1. What are the products of the following elimination Ereactions showing a mechanism by which the...
1. What are the products of the following elimination reactions showing a mechanism by which the products are formed. (20 pts) po NaOCH, CH HOCH2CH3 b) 8
3. In the deuterium labeled compound below nredict the products of the elimination of the following elimination reaction and tell whether the alkene formed contains deutenum or not. (20 pts) HC CH3 OH H2SO4(aq) IH heat нстр (ii) NaOCH.CH CH,CH,OH heat CH3 (iii) Write a detail mechanism for the formation of the product in question 3(1).
Complete the curved arrow mechanism of the following double
elimination reaction when 2,3-dibromopentane is treated with two
equivalents of sodium amide and heated in mineral oil.
can someone answer this question for me please. thank you.
complete drawing for sapling. i will rate you!! thank you!!
a) Use three curved arrows to show the b) Use three curved arrows to show the elimination of the first hydrogen bromide. elimination of the second hydrogen bromide NH3 :Br: Bi H3 CH3 H3...
3. In the deuterium -labeled compound below predict the product (s) of the elimination reactions of the following elimination reaction and tell whether the alkene formed contains deuterium (D) or not. (20 pts) Н.с, сн, OH H2SO&(aq) (i) heat НС NAOCH2CH3 (ii) CH3CH2OH н CH3 heat (iii) Write a detail mechanism for the formation of the product in question 3(i)
(4) Which of the following shows a mechanism of a concerted elimination? OMe A. OMe C. D. OMe (5) The major product of the following elimination reaction is Ot e the MAJOR products for the reactions and MAJOR stereochemistry products I (8), or fill the blank for (5). (36 pts) CH3 HBr
Choose the sequence of reagents which would best accomplish the following transformation: 2-bromopropane ----------> 1,2-dibromopropane [(R) + (S)] 01. (i) KMnO4, NaOH in water at 0 °C 2. (i) Br2 in CCl4 (ii) excess NaNH2 (iii) CH31 (iv) H20, H2SO4, HgSO4 Choose the sequence of reagents which would best accomplish the following transformation: 2-bromopropane ---------> 1,2-dibromopropane [(R) + (S)] 01. (i) KMnO4, NaOH in water at 0 °C 2. (i) Br2 in CC14 (ii) excess NaNH2 (iii) CH3 (iv) H20,...
Complete the curved arrow mechanism of the following double elimination reaction when 1,2-dibromopropane is treated with two equivalents of sodium amide and heated in mineral oil. a) Use three curved arrows to show the elimination of the first hydrogen bromide. b) Use three curved arrows to show the elimination of the second hydrogen bromide. ENHE •NH HC Hac Bra , -NH3, Br c) Complete the structure of the organic product formed from the double elimination. N-H H3C- C- & Use...
Which product(s) would you expect to obtain from each of the following reactions? In each part give the mechanism (Sw1, SN2, E1 or E2) by which each product is formed. Explain your reasoning. (20 pts) 6. a. NaSH OTs DMSO b. CI NaOCH3 C. OMs NaOCH2CH3 d. ON HCECNa e. KOC(CH3).3 CI Br NaOCH2CH3 CH3CH2OHH
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1. Draw the structure of the principal organic product and predict the stereochemistry to be expected from the reaction of (IR, 2R)-1-bromo-2-methylcyclohexane with each of the following: a. NaOCH, in CH,OH at 60° d. NaNH, in NH, at 50° b. aqueous CH,OH at 140° e. aqueous CH,CH,OH at 25° c. Nal in DMSO at 40° 2. Draw the major product(s) (showing appropriate stereochemistry when necessary) for the following reactions. Indicate the mechanism(s) in operation (SNI, SN2, E1,...
Which of the following products is the major product formed from the bimolecular elimination (E2) reaction shown? ook , "E2" Which of the following products is the major product formed from the bimolecular elimination (E2) reaction shown? "E2" Which of the following products is the major product formed from the unimolecular elimination (E1) reaction shown? H2O "E1" Br