1) SHOW WORK 12. During glycolysis, glucose 1-phosphate is converted to fructose 6-phosphate in two successive...
2. Hydrolysis of 0.5 M studentose catalyzed by teacherase to become successose is 95% complete at equilibrium (i.e., only 5% of the studentose remains). What is AG"? (R = 8.315 J/mol K; T = 298 K) 3. The standard free-energy changes for the reactions below are given. Phosphocreatine creatine + Pi AG"=-43.0 kJ/mol ATP → ADP + Pi AG" = -30.5 kJ/mol The overall AG" for the reaction: Phosphocreatine + ADP creatine + ATP, is _ A) -73.5 kJ/mol C)...
2. The first step in glycolysis is catalyzed by the enzyme herokinase: glucose + ATP glucose-6-P + ADP This reaction can be thought of as two coupled reactions (P is phosphate): (1) glucose + P + glucose-6-P (2) ATP + ADP + P For the overall reaction, AG" = -16.7 kJ/mol. For the hydrolysis of ATP (equation 2), AG = -310 kJ/mol. All reactions are performed at 37°C. (a) What is AGº for reaction 1? Iglucose - 6-11 if AG...
Consider the given interconversion, which occurs in glycolysis. fructose 6-phosphate glucose 6-phosphate K1.97 What is AG for the reaction (K measured at 25 °C)? AG -1680.9 kJ/mol If the concentration of fructose 6-phosphate is adjusted to 1.4 M and that of glucose 6-phosphate is adjusted to 0.75 M, what is AG? AG =-4402.59 kJ/mol Which statements are consistent with the conditions at which AG is measured? The temperature is 273 K. The initial concentrations of reactant and product are 1...
the enzyme hexokinase can catalyze the following reaction: fructose + ATP -> fructose 6 phosphate + adp if the deltaG of hydrolysis of fructose 6 phosphate to fructose + Pi is -13.8 kj/mol and hydrolysis of atp to adp + pi is -30kj/mol, calculate Keq for the reaction above (R = 8.31 j mol-1 K-1, T = 298 k 3a. The enzyme hexokinase can catalyze the following reaction: Fructose + ATP → Fructose-6-phosphate + ADP If the ΔGo of hydrolysis...
The second step of glycolysis is the conversion of glucose-6-phosphate to fructose-6-phosphate. What is the ΔG for this reaction at 25oC, when the glucose-6-phosphate] is 60 mM and the [fructose-6-phosphate] is 40 mM. Note: the ΔGo’ for this reaction is +1.7 kJ/mol (at 25oC). 0.780 kJ/mol 1.26 kJ/mol 1.47 kJ/mol 2.70 kJ/mol 0.695 kJ/mol 2.62 kJ/mol Answer not listed
Shown is acetyl phosphate. Say a new enzyme uses acetyl phosphate to phosphorylate ADP to make ATP (acetyl phosphate + ADP —> acetate + ATP). What is the standard free energy change of this reaction? CH3 Table 13-2 Standard Free Energies of Phosphate Hydrolysis of Some Compounds of Biological Interest AGo (kJ mol 1) 61.9 -49.4 45.6 43.1 -43.1 30.5 -20.9 19.2 13.8 13.8 -9.2 Compound Phosphoenolpyruvate 1,3-Bisphosphoglycerate ATP AMP + PP,) Acetyl phosphate Phosphocreatine ATP ㈠ ADP + Pi)...
1. 2. 3. 4. Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate ~2-phosphoglycerate 1) fructose-6-phosphate→ fructose-1,6-bisphosphate . glucose glucose-6-phosphate Select all that apply. Alcohol fermentation: consumes ATP as it produces ethanol. O produces carbon dioxide begins as pyruvate is decarboxylated to acetaldehyde in a reaction catalyzed by alcohol dehydrogenase m regenerates NAD requires the enzyme alcohol dehydrogenase, In the figure below, what is the reaction occurring at the location...
Glycolysis is the process by which energy is harvested from glucose by living things. Several of the reactions of glycolysis are thermodynamically unfavorable (nonspontaneous), but proceed when they are coupled with other reactions. Reaction A: P + glucose glucose-6-phosphate +HO AG13.8 kJ/mol Reaction B: P fructose-6-phosphate + fructose-1,6-bisphosphate +1,0 AG 16.3 kJ/mol Reaction C: ATP+H, ADP +P, AG - 30.5 kJ/mol Select every unfavorable reaction. reaction B reaction C reaction A Select every set of coupled reactions where the overall...
During glycogen degradation glucose-1-phosphate is converted to glucose-6-phosphate and is an example of a coupled reaction. If the phosphoryl group transfer potential for glucose-1-phosphate is -20.9 kJ/mol and for glucose-6-phosphate is -13.8 kJ/mol, then what is the Keq (K) at 298 K? Is the conversion of glucose-1-phosphate to glucose-6-phosphate favorable or unfavorable under standard conditions? ΔG° = -RT ln K where R = 8.315 x 10-3 kJ/mol*K K = 0.057 and the reaction is unfavorable. K = 17.5 and the...
Why are these reactions for gluconeogenesis exergonic? I get that Glucose 6-phosphate -> glucose and fructose 1,6-biphosphate -> fructose 6 phosphate release Pi, but doesn't the formation of formation of oxaloacetate and phosphoenolpyruvate require energy ( ATP and GTP) ruvate. CH,OH CHOPO; HO он glucose 6- phosphatase HO OH OH 94 Он glucose 6-phosphate glucose glycolysao OPOH COCHZOPO HO O HO OH fructose 1,6- bisphosphatase ,POH COCH,OH HO он OH fructose 6-phosphate OH fructose 1,6-bisphosphate HCO; + ATP ADP +...