1-bromo-4-ethylcyclohexane d. cis-2-bromo-1-methylcycclohexane Sppecifically, show the ring flipping and calculate the strain using the table given in the power point slides.
Observations. нь со скрипис 9. Build the cyclopentane ring and study the angle strain and torsional strain in the ring. Draw the structures to explain these factors. Cyclopentane actually assumes a slightly puckered "envelope" conformation that reduces the eclipsing and lowers the torsional strain. Convince yourself about this fact. Provide the relevant drawings. 10. Build the cyclohexane ring and study the angle strain and torsional strain. Build the chair and boat conformations and identify the axial and equatorial bonds. Also...
Name or draw the following molecules (use cis/trans naming system) 1. Name or draw the following molecules (use cis/trans naming system): CI CI CH3 CH2CH3 a. b. c. 4-ethyl-6-(1,2-dimethylpropyl)decane 2. Draw all of the resonance structures for the following compounds. CH2