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4) A piece of steel is to be hardened by nitrogen diffusion into its outer layer. The initial nitrogen content of the steel is 0.010 wt%, and the surface concentration (from an external nitrogen-rich gas) is to be maintained at 0.75 wt%. Goal: nitrogen content of 0.25 wt% at a position of 0.50 mm below the surface. Specify a minimum of three appropriate heat treatments (time and temperature combinations) for temperatures between 600°C and 850°C (use the minimum and maximum temperatures) Pre-exponential and activation energy for nitrogen diffusion into iron are 3*10 m/s and 76,150 J/mol, respectively.

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