pts) Give the missing reagents, reactants or products in the following reactions: (each box or blank...
give the missing reagents or products or reactants. also for letter C give me an arrow pushing mechanism with the name of the synthesis. please be serious with your answer кон но ΕΙΝΗ, H2SO4 SOCI CH,C12 Na NH.. Etон 1) Brz PBry Na Cro H2SO4 so 2) H.O and 2 x H202 ACOH NH HO NH H2SO4 HgSo. HO H2SO4 CH2CH2
6. Give reactants, reagents, and/or products for the following reactions, as appropriate. SOCI2 он 1) NaBH, (excess) OCH3 2) H307 OH, H20 (excess) 1. CH3CH2MgBr (excess) 2. H30*
5. Complete the following reactions by filling in the missing Reactants, Reagents, or MAJOR Product. If TWO products are equally formed show BOTH. 1. DIBAL 2. H307 Colon - ohne кон ОН OH NH2 LIAIH4 1. LDA / Dry THE - to 1.LA/D THE 1.1.2 Equiv. LDA/THF 2. Br Br2 acetic acid Pyridine Heat Nat Et EtOH single product
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2) 1. BH3 2. H2O2, NaOH, H2O PCC HBr/ROOR how many stereoisomers? PCC ad Excess H, H CH2Cl2 OT_HBr SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction ОН PCC CH2Cl2 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH PCC CH2Cl2 HI (SN1)
2. (12 pts) Reactions Give the reagents or products to the following systems. If a reaction does not give a product, write "NR" for No Reaction. Provide the product with the highest yield. Assume 1 to 1 stoichiometry unless otherwise stated. Provide stereochemistry if applicable. NC heat но но H ETOH 1. SOCI2 2. Heat, Hас -о н Но H но ETOH 1. TsCl NC H но но Н 2. CH,ок, CH,он
give reactants, reagents, and/or products for the following reactions, as appropriate. reactants, reagents, and/or products for the following reactions, as appropriate SOCI dom OH 1) NaBH, (excess) SOCIE OCH 2) H,O* OH, H2O (excess) 1. CH3CH2MgBr (excess) 2. H30 NaBH4 (excess) Br 1) Mg, ether 2) H30*
13. (15) For each a For each of the following reactions, fill in the missing reagents from the list provided for Wormation of the product shown. Sequential steps, if necessary. should be numbered. Reagents can be used more than once. Reagent List: H2 C H2O2 = NaH PBT OCI NaBH. Pd/C NaOH BH2O HO HgCl2 Pd/Caco, Br2 HBr H2O (HOAC) (MCPBA) (pyridine) (Msch) por -Cl menos de plaqueta don -он i н он
The following four reactions show reactants, reagents, and products. In each reaction one of the categories is missing. Supply the missing compound or reagents in each of the reactions. Be sure to indicate stereochemistry where warranted.
2.(20) The following five reactions show reactants, reagents and products. In each reaction one of the categories is missing (represented by a letter). Supply the missing reactant, reagents or product where appropriate in each reaction. In your structures, be sure to indicate stereochemistry where warranted. A= a) b) H2, 5%Pt/C CH212. Zn(Cu) in ether c) C : CH Br2 in H20 d) D : phase transf. cat OH 1) Hg(OAc)2, H20 2) NaBH4 e)