Homework Answers
1. The NaI/Acetone test gives a precipitate with 1-chlorobutane and 1-bromobutane, but not with 1-iodobutane because this test requires Iodine to form a precipitate in the form of I2
Iodobutane contains already an Iodine and since it is not as much reactive as the added NaI, there is no precipitation.
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Follow-up Questions 1. The Nal al/acetone test gives a precipitate with 1-chlorobutane and 1-bromobutane, but not...
In this exercise, you will use two reagent mixtures to test a variety of organic halides....
In this exercise, you will use two reagent mixtures to test a variety of organic halides. The distinct differences in the factors affecting the SN2 and SN1 mechanisms make it possible to determine which mechanism is favored by a given compound. One reagent and solvent favors SN2 reactivity, the other SN1 reactivity. From the results of your tests, you will determine which mechanism, if either, is favored by a given compound. In your post-lab assignment, you will be required to...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
can all parts of question A be answered and labeled please. there is no data for...
can all parts of question A be answered and labeled please.
there is no data for precipitation of Nal in acetone.
NUCLEOPHILIC SUBSTITUTION A. Structural Effects on Sa1 and Sa2 Reactivity A1. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form. If you heated any of...
can question A2 part a and b be answered and labeled please. information has been provided....
can question A2 part a and b be answered and labeled please.
information has been provided.
NUCLEOPHILIC SUBSTITUTION A. Structural Effects on S, 1 and S 2 Reactivity Al. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form. I you heated any of the test tubes,...
can question A parts A4 (a and b) A5 and A6 be answered neatly and labled....
can question A parts A4 (a and b) A5 and A6 be answered neatly
and labled. with specifics in A5 and A6
Dale Tepot sub Partners NUCLEOPHILIC SUBSTITUTION A. Structural Effects on Sn1 and Sn2 Reactivity A1. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form....
sn1: write the reactions for each of the secondary, tertiary, and aryl substrates Chemicals and Solvents,...
sn1: write the reactions for each of the secondary, tertiary, and
aryl substrates
Chemicals and Solvents, Chemical Abstract Service (CAS): (1) 1-chlorobutane, (109-69-3] (2) 1-bromobutane, (109-65-9) (3) 2-chlorobutane, (78-86-4) (4) 2-bromobutane, (78-76-2] (5) 2-chloro-2-methylpropane, (507-20-0) (6) bromobenzene, (108-86-1) (7) 2-bromo-2-methylpropane, (507-19-7) (8) ethanol, [64-17-5) 2. Sn1 Reaction. For the Sn1 reaction, the nucleophile is ethanol, introduced into the solution as the solvent in a silver nitrate-ethanol solution. If the reaction occurs, silver chloride or silver bromide will form a precipitate...
Read the experiment and briefly describe what you would predict to be your result if you...
Read the experiment and briefly describe what you would predict
to be your result if you were to perform this experiment and
why.
Part A: Determination of Factors Affecting the Relative Rates of Sy2 Reactions All test tubes must be dry. Effect of Structure of the Alkyl Halide Measure 2 mL of 15% sodium iodide in acetone into each of three clean, dry 10-cm test tubes. Add 2 drops of 1-bromobutane (butyl bromide) to the first test tube; add 2...
Draw the strcture of all substrates you will be using in this reaction and classify them...
Draw the strcture of all substrates you will be using in this
reaction and classify them as( primary, Secondary, and tertiary)
aryl bezylic or some combination of these (such as primary
bezylic). Identify the nucleophile, substrate, and leaving group in
general equations for reactions 1 and 2
ORRAS sminilah you dimensions (R) or (S), and show their stereochemistry clearly. If your instructor reguests, obtain another set of atoms and connectors and use it to prepare isomers as well. R eal...
A. What is the best procedure to prepare isopropyl methyl ether (CH)CHOCH? a. isopropyl iodide and...
A. What is the best procedure to prepare isopropyl methyl ether (CH)CHOCH? a. isopropyl iodide and NaOCH, b. isopropyl iodide and methanol c. methyl iodide and KOCH(CH) d. methyl iodide and (CH).CHOH B. Which alkyl halide would be most reactive in an S2 reaction? сн, a. (CHC-CHCI b d. B. What is the order of increasing reactivity for the following nucleophiles (least first)? Cно Н.О CH CO CHS Which is not a polar aprotic solvent? C. ь. снCN с. снон...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
can all parts of question A be answered and labeled please.
there is no data for precipitation of Nal in acetone.
NUCLEOPHILIC SUBSTITUTION A. Structural Effects on Sa1 and Sa2 Reactivity A1. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form. If you heated any of...
can question A2 part a and b be answered and labeled please.
information has been provided.
NUCLEOPHILIC SUBSTITUTION A. Structural Effects on S, 1 and S 2 Reactivity Al. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form. I you heated any of the test tubes,...
can question A parts A4 (a and b) A5 and A6 be answered neatly
and labled. with specifics in A5 and A6
Dale Tepot sub Partners NUCLEOPHILIC SUBSTITUTION A. Structural Effects on Sn1 and Sn2 Reactivity A1. In the following table, record the results of your group's experiments with the five alkyl halides and the two reagents, sodium iodide in acetone and alcoholic silver nitrate. Note the elapsed time required for turbidity to appear and for a precipitate to form....
sn1: write the reactions for each of the secondary, tertiary, and
aryl substrates
Chemicals and Solvents, Chemical Abstract Service (CAS): (1) 1-chlorobutane, (109-69-3] (2) 1-bromobutane, (109-65-9) (3) 2-chlorobutane, (78-86-4) (4) 2-bromobutane, (78-76-2] (5) 2-chloro-2-methylpropane, (507-20-0) (6) bromobenzene, (108-86-1) (7) 2-bromo-2-methylpropane, (507-19-7) (8) ethanol, [64-17-5) 2. Sn1 Reaction. For the Sn1 reaction, the nucleophile is ethanol, introduced into the solution as the solvent in a silver nitrate-ethanol solution. If the reaction occurs, silver chloride or silver bromide will form a precipitate...
Read the experiment and briefly describe what you would predict
to be your result if you were to perform this experiment and
why.
Part A: Determination of Factors Affecting the Relative Rates of Sy2 Reactions All test tubes must be dry. Effect of Structure of the Alkyl Halide Measure 2 mL of 15% sodium iodide in acetone into each of three clean, dry 10-cm test tubes. Add 2 drops of 1-bromobutane (butyl bromide) to the first test tube; add 2...
Draw the strcture of all substrates you will be using in this
reaction and classify them as( primary, Secondary, and tertiary)
aryl bezylic or some combination of these (such as primary
bezylic). Identify the nucleophile, substrate, and leaving group in
general equations for reactions 1 and 2
ORRAS sminilah you dimensions (R) or (S), and show their stereochemistry clearly. If your instructor reguests, obtain another set of atoms and connectors and use it to prepare isomers as well. R eal...
A. What is the best procedure to prepare isopropyl methyl ether (CH)CHOCH? a. isopropyl iodide and NaOCH, b. isopropyl iodide and methanol c. methyl iodide and KOCH(CH) d. methyl iodide and (CH).CHOH B. Which alkyl halide would be most reactive in an S2 reaction? сн, a. (CHC-CHCI b d. B. What is the order of increasing reactivity for the following nucleophiles (least first)? Cно Н.О CH CO CHS Which is not a polar aprotic solvent? C. ь. снCN с. снон...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
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