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The following data were obtained from a laboratory analysis of a...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
2 problems REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
please 5. Predict the eliminations products A and B formed (E-1 mechanism) when 4,4-dimethylhexan- 3-ol is...
please
5. Predict the eliminations products A and B formed (E-1 mechanism) when 4,4-dimethylhexan- 3-ol is heated with concentrated phosphoric acid. Also, identify the rate determining step and the major product using Zaitsey's Rule? (Mechanism must be shown to receive full points). (20 pts) он conc. H3PO4 - CH₂ Products A and B H₃C X E-l condition HzC CH3 4,4-dimethylhexan-3-ol
1. You are attempting to make hexan-2-ol from a hexene through a hydration reaction. Hex-1-ene, hex-2-ene,...
1. You are attempting to make hexan-2-ol from a hexene through a hydration reaction. Hex-1-ene, hex-2-ene, and hex-3-ene are available to you. Which of these reactants is the best starting material to made hexan-2-ol, and why? i. Bi !!! 2. Which of the following represents a propagation reaction in the free radical bromination of ethane? Select one: a. CH3CH3 + Br2 - BrCH2CH3 + HBr b. •CH2CH3 + Bra -- BrCH2CH3 + Bro C..CH2CH3 + Br. - BrCH2CH3 O d..CH3...
Problem #3 Calculate AH° for the following reaction using the bond energies found in Table 6.1...
Problem #3 Calculate AH° for the following reaction using the bond energies found in Table 6.1 on page 228. Is this reaction spontaneous? (CH3)3C-H + 12 (CH3)3C-1 + HI TABLE 6.1 BOND DISSOCIATION ENERGIES (AH) OF COMMON BONDS KJ/MOL KCAL/MOL H2C=CH-CH3 HC-C-CH KJ/MOL KCAL/MOL 385 92 489117 KJ/MOL KCAL/MOL 444 106 335 80 285 Bonds to H. H-H H-CH3 H-CH2CH3 H-CH(CH3)2 H-C(CH3)3 (CH3)2CH-F (CH3)2CH-CI (CH3)2CH-Br (CH3)2CH- (CH3)2CH-OH 68 222 435 104 435 104 41098 39795 91 473 113 53 381...
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе mos...
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
Can you answer the questions given in the photos above? The sec-butyl cation can react as...
Can you answer the questions given in the photos
above?
The sec-butyl cation can react as both a Lewis acid and a Brønsted- Lowry acid in the presence of a water-sulfuric acid mixture. In each case, however, the product is different. The two reactions are: 2. H2o +H3O+ a. In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? b. Write Lewis structures for reactants and products and show by...
The following synthesis is done in 3 steps. 1. The selective oxidation of alcohols. 2. Aromatic...
The following synthesis is done in 3 steps.
1. The selective oxidation of alcohols.
2. Aromatic Grignard
3. Carbon-Carbon coupling.
Perform stoichiometric calculations to obtain 1 ml of
the final product, using the concept of limit reagent in the
synthesis of geranial and phenylmagnesium bromide. assuming 100%
yield.
The complete equations of the synthesis of geranial and
grignard reagent are shown below. (They are needed to calculate the
final 1 ml of product of the reaction above)
Density of Final...
Substitution occurs more readily when a halide ion (eg cl from HCI) is present, resulting in...
Substitution occurs more readily when a halide ion (eg cl from HCI) is present, resulting in the -OH group of the alcohol being replaced by a halogen atom. A strong acid is necessary, since the H* converts the -OH group into - OH2*, which can then be lost as a water molecule: CH3 H2C=C elimination CHą -H,,! CH3 CH3 CH3 CH3 H3C-Ć-OH H3C-Ć-ÖH2 + H2O + H3C-c@ сна CH? CH3 2-methyl-2-propanol C H3C-C-Cl a 3° carbocation substitution CH3 2-chloro-2-methylpropane Carbocations...
please answer in multiple choice format What is the relationship between these two 23. What is...
