Homework Answers
The products of the above given reactions with Fischer projections are given in the following picture,
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by showing resonance structure. 2. Predict the major product/s formed in each of the following reactions,...
Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts...
Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts either regioselectivity or stereo specificallyl or both in relevant cases a. Write product/s of the reaction using Fischer projection. HCI (Z)-3-methyl-pent-2-ene – b. Write product/s of the reaction using Fischer projection. Bra wa c. Write products of the reaction using Fischer projection. M Bha H2O2, NaOH 1 mole of H2, Pd/C e. MeOH is in a large excess. Write product/s of the reaction using...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box labeled CM-241 near room SC236 Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP 1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism): (ii) write the products of the reaction; (iii) name the reaction product/s....
CM-241 F19 Homework # 7 is due on 11/8/19 at 5pm in the mail box labeled...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5pm in the mail box labeled CM-241 new OS Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the 19ACAMP 4. Predist reagents that can be used to obtain the following transformations (5 x 2-10 points 8? OH Name CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pm in the mail box labeled CM-241 near room Supplementary session is on 10/31/19 between 5:30 pm...
1. Predict the major products formed in each of the following reactions, indicate if the reagent...
1. Predict the major products formed in each of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2-10 points): a. Write products of the reaction using Fischer projection. (2)-3-methyl-pent-2-ene - HCI 2 b. Write product/s of the reaction using Fischer projection. y Brze? c. Write product/s of the reaction using Fischer projection BH3 H2O2. NaOH 1 mole of Hz. Pd/C e. MeOH is in a large excess. Write products...
2. Predict the major product formed in each of the following reactions, write if the reaction...
2. Predict the major product formed in each of the following reactions, write if the reaction is regioselective and/ or stereospecific (particular stereoisomers are obtained) in relevant cases (5 x 2 = 10 points): Ô 1 mol of t, Parc 1 mole of H2, Pd/C e. MeQH is in a large excess. Write product/s of the reaction using Fischer projection. (E)-3,4-dimethylpent-2-ene Bra in meos 2
Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts either regioselec...
Predict the major product/s formed in each of the following
reactions, indicate if the reagent reacts either regioselectively
or stereospecifically, or both in relevant cases
2. Predict the major product/s formed in cach of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2 10 points): Write product/s of the reaction using Fischer projection на (Z)3-methyl-pent-2-ene .Write product/s of the reaction using Fischer projection. Br2 Write product/s of the reaction...
Write the product/s in each of the following reactions. If a racemic mixture is a product of the reaction, write struct...
Write the product/s in each of the following reactions. If a racemic mixture is a product of the reaction, write structure of both enantiomers. Assign absolute configuration (R or S) of the starting compounds and final 1 compounds in a case they possess a stereogenic center. (2.5 x 10 25 points) pyridine = v a. - ONa ? Pyridines byрroduct b. S-Ci NH2 (RZ-pent-3-en-2-ol pyridine excess с. FC CF3 NaCCCH он pyridine d. Вгz. Но 1 mol NaOH cis-pent-2-ene е....
2. (16 points) In each of the following pairs of reactions elimination competes with substitution. Write...
2. (16 points) In each of the following pairs of reactions elimination competes with substitution. Write the starting material and all possible products of the reactions, don't write mechanistic part Write "elimination is favored" for reaction in which elimination products can be obtained in higher yield comparing to the yield of the elimination product/s in the second reaction. Provide the reason for such statement, reason is in reaction conditions. Supplementary session is on 10/31/19 between 5:30 PM an write an...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl, Sy2, E, B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
Predict the major product/s formed in each of the following reactions, indicate if the reagent reacts either regioselectivity or stereo specificallyl or both in relevant cases a. Write product/s of the reaction using Fischer projection. HCI (Z)-3-methyl-pent-2-ene – b. Write product/s of the reaction using Fischer projection. Bra wa c. Write products of the reaction using Fischer projection. M Bha H2O2, NaOH 1 mole of H2, Pd/C e. MeOH is in a large excess. Write product/s of the reaction using...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box labeled CM-241 near room SC236 Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP 1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism): (ii) write the products of the reaction; (iii) name the reaction product/s....
CM-241 F19 Homework # 7 is due on 11/8/19 at 5pm in the mail box labeled CM-241 new OS Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the 19ACAMP 4. Predist reagents that can be used to obtain the following transformations (5 x 2-10 points 8? OH Name CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pm in the mail box labeled CM-241 near room Supplementary session is on 10/31/19 between 5:30 pm...
1. Predict the major products formed in each of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2-10 points): a. Write products of the reaction using Fischer projection. (2)-3-methyl-pent-2-ene - HCI 2 b. Write product/s of the reaction using Fischer projection. y Brze? c. Write product/s of the reaction using Fischer projection BH3 H2O2. NaOH 1 mole of Hz. Pd/C e. MeOH is in a large excess. Write products...
2. Predict the major product formed in each of the following reactions, write if the reaction is regioselective and/ or stereospecific (particular stereoisomers are obtained) in relevant cases (5 x 2 = 10 points): Ô 1 mol of t, Parc 1 mole of H2, Pd/C e. MeQH is in a large excess. Write product/s of the reaction using Fischer projection. (E)-3,4-dimethylpent-2-ene Bra in meos 2
Predict the major product/s formed in each of the following
reactions, indicate if the reagent reacts either regioselectively
or stereospecifically, or both in relevant cases
2. Predict the major product/s formed in cach of the following reactions, indicate if the reagent reacts either regioselectively or stereospecifically, or both in relevant cases (5 x 2 10 points): Write product/s of the reaction using Fischer projection на (Z)3-methyl-pent-2-ene .Write product/s of the reaction using Fischer projection. Br2 Write product/s of the reaction...
Write the product/s in each of the following reactions. If a racemic mixture is a product of the reaction, write structure of both enantiomers. Assign absolute configuration (R or S) of the starting compounds and final 1 compounds in a case they possess a stereogenic center. (2.5 x 10 25 points) pyridine = v a. - ONa ? Pyridines byрroduct b. S-Ci NH2 (RZ-pent-3-en-2-ol pyridine excess с. FC CF3 NaCCCH он pyridine d. Вгz. Но 1 mol NaOH cis-pent-2-ene е....
2. (16 points) In each of the following pairs of reactions elimination competes with substitution. Write the starting material and all possible products of the reactions, don't write mechanistic part Write "elimination is favored" for reaction in which elimination products can be obtained in higher yield comparing to the yield of the elimination product/s in the second reaction. Provide the reason for such statement, reason is in reaction conditions. Supplementary session is on 10/31/19 between 5:30 PM an write an...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl, Sy2, E, B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
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