HNO Cl AlCI H,so, Zn(Hg) HCl KMnO (hot, concd.) HBr (CH3)CO K+ NH3 (excess) NaOCH3 Write complete equations for each of the following conversions. Include appropriate reagents.
For the following reaction, what is the product? 1.) Oso 2.) H,02 OH OH OH enantiomer D A cubitawan GO 90 2 3 $ 4 5 6 7 00 9 0 w E R Т. Y C 1 O Р S D F G H J K L C V B N М.
Aspirin, CH(OCOCH,CO,H, is produced by the reaction of salicylic acid, CH(OH)CO,H, and acetic anhydride, (CH,CO),0. CH(OH)CO2H(s) + (CH,CO), 0(1) → CH(OCOCH)CO2H(s) + CH,CO, H(4) If you mix 150 g of each of the reactants, what is the maximum mass of aspirin that can be obtained? Masitos
Write the concentration equilibrium constant expression for this reaction. CH,CO,C2H3(aq)+H,0(1) - CH, CO H(aq)+C,H,OH(aq)
Hot KMnO, OH HO 1. CHECO,H 2. H,O H ,O* ? Cold KMnO, H2O/OH -CH3 MCPBA CH3CH2CH2CH2C= CCH2CH3 Na/CH2CH NH2 Hydrogenation
6. CH3 Br CCI 7. CH3 Br CH, OH 8. CHE 1. MCPBA 2. CH,OH, H* 9. CH Oso,,H,O, 10. Na, NH 0
Hot KMnO, OH H,01 ? 1. CHECO,H 2. H2O /H,O* Cold KMnO4 H2O/OH dah MCPBA , CH, MCPBA CH3CH2CH2CH2C= Na/CH3CH2NH2 CCH2CH3 Hydrogenation
complete the indicated reactions. (only the circled ones please!)
8-47 Predict the major products of the following reactions, and give the structures of any intermediates. Include stereochemistry where appropriate. (1) O (2) (CH), HBE ROOR HCI ROOR PhCO, H KMnO OH (cold, dil.) CHCOH KMnOOH HHO (1) 0, (2) (CH), (warm, cond) Study Problems 387 (1) Hg(OA), H,O (2) NaBH
(1) HCOAc),,H,O (2) N.BH, (1) BH, THE (2) H,02, OH (CH-CH),Cuti + CH,CH,CH-CHCH, Br
1. Predict the product(s) using the same alkens reactant for the following reactions PUC CH,CI, Bry CH,OH HI DBr HBr H,O,/hv H,OH,O 1. Hg. THF-H,0 2. NaBH,/NaOH 1. B.H/THE 2. H,O,/NaOH KMnO,H,O cold 1. OsO 2. NaHSO, 1. KMnO/OH/heat 2. H0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. HOOH