Short Answer: (A) Draw all 3 steps of mechanism that gives the product 2-butene. You do...
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Short Answer: (A) Draw all 3 steps of mechanism that gives the product 2-butene. You do not have to draw mechanisms for both products - just 2-butene (either cis or trans). Finally, clearly label each product below as the Hoffman or Zaitsev product. See Key Mechanism 7-5. ОН H2SO4 heat trans-2-butene 1-butene (C) Show ALL steps of the mechanism for the complete chlorination of 2 Cl2
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do you write the mechanism for trans 2 butene in the energy diagram
6. (20 points) Write the mechanism of the reaction of trans-2-butene with hydrogen bromide. Label the transition state and intermediate and the product. Draw an energy diagram for this reaction assuming the reaction is exergonic. Br Corbed Antrnediae transitn pealur
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Show the complete mechanism for the reaction of trans-2-butene with Br using curved arrows to represent every bond broken and every bond formed Pay careful attention to the stereochemistry, using dashes and wedges to draw the reactant, intermediate, and product. Name the product or products. Be sure to include the stereochemical configuration of the product(s) if necessary. Part 4. Synthesis (5 points each). Show a reasonable synthetic pathway for the following transformations, 1. Acetylene - 1,2-butanediol 2. cis-2-butene-trans-2-butene
3. Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН conc H2SO4 heat OH conc H2SO4 heat
Provide a mechanism that leads to the E2 elimination product(s). Pay close attention to the stereochemistry and provide a name for the elimination product(s). 6. H .CH3 CH3ONA Br CH,он CH3 н Provide a detail explanation of how Zaitsev product and Hoffman product is formed. Give examples of both using a substrate and proper reaction conditions.. 7. Follow the instructions in Problem 7-13 on page 306 of your textbook. Additionally, provide mechanisms that lead to the products. 8. For each...
1.Predict all the products for the following reaction. Which is the major product? Why? + conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? din 3.Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН ОН conc H2SO4 conc H2SO4 heat heat
Application Questions 1. Predict all the products for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? o in s 3. Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН conc H2SO4 heat...
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The reaction below gives two S_N1 products. Draw them. Do not consider enantiomers. For each pair of molecules below circle the one that will undergo an S_N1 reaction the fastest. In class we discussed two possible mechanisms for the reaction below (see also section 8.6a of the text). Draw side-by-side reaction energy diagrams for each mechanism that clearly show the relative energies after each step. Give a curved arrow mechanism for the E1 reaction below. TFA (trifluoroacetic acid,...
Discussion Questions: 1. a) Carefully draw a three-dimensional structure of each stereoisomer of stilbene dibromide. Do not include any identical structures. b) Identify the enantiomeric pair, and identify one pair of structures that are diastereomers. 2. Give careful stereo-drawings representing the complete mechanism for the reaction of cis-stilbene with bromine. Remember to show the two different modes of anti-attack that are possible, depending on whether you add the bromine from above to the left-hand or the right-hand carbon of the...
Be sure to answer all parts. Draw a stepwise mechanism for the following reaction: LOH H,SO Part 1 out of 4 A. SO2 B. H2SO4 c. H20 finish structure ... D. HSO4 3 attempts left Check my work Next part What is the major organic product obtained from the following sequence of reactions? OH PBrg CN Multiple Choice (+)-2-Methylpentanenitrile O trans-2-Butene O (R)-2-Methylpentanenitrile O (9)-2-Methylpentanenitrile O