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1. In phosphorolysis, a bond is attacked and cleaved by inorganic phosphate rather than water (as...
the enzyme hexokinase can catalyze the following reaction: fructose + ATP -> fructose 6 phosphate +...
the enzyme hexokinase can catalyze the following
reaction:
fructose + ATP -> fructose 6 phosphate + adp
if the deltaG of hydrolysis of fructose 6 phosphate to
fructose + Pi is -13.8 kj/mol and hydrolysis of atp to adp + pi is
-30kj/mol, calculate Keq for the reaction above (R = 8.31 j mol-1
K-1, T = 298 k
3a. The enzyme hexokinase can catalyze the following reaction: Fructose + ATP → Fructose-6-phosphate + ADP If the ΔGo of hydrolysis...
1) SHOW WORK 12. During glycolysis, glucose 1-phosphate is converted to fructose 6-phosphate in two successive...
1) SHOW WORK
12. During glycolysis, glucose 1-phosphate is converted to fructose 6-phosphate in two successive reactions: glucose 1-phosphate → glucose 6-phosphate glucose 6-phosphate + fructose 6-phosphate AG'' = -7.1 kJ/mol AG'º = +1.7 kJ/mol 13. The standard free-energy changes for the reactions below are given. phosphocreatine → creatine + Pi ATP → ADP + Pi AG" = 43.0 kJ/mol AG" = -30.5 kJ/mol What is the overall AG' for the following reaction? Iw a dee Hydrolysis of 1 M...
8) (30 points) The AG° of hydrolysis for glucose 1--phosphate is -20.9 kJ/mol. The AG° of...
8) (30 points) The AG° of hydrolysis for glucose 1--phosphate is -20.9 kJ/mol. The AG° of hydrolysis for glycerol 3-phosphate is –9.2 kJ/mol. a) Label the following reactions as spontaneous or nonspontaneous: glycerol 3-phosphate + H2O glycerol + P; glucose + P, S glucose 1-phosphate + H20 b) Calculate the AG° and Kea for the following reactions (i and ii). Are they spontaneous or nonspontaneous? i) glycerol 3-phosphate + glucose s glycerol + glucose 1-phosphate AG°: Keg Spontaneous: Yes/No ii)...
1. 2. 3. 4. Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate...
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2.
3.
4.
Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate ~2-phosphoglycerate 1) fructose-6-phosphate→ fructose-1,6-bisphosphate . glucose glucose-6-phosphate Select all that apply. Alcohol fermentation: consumes ATP as it produces ethanol. O produces carbon dioxide begins as pyruvate is decarboxylated to acetaldehyde in a reaction catalyzed by alcohol dehydrogenase m regenerates NAD requires the enzyme alcohol dehydrogenase, In the figure below, what is the reaction occurring at the location...
CHEM 351 Biochemistry I - Fall 2018 Study Problems for Metabolism and Glucose Catabolism For the...
CHEM 351 Biochemistry I - Fall 2018 Study Problems for Metabolism and Glucose Catabolism For the reaction: aA + bB =cC + dD Gibbs free energy: AG = AG" + RT IN THE glucose + glucose 6-phosphate + H20 1. The equilibrium constant for phosphorylation of glucose is: Ke = 3.97 x 10- a. Calculate the standard Gibbs free energy for the uncatalyzed reaction. b. Use the physiological concentrations for glucose (2.0 mm) and inorganic phosphate (20 mM) to determine...
Question 1 - Linked Reactions (10 marks) The reaction catalysed by pyruvate kinase is: Phosphoenolpyruvate+ ADPpyruvateATP Keg 3.63 x 105 a) Calculate the AG" for this reaction. Show your work...
Question 1 - Linked Reactions (10 marks) The reaction catalysed by pyruvate kinase is: Phosphoenolpyruvate+ ADPpyruvateATP Keg 3.63 x 105 a) Calculate the AG" for this reaction. Show your working. 3 marks b) The hydrolysis of ATP has following equation: AG 30.5 kJ/mol Calculate the AG" for the following reaction: Phosphoenolpyruvate pyruvateP Show your working. 2 marks c) At 37 °C, the steady-state concentrations of phosphoenolpyruvate, ATP, and ADP have been measured to be 23 HM, 1.85 mM and 140...
Find the Laplace Transformation (10 points) u(t) (10 points) eu(t) (10 points) 30 cos wt u(t)...
Find the Laplace Transformation (10 points) u(t) (10 points) eu(t) (10 points) 30 cos wt u(t) Use this ental infor- vorewo Pekes 1e of 500 K. Obtain a numerical value, includ- ing units, for each of the following partial derivatives for this gas. he values which the concentration of the andioen- antibody complex will be equal to the concen- tration of the unbound antibody. perimen- plies that consider- aG (b) (a) aT 19. The isomerization of glucose-6-phosphate G6P) to fructose-6-phosphate...
