U. Complete the specified Newman projections for the two chair conformations of cis-1-isopropyl-3- methylcyclohexane. It may...
Chem 241 Chapter 3 -Class Praetice 2 Draw the 2 chair conformations of the following, label the substituents as axial or equatorial Determine which conformation between the 2 is more stable. cis-1-ethyl-3-isopropylcyclohexane trans-1-isopropyl-2-methyleyclohexane trans-1-methyl-2-isopropylcyclohexane cis-1-ethyl-4-methylcyclohexane Among the following, which respresent the same compound? Which represent different compounds? CH3 H3C HyC CHs H. CH3
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
Which of the following two conformations of
cis-1-isopropyl-4-methylcyclohexane is
more stable? Use the strain energy increments in the table below
estimate the energy difference (a positive number) between
them.
Which of the following two conformations of cis-1-isopropyl-4-methylcyclohexane is more stable? Use the strain energy increments in the table below estimate the energy difference (a positive number) between them. 1,3-Diaxial Strain Energies for Monosubstituted Cyclohexanes SubstituentkJ/mol Substituent kJ/mol 0.4 0.5 -C CH, ethynyl 0.85 2.95 2.95 -CH-CH23.55 3.64 -CH2CH 3.65 -CN,...
Select the most stable chair conformation for
(1R,3S,5S)-1-chloro-3-isopropyl-5-methylcyclohexane.
Select the most stable chair conformation for (1R,3S,5S)-1-chloro-3-isopropyl-5-methylcyclohexane Select the most stable chair conformation. CH(CH3)2 (1R,3S,5S)-1-chloro-3-isopropyl-5-methylcyclohexane Chair choices: CI CH CH3 CH3 (H3C)2HC CH(CH3)2 (H3C)2HC CH3 CH3 CH3 Cl CH(CH3)2 (H3C2HC (H3C)2HC
5. Draw the two chair conformations for trans-1-ethyl-3-methylcyclohexane. Label substituents as to whether they are in an axial or equatorial position. Circle the most stable conformation.
Draw the two chair conformations of each compound and label the substituents as axial and equatorial. In each case, determine which conformation is more stable. a. trans-1-ethyl-2-isopropylcyclohexane b. trans-1-ethyl-3-methylcyclohexane C. Cis-1-ethyl-4-methylcyclohexane d. cis-1-ethyl-3-methylcyclohexane
1(a). Draw both chair conformations of trans-1-chloro-2-methylcyclohexane. Compare stabilities. (b) .Draw both chair conformations of cis-1- chloro-2-methylcyclohexane.Compare stabilities. (c).Draw both chair conformations of cis-1,4-dimethylcyclohexane. Compare stabilities .
Draw cis-1-isopropyl-3-methylcyclohexane in its most stable chair conformation.
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
5. Draw b . Clearly label the oth chair conformations of trans-1-ethyl-3-methylcyclohexane ubstituents as axial or equatorial. (You do not need to show all the hydro Which conformer is lower energy? 6. For the following reactions, (1) predict the products, (2) provide curved arrows, and (3) predict whether the reaction equilibrium favors products or reactants. Provided an explanation for ONa OH