Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts...
1. Predict the major products formed in each of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2-10 points): a. Write products of the reaction using Fischer projection. (2)-3-methyl-pent-2-ene - HCI 2 b. Write product/s of the reaction using Fischer projection. y Brze? c. Write product/s of the reaction using Fischer projection BH3 H2O2. NaOH 1 mole of Hz. Pd/C e. MeOH is in a large excess. Write products...
by showing resonance structure. 2. Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2 = 10 points): a. Write product/s of the reaction using Fischer projection. HCI (Z)-3-methyl-pent-2-ene 2 Name CM-241 F19 18/19 at 5pm in the mail box labeled CM-241 near room SC Homework #7 is due on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP Supplementary...
Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases 2. Predict the major product/s formed in cach of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2 10 points): Write product/s of the reaction using Fischer projection на (Z)3-methyl-pent-2-ene .Write product/s of the reaction using Fischer projection. Br2 Write product/s of the reaction...
2. Predict the major product formed in each of the following reactions, write if the reaction is regioselective and/ or stereospecific (particular stereoisomers are obtained) in relevant cases (5 x 2 = 10 points): Ô 1 mol of t, Parc 1 mole of H2, Pd/C e. MeQH is in a large excess. Write product/s of the reaction using Fischer projection. (E)-3,4-dimethylpent-2-ene Bra in meos 2
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. 2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
Write the product/s in each of the following reactions. If a racemic mixture is a product of the reaction, write structure of both enantiomers. Assign absolute configuration (R or S) of the starting compounds and final 1 compounds in a case they possess a stereogenic center. (2.5 x 10 25 points) pyridine = v a. - ONa ? Pyridines byрroduct b. S-Ci NH2 (RZ-pent-3-en-2-ol pyridine excess с. FC CF3 NaCCCH он pyridine d. Вгz. Но 1 mol NaOH cis-pent-2-ene е....
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box labeled CM-241 near room SC236 Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP 1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism): (ii) write the products of the reaction; (iii) name the reaction product/s....
Predict the product(s) and reagent(s) or if there is no reaction write NR. 041 for 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAlD4, THE 4. HCI, H20 1. SOCl2, NEt3, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O OTE hint: multiple steps 1. LIAIH4, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, BuOH
2. Provide the major products from the following reactions. Starting Material Reagent(s) Product? Br2 Place appropriate groups H, Br CH, on scaffold) HCI Place appropriate groups (H, Br, CH, on scaffold) CH Brz/H20 Place appropriate groups H, Br CHs on scaffold] 1) O3 2) Zn/HOÁC LICH H2, Pd/C CH₂ 1. BH3 2. H2O2, NaOH(aq) CH2 hot KMnO4 in H2O - CH₂ CH3CO3H Product from above H30+, H2O