8. Predict the major organic products of each of the following reaction conditions (20 points) 1)...
8. predict the major organic products of each of the following reaction conditions? 9. show how yiu could synthesize the targeted products from the starting opoxides. show all reagengs and reaction conditions in the boxes above reaction arrows. 8. Predict the major organic products of each of the following reaction conditions (20 points) 1) LAIH, diethylether 2) H0 HO + KOH CrO3. HọSO, HẠO acetone (co-solvent) 1) CH,MgBr, diethylether 2) H,0 9. Show how you could synthesize the targeted products...
Predict the major organic products of each of the following reaction conditions Н.О + КОН CrO3, H2SO4, H20 HO acetone (co-solvent) 1) CH3MgBr, diethylether 2) H2O
10). (18 pts) Predict the structures of the products from each of the following S2 reactions. If no reaction is expected, write "No Rxn" Hас. H,с-о° Br A). н,с- он сH H,с. KBr сH, В). acetone он NaN С). ethanol Br CH3 кCN D). H,с. Br DMSO сн, SH но E) CH3 ethanol "сH,
Give the organic products, with the CORRECT REGIOCHEMISTRY AND STEREOCHEMISTRY, when appropriate. !!! CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
Chem 6A Homework #8 (28 pts) Due: 12/2/19 in class Give the organic product(s) of the following reactions Name Write your answers on this sheet. 1) CH3CH Mg CH3CH2CH2CI 2) H,о 1)LIAIH 2) н,б осн, н 1) ether Acetone CH3CH2CH2LI + 2) н,о* Hас Он 1) NaBH 2) н,о' BrMgсHCH,CHз CH2CH3 2) Н,о он Он РСС он PBr он о о но TsCl KCN CH3CH2OH
2. (12 pts) Reactions Give the reagents or products to the following systems. If a reaction does not give a product, write "NR" for No Reaction. Provide the product with the highest yield. Assume 1 to 1 stoichiometry unless otherwise stated. Provide stereochemistry if applicable. NC heat но но H ETOH 1. SOCI2 2. Heat, Hас -о н Но H но ETOH 1. TsCl NC H но но Н 2. CH,ок, CH,он
П. (40 points, 5 points each) Predict the products of the following sequences. No reaction is a possible answer. 1. HBr Page 6 of 11 1. NaBD, Ethanol 2. DO "н 1. NaBH 3. 2. H,о 4. 1. CH,CH2MgBr 2. 3. Н.о° NaBH, ethanol Он SOCI2 7. HBr ОН 8. Он PBrs -oe, ethanol
Predict the major product in each of the following transformations. No mechanisms are required for this question. [3 Marks] 1. CH3CH2MgBr (excess) 2. HCl(aq) 1. PhMgBr (1 equiv.) 2. HCl(aq) ОН о но 1. CH3MgBr (2 equiv.) 2. HCl(aq) н Show how you could synthesize the products below using a Grignard reagent and appropriate electrophile by drawing the overall balanced equation. No mechanisms are required for this question. You do not need to show formation of the Grignard reagent. [2...
Predict the products Predict the Product. Provide the stable organic product(s) for each reaction below NaBH CHOH 1 2 HCI, H,0 NaBH, (1 вg.)., сн,он 1. 2. HC, н,о 1. NaBH(осH (1 eq.), сн,он CI 2. HCI, H,O 1. LIAIH (1 eq.), THF Br 2. HCI, H2O
6. Give the major organic product from each mixed aldol reaction. Then explain why the reaction conditions favor one product instead of generating a mixture of products. NaOH a. + Н,о "СС, NaOH b. Н.о a. LDA c. b. О H н 7. Give the curved arrow mechanism for this reaction. NaOH, H,O Н heat