please answer in multiple choice format
What is the relationship between these two 23. What is the relationship between these two molecules? molecules? BH BH que a. identical b. enantiomers c. diastereomers d. constitutional isomers 19. Which statement is FALSE about chiral molecules? a. Their chiral Carbons are sp hybridized. b. They have an internal plane of symmetry. c. They are optically active. d. Chiral centers are bonded to four different groups. a. enantiomers b. diastereomers c. identical d. unrelated...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
please
5. Predict the eliminations products A and B formed (E-1 mechanism) when 4,4-dimethylhexan- 3-ol is heated with concentrated phosphoric acid. Also, identify the rate determining step and the major product using Zaitsey's Rule? (Mechanism must be shown to receive full points). (20 pts) он conc. H3PO4 - CH₂ Products A and B H₃C X E-l condition HzC CH3 4,4-dimethylhexan-3-ol
1. You are attempting to make hexan-2-ol from a hexene through a hydration reaction. Hex-1-ene, hex-2-ene, and hex-3-ene are available to you. Which of these reactants is the best starting material to made hexan-2-ol, and why? i. Bi !!! 2. Which of the following represents a propagation reaction in the free radical bromination of ethane? Select one: a. CH3CH3 + Br2 - BrCH2CH3 + HBr b. •CH2CH3 + Bra -- BrCH2CH3 + Bro C..CH2CH3 + Br. - BrCH2CH3 O d..CH3...
Problem #3 Calculate AH° for the following reaction using the bond energies found in Table 6.1 on page 228. Is this reaction spontaneous? (CH3)3C-H + 12 (CH3)3C-1 + HI TABLE 6.1 BOND DISSOCIATION ENERGIES (AH) OF COMMON BONDS KJ/MOL KCAL/MOL H2C=CH-CH3 HC-C-CH KJ/MOL KCAL/MOL 385 92 489117 KJ/MOL KCAL/MOL 444 106 335 80 285 Bonds to H. H-H H-CH3 H-CH2CH3 H-CH(CH3)2 H-C(CH3)3 (CH3)2CH-F (CH3)2CH-CI (CH3)2CH-Br (CH3)2CH- (CH3)2CH-OH 68 222 435 104 435 104 41098 39795 91 473 113 53 381...
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
Can you answer the questions given in the photos
above?
The sec-butyl cation can react as both a Lewis acid and a Brønsted- Lowry acid in the presence of a water-sulfuric acid mixture. In each case, however, the product is different. The two reactions are: 2. H2o +H3O+ a. In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? b. Write Lewis structures for reactants and products and show by...
The following synthesis is done in 3 steps.
1. The selective oxidation of alcohols.
2. Aromatic Grignard
3. Carbon-Carbon coupling.
Perform stoichiometric calculations to obtain 1 ml of
the final product, using the concept of limit reagent in the
synthesis of geranial and phenylmagnesium bromide. assuming 100%
yield.
The complete equations of the synthesis of geranial and
grignard reagent are shown below. (They are needed to calculate the
final 1 ml of product of the reaction above)
Density of Final...
Substitution occurs more readily when a halide ion (eg cl from HCI) is present, resulting in the -OH group of the alcohol being replaced by a halogen atom. A strong acid is necessary, since the H* converts the -OH group into - OH2*, which can then be lost as a water molecule: CH3 H2C=C elimination CHą -H,,! CH3 CH3 CH3 CH3 H3C-Ć-OH H3C-Ć-ÖH2 + H2O + H3C-c@ сна CH? CH3 2-methyl-2-propanol C H3C-C-Cl a 3° carbocation substitution CH3 2-chloro-2-methylpropane Carbocations...
please answer in multiple choice format
What is the relationship between these two 23. What is the relationship between these two molecules? molecules? BH BH que a. identical b. enantiomers c. diastereomers d. constitutional isomers 19. Which statement is FALSE about chiral molecules? a. Their chiral Carbons are sp hybridized. b. They have an internal plane of symmetry. c. They are optically active. d. Chiral centers are bonded to four different groups. a. enantiomers b. diastereomers c. identical d. unrelated...
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