Draw the two chair conformations of cis-l-isopropyl-2 methy kyclohexane and indicate, by means of equilibrium arrows,...
Draw two chair conformations for cis-1-isopropyl-2-methylcyclohexan Determine which of them is more stable with an explanation Q10: If the radius of the Earth is equal to 6371.000 km, determine the difference between: ? The chord and the arc if the chord = 15 km (to the nearest mm) ? The difference in height if the chord = 15 km (to the nearest cm) 6:02 PM
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
2. (25 points) Draw the two chair conformations in equilibrium) for (1 R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation. 2. (25 points) Draw the two chair conformations (in equilibrium) for (1 R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation.
Draw the 2 chair conformations, in the chair format, of cis-1,3-dimethylcyclohexane. Label which one is the least stable and which is the most stable. If they are of equal stability, clearly state that they are of equal stability.
U. Complete the specified Newman projections for the two chair conformations of cis-1-isopropyl-3- methylcyclohexane. It may be helpful to add some missing axial and equatorial hydrogen atoms to the chair conformations before you start. (0.3 pts) H3C CH3 C(1) to C(6) view C(1) to C(2) view C(1) to C(6) view 11. Indicate whether the rate of each interconversion is finite (measureable) or near zero at 25°C. (0.3 pts)
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
7. (13 points) For the compound 1-tert-butyl-4-methylcyclohexane: a. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one b. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one trans: C. Between the two more stable isomers circled above, which is more stable? Why?
1(a). Draw both chair conformations of trans-1-chloro-2-methylcyclohexane. Compare stabilities. (b) .Draw both chair conformations of cis-1- chloro-2-methylcyclohexane.Compare stabilities. (c).Draw both chair conformations of cis-1,4-dimethylcyclohexane. Compare stabilities .
2. (25 points) Draw the two chair conformations (in equilibrium) for (1R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation.
10) a) Draw the most stable and least stable chair conformations of rms- l ethylcyclohexane. b) Caleulate the energy of both structures. 11) Draw the most stable chair conformation of cis-1-ethyl-3-methyleyclohexane.