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1. Describe the effects each case for an 2. Describe the effects each case has for...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary,...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary, Label the nucleophile as strong or weak. Decide whether an S2 or an Sol reaction occurs. Alter, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol + Na CH₂ CH OH b. Reaction of 2-bromopropane in ethanol Br + CH.CH, OH - c. Reaction of (R) 3-chloro-3-methylheptane in acetic acid CH3...
2. Consider the Sn1 reaction shown below and answer the following questions. + CH3OH "CH₃ +...
2. Consider the Sn1 reaction shown below and answer the following questions. + CH3OH "CH₃ + HBr A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solventi Panther ID...... C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d. Changing the alkyl halide from a bromide to...
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH...
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH + CH3OH — Kºchs + HBr CH3 + HBr Ph Ph A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d....
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br + NaSCHE...
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br + NaSCHE SCHg+ NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. c. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3 to CH3OH.
1. Consider the SN2 reaction shown below and answer the following questions. acetone + NaSCHE SCH3...
1. Consider the SN2 reaction shown below and answer the following questions. acetone + NaSCHE SCH3 + NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. C. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3 to CH3OH.
1. Consider the SN2 reaction shown below and answer the following questions. Br + acetone NaSCH—...
1. Consider the SN2 reaction shown below and answer the following questions. Br + acetone NaSCH— ^ SCH3 + NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. c. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3...
Consider the SN2 reaction shown below and answer the following questions. Consider the SN1 reaction shown...
Consider the SN2 reaction shown below and answer the
following questions.
Consider the SN1 reaction shown below and answer the following
questions.
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br NaSCH3 SCH3 NaBr + A. Write the rate law for the reaction B. Identify the nucleophile and the electrophile in the reaction C. State how each of the following factors would affect the rate of the reaction a. Increasing the concentration of 1-bromopropane. b....
consider the Sn1 reaction shown below and answer the following questions. Br Br + CH3OH CH3...
consider the Sn1 reaction shown below and answer the following questions. Br Br + CH3OH CH3 + HBO A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d. Changing the alkyl halide from a bromide to an...
2. We can measure how fast the Product is formed at increasing levels of Substrate Concentration...
2. We can measure how fast the Product is formed at increasing levels of Substrate Concentration The rate of the reaction can be plotted below. This is called a Michaelis-Menten Graph and it shows several important features of the enzyme: a. What happens to the reaction rate as the amount of substrate is increased? reaction rate- b. Why does the graph level off at high levels of substrate concentration? substrate concentration
1. To which mechanism(s) if any does each statement apply? Fill in each blank with SN1,...
1. To which mechanism(s) if any does each statement apply? Fill in each blank with SN1, SN2, E1, E2, or N/A (not applicable) a) Involves a carbocation intermediate: - and b) Involves retention of configuration at the site of substitution: c) Substitution at the chiral center gives predominantly a racemic product:__ d) The reaction rate can be altered by changing the concentration of the nucleophile/base: - and
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary, Label the nucleophile as strong or weak. Decide whether an S2 or an Sol reaction occurs. Alter, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol + Na CH₂ CH OH b. Reaction of 2-bromopropane in ethanol Br + CH.CH, OH - c. Reaction of (R) 3-chloro-3-methylheptane in acetic acid CH3...
2. Consider the Sn1 reaction shown below and answer the following questions. + CH3OH "CH₃ + HBr A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solventi Panther ID...... C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d. Changing the alkyl halide from a bromide to...
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH + CH3OH — Kºchs + HBr CH3 + HBr Ph Ph A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d....
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br + NaSCHE SCHg+ NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. c. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3 to CH3OH.
1. Consider the SN2 reaction shown below and answer the following questions. acetone + NaSCHE SCH3 + NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. C. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3 to CH3OH.
1. Consider the SN2 reaction shown below and answer the following questions. Br + acetone NaSCH— ^ SCH3 + NaBr A. Write the rate law for the reaction. B. Identify the nucleophile and the electrophile in the reaction. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of 1-bromopropane. b. Decreasing the concentration of NaSCH3 by one-half. c. Changing 1-bromopropane to 2-bromopropane. d. Changing 1-bromopropane to 1-iodopropane. e. Changing NaSCH3...
Consider the SN2 reaction shown below and answer the
following questions.
Consider the SN1 reaction shown below and answer the following
questions.
1. Consider the SN2 reaction shown below and answer the following questions. acetone Br NaSCH3 SCH3 NaBr + A. Write the rate law for the reaction B. Identify the nucleophile and the electrophile in the reaction C. State how each of the following factors would affect the rate of the reaction a. Increasing the concentration of 1-bromopropane. b....
consider the Sn1 reaction shown below and answer the following questions. Br Br + CH3OH CH3 + HBO A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d. Changing the alkyl halide from a bromide to an...
2. We can measure how fast the Product is formed at increasing levels of Substrate Concentration The rate of the reaction can be plotted below. This is called a Michaelis-Menten Graph and it shows several important features of the enzyme: a. What happens to the reaction rate as the amount of substrate is increased? reaction rate- b. Why does the graph level off at high levels of substrate concentration? substrate concentration
1. To which mechanism(s) if any does each statement apply? Fill in each blank with SN1, SN2, E1, E2, or N/A (not applicable) a) Involves a carbocation intermediate: - and b) Involves retention of configuration at the site of substitution: c) Substitution at the chiral center gives predominantly a racemic product:__ d) The reaction rate can be altered by changing the concentration of the nucleophile/base: - and
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