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14. Which of the following reagents should be used to prepare tert-butyl ethyl ether a) tert-butyl...
2. Please convert the following IUPAC chemical names into their corresponding structures. (10 pts) (b) tert-butyl...
2. Please convert the following IUPAC chemical names into their corresponding structures. (10 pts) (b) tert-butyl isobutyl ether (c) 1,2-epoxy-1-methylcyclopentane (a) 4-methylpentan-2-ol
help with all please 14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol...
help with all please
14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? H-Br: в) (CH);С —ӧ: A) (CH3)3C-ö: н- Br: Н H-Br н D) (CH3)3C-ö H- Вr: C) (CH3)3CÖ: d. D c. C b.B a. A 15. What would by the effect of doubling both the concentration of t-butyl bromide and the concentration of sodium iodide in the reaction of t-butyl bromide with sodium iodide in methanol? a. The rate stays the same....
1. (1R, 2R)-1-bromo-1,2-dimethylcyclohexane is heated in the presence of potassium tert-butoxide (KO-tert-Bu). Name mino...
1. (1R, 2R)-1-bromo-1,2-dimethylcyclohexane is heated in the presence of potassium tert-butoxide (KO-tert-Bu). Name minor product/s only 2. 2-iodo-1,1,2,3,3-pentamethylcyclohexane is heated in the presence of sodium ethoxide in ethanol, don’t name the product/s of the reaction 3. ,2,2-trimethylcyclohexan-1-ol is heated in aqueous sulfuric acid 4. (3S)-2-methyl-3-pentanol is heated in aqueous sulfuric acid
1.1 What is the equation for the rate of formation of tert-butyl alcohol from the reaction...
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
1.1 In which of the following solvents would the reaction of 1-bromobutane with sodium azide,NaN3, proceed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
a) tert 14. Which of any alcohol upon reaction with methylmagnesium Which of the following compounds...
a) tert 14. Which of any alcohol upon reaction with methylmagnesium Which of the following compounds does NOT give a tertiary bromide? CH, HC CH₂ D - Η Β) 10. Which of the following compounds is NOT oxidized by pyridinium chlorochromate (PCC)? a) 2-methyl-2-butanol b) 1-pentanol c) 2-pentanol D) 1,3-propanediol 11. What is the complete systematic IUPAC name for the following compound? A) 4-(1-methylethoxy)-4-isopropyl-4-methylpent-2-cne B) 4-isopropyl-2,4-dimethylhept-5-en-3-ol C) isopropyl-(4-isopropyl-4-methylbut-2-enyl) ether D) 4 isopropoxy-4,5-dimethylhex-2-ene E) 4-isopropyl-4-methylbut-2-en-isopropyl ether 12. Which of the following...
answer all please. 23. What is the equation for the rate of formation of tert-butyl alcohol...
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
Malonic ester (diethyl malonate) is treated successively with sodium ethoxide (1 eq.), ethyl bromide, potassium tert-butoxide,...
Malonic ester (diethyl malonate) is treated successively with sodium ethoxide (1 eq.), ethyl bromide, potassium tert-butoxide, isobutyl chloride, hot aqueous NaOH HCI, and heat. What is the final product? 6-Methylheptanoic acid • 2-Ethyl-3-methylpentanoic acid HE Ethylisobutylmalonic acid 4-Ethyl-2-methylpentanoic acid 2 Ethyl-4-methylpentanoic acid
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether,...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
NOMENCLATURE: Choose the correct IUPAC name for each of the structures below. If the correc name...
NOMENCLATURE: Choose the correct IUPAC name for each of the structures below. If the correc name doesn't appear, choose "none of the above." (3 pts each) a. 2-butyl-2-methylepoxide b. 1,2-epoxy-2-methylbutane c.2-butyl-2-methyloxirane d. 1,2-epoxy-2-methylpropane e. none of the above a. 1-ethoxy-2-isopropyl ether b. ethyl isobutyl ether c. 1-ethyl-2-methylbutane d. 1-ethoxy-2-isobutyl ether e. none of the above 3. I a. 1-sec-butyl-2-methylcyclopentene b. 1-iso-butyl-2-methylcyclopentane c. 1-methyl-2-sec-butylcyclopentene d. 1-sec-butyl-2-methylcyclohexene e, none of the above 4. Provide the structure for pyridine in the box below:...
2. Please convert the following IUPAC chemical names into their corresponding structures. (10 pts) (b) tert-butyl isobutyl ether (c) 1,2-epoxy-1-methylcyclopentane (a) 4-methylpentan-2-ol
help with all please
14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? H-Br: в) (CH);С —ӧ: A) (CH3)3C-ö: н- Br: Н H-Br н D) (CH3)3C-ö H- Вr: C) (CH3)3CÖ: d. D c. C b.B a. A 15. What would by the effect of doubling both the concentration of t-butyl bromide and the concentration of sodium iodide in the reaction of t-butyl bromide with sodium iodide in methanol? a. The rate stays the same....
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
a) tert 14. Which of any alcohol upon reaction with methylmagnesium Which of the following compounds does NOT give a tertiary bromide? CH, HC CH₂ D - Η Β) 10. Which of the following compounds is NOT oxidized by pyridinium chlorochromate (PCC)? a) 2-methyl-2-butanol b) 1-pentanol c) 2-pentanol D) 1,3-propanediol 11. What is the complete systematic IUPAC name for the following compound? A) 4-(1-methylethoxy)-4-isopropyl-4-methylpent-2-cne B) 4-isopropyl-2,4-dimethylhept-5-en-3-ol C) isopropyl-(4-isopropyl-4-methylbut-2-enyl) ether D) 4 isopropoxy-4,5-dimethylhex-2-ene E) 4-isopropyl-4-methylbut-2-en-isopropyl ether 12. Which of the following...
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
Malonic ester (diethyl malonate) is treated successively with sodium ethoxide (1 eq.), ethyl bromide, potassium tert-butoxide, isobutyl chloride, hot aqueous NaOH HCI, and heat. What is the final product? 6-Methylheptanoic acid • 2-Ethyl-3-methylpentanoic acid HE Ethylisobutylmalonic acid 4-Ethyl-2-methylpentanoic acid 2 Ethyl-4-methylpentanoic acid
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
NOMENCLATURE: Choose the correct IUPAC name for each of the structures below. If the correc name doesn't appear, choose "none of the above." (3 pts each) a. 2-butyl-2-methylepoxide b. 1,2-epoxy-2-methylbutane c.2-butyl-2-methyloxirane d. 1,2-epoxy-2-methylpropane e. none of the above a. 1-ethoxy-2-isopropyl ether b. ethyl isobutyl ether c. 1-ethyl-2-methylbutane d. 1-ethoxy-2-isobutyl ether e. none of the above 3. I a. 1-sec-butyl-2-methylcyclopentene b. 1-iso-butyl-2-methylcyclopentane c. 1-methyl-2-sec-butylcyclopentene d. 1-sec-butyl-2-methylcyclohexene e, none of the above 4. Provide the structure for pyridine in the box below:...
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