(9) A spontaneous process has the change of free energy (a) AG>0 (c) AG = 0...
(9) A spontaneous process has the change of free energy (a) AG > 0 (b) AG <0 (c) AG = 0 (d) AH >0 and AS <0 (10) A chemical reaction has AH = 10 kJ, AS = 50 J/K at temperature T = 300 K, the reaction AG = (a) 5000 (b)-5000 (c) 10000 (d) 50 (11) For reaction : Ag (s) + 1/2 Cl2 (g) = Agt (aq) + CI+ (aq), the standard free energy of formation: AGE"...
Gibbs free energy change AG is defined as AG= AH-TAS. For a spontaneous process, AG<0. For a. reversible reaction at equilibrium, AG = 0. The equilibrium constant K of the reversible reaction is relate- AG"=-RTIn(K). Symbol 40" refers to thermodynamics standard condition: 298 K and 1 atm. Exercise:consider the following reaction: bo:pfoiex 2 HNO:(aq)+NO(g)- 3 NO2(g) + H2O(I) AH=+136.5 kJ; AS = +287.5 J/K a. Below what temperature does the following reaction becomes nonspontaneous? niliod sis anotsole s ob io...
(CM13201_S20), Calculate the value of the free energy change, AG, for the reaction below at 127.0°C when the pressures of NOCI (g) = 5.00 atm, NO (g) = 0.0200 atm, and Cl (g) - 0.0100 atm. 2 NOCI (9) - 2 NO (g) + Cl2 (g) AG° = 41.00 kj AH° = 77.08 kJ AS° = 121.24 J/K AGE Check
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(l) → CO2(g) + 2NH3(g) Substance CO(NH2)2(aq) H2O(1) CO2(g) NH AH° (kJ/mol) -391.2 -285.9 -393.5 -46.19...
Consider the reaction: 12(g) + Cl2(g)—>21CI(g) Using standard thermodynamic data at 298K, calculate the free energy change when 1.950 moles of L2(g) react at standard conditions. AGºrxn = kJ Iodine AHºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 12(s) 0 0 116.1 12(9) 62.4 19.3 260.7 23.0 16.0 137 12(aq) I(g) 106.8 70.3 180.8 1 (9) -197.0 -55.0 -52.0 106.0 I'(aq) ICI(9) 17.8 -5.5 247.6 Chlorine Cl(9) AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) 121.7 105.7 165.2 0 0 223.1 -23.0...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(1) ► CO2(g) + 2NH3(g) Substance CO(NH3)2(aq) H00 AH(kJ/mol) 1-391.2 -285.9 -3935 -46.19 S'J/mol K) 173.8...
For the following reaction: C2H4(9) +302(g) + 2C02(g) + 2H2O(1) What is the change in free energy in kJ ? The relevant standard free energies of formation are: kJ AG . C.H. = 68.4- mol mol AG, 0, = 0 AGC, CO, = -393.3 kJ AGF, 4,0 = -285.8 kJ mol mol • Your answer should include three significant figures.
please solve all FREE ENERGY AND CALCULATING AG FOR REACTIONS (Math) 21. Any reaction will be spontaneous if AG > 0 d. AS < 0 b. AG0 AH, <0 AS > 0 a. e. c. From AGformations 22. What is the AG for the reaction given: CH_(8) +20,(8) CO2(g) + 2H2O(g) Substance CH.(g) CO.(g) H.O(g) AGform (kJ/mol) 50.8 394.4 -228.57 a. -50.8 kJ/mol b. -- 751 kJ/mol c. -113 kJ/mol d. -115 kJ/mol e. -807 kJ/mol 23. Determine AG for...
A process at constant T and P can be described as spontaneous if AG <0 and nonspontaneous if AG> 0. Over what range of temperatures is the following process spontaneous? Assume that gases are at a pressure of 1 atm. (Hint: Use the data below to calculate AH and AS [assumed independent of temperature and equal to AH° and AS°, respectively] and then use the definition of AG.) 2 MnO2(s) 02(g) 2 MnO(s) AH (kJ mol) -520.0 -385.2 s° (J...
Calculate the standard change in Gibbs free energy, AG , for the given reaction at 25.0 "C. Consult the table of thermodynamic properties for standard Gibbs free energy of formation values. NH, CI() = NH(aq) + Cl" (aq) AGxn = kJ/mol Determine the concentration of NH(aq) if the change in Gibbs free energy, AGx. for the reaction is -9.39 kJ/mol. INH1 = Thermodynamic Properties at 298 K So 0 1 ΔΗ kJ/mol 0 105.8 -31.1 -32.6 -100.4 -127.0 -61.8 -124.4...