1. According to the paper, what does lactate dehydrogenase (LDH) do and what does it allow...
1. According to the paper, what does lactate dehydrogenase
(LDH) do and what does it allow to happen within the myofiber? (5
points)
2. According to the paper, what is the major disadvantage of
relying on glycolysis during high-intensity exercise? (5
points)
3. Using Figure 1 in the paper, briefly describe the different
sources of ATP production at 50% versus 90% AND explain whether you
believe this depiction of ATP production applies to a Type IIX
myofiber in a human....
the enzyme hexokinase can catalyze the following
reaction:
fructose + ATP -> fructose 6 phosphate + adp
if the deltaG of hydrolysis of fructose 6 phosphate to
fructose + Pi is -13.8 kj/mol and hydrolysis of atp to adp + pi is
-30kj/mol, calculate Keq for the reaction above (R = 8.31 j mol-1
K-1, T = 298 k
3a. The enzyme hexokinase can catalyze the following reaction: Fructose + ATP → Fructose-6-phosphate + ADP If the ΔGo of hydrolysis...
1) SHOW WORK
12. During glycolysis, glucose 1-phosphate is converted to fructose 6-phosphate in two successive reactions: glucose 1-phosphate → glucose 6-phosphate glucose 6-phosphate + fructose 6-phosphate AG'' = -7.1 kJ/mol AG'º = +1.7 kJ/mol 13. The standard free-energy changes for the reactions below are given. phosphocreatine → creatine + Pi ATP → ADP + Pi AG" = 43.0 kJ/mol AG" = -30.5 kJ/mol What is the overall AG' for the following reaction? Iw a dee Hydrolysis of 1 M...
8) (30 points) The AG° of hydrolysis for glucose 1--phosphate is -20.9 kJ/mol. The AG° of hydrolysis for glycerol 3-phosphate is –9.2 kJ/mol. a) Label the following reactions as spontaneous or nonspontaneous: glycerol 3-phosphate + H2O glycerol + P; glucose + P, S glucose 1-phosphate + H20 b) Calculate the AG° and Kea for the following reactions (i and ii). Are they spontaneous or nonspontaneous? i) glycerol 3-phosphate + glucose s glycerol + glucose 1-phosphate AG°: Keg Spontaneous: Yes/No ii)...
1.
2.
3.
4.
Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate ~2-phosphoglycerate 1) fructose-6-phosphate→ fructose-1,6-bisphosphate . glucose glucose-6-phosphate Select all that apply. Alcohol fermentation: consumes ATP as it produces ethanol. O produces carbon dioxide begins as pyruvate is decarboxylated to acetaldehyde in a reaction catalyzed by alcohol dehydrogenase m regenerates NAD requires the enzyme alcohol dehydrogenase, In the figure below, what is the reaction occurring at the location...
CHEM 351 Biochemistry I - Fall 2018 Study Problems for Metabolism and Glucose Catabolism For the reaction: aA + bB =cC + dD Gibbs free energy: AG = AG" + RT IN THE glucose + glucose 6-phosphate + H20 1. The equilibrium constant for phosphorylation of glucose is: Ke = 3.97 x 10- a. Calculate the standard Gibbs free energy for the uncatalyzed reaction. b. Use the physiological concentrations for glucose (2.0 mm) and inorganic phosphate (20 mM) to determine...
Question 1 - Linked Reactions (10 marks) The reaction catalysed by pyruvate kinase is: Phosphoenolpyruvate+ ADPpyruvateATP Keg 3.63 x 105 a) Calculate the AG" for this reaction. Show your working. 3 marks b) The hydrolysis of ATP has following equation: AG 30.5 kJ/mol Calculate the AG" for the following reaction: Phosphoenolpyruvate pyruvateP Show your working. 2 marks c) At 37 °C, the steady-state concentrations of phosphoenolpyruvate, ATP, and ADP have been measured to be 23 HM, 1.85 mM and 140...
Find the Laplace Transformation (10 points) u(t) (10 points) eu(t) (10 points) 30 cos wt u(t) Use this ental infor- vorewo Pekes 1e of 500 K. Obtain a numerical value, includ- ing units, for each of the following partial derivatives for this gas. he values which the concentration of the andioen- antibody complex will be equal to the concen- tration of the unbound antibody. perimen- plies that consider- aG (b) (a) aT 19. The isomerization of glucose-6-phosphate G6P) to fructose-6-phosphate...
1. According to the paper, what does lactate dehydrogenase
(LDH) do and what does it allow to happen within the myofiber? (5
points)
2. According to the paper, what is the major disadvantage of
relying on glycolysis during high-intensity exercise? (5
points)
3. Using Figure 1 in the paper, briefly describe the different
sources of ATP production at 50% versus 90% AND explain whether you
believe this depiction of ATP production applies to a Type IIX
myofiber in a human....
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