Homework Answers
14. Option A, electrons moves from rich site to deficient site.
15. Option C , rate increases by two times
Since it is SN1 mechanism and follow first order kinetics. Rate depends only on alkyl halides.
16. Option D,
Dehydration of alcohol order : 3°> 2° > 1° alcohol.
17. Option A, R configuration
Sicne it is SN2 reaction, hence inversion of configuration occured.
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14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol...
Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? A) (CH3)3CÖ:...
Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? A) (CH3)3CÖ: HBr: B) (CH3)3C—ö: H'Br: C) (CH3)3C-Ö: » caused D) (CHỌC 6:
13. What is the major product obtained from the following reaction (CH3),CO Nat Br t-butanol OC(CH),...
13. What is the major product obtained from the following reaction (CH3),CO Nat Br t-butanol OC(CH), 1 a. 1 b. 2 c. 3 d. 4 14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? A) (CH3),C-Ö: H Br: B) (CH3),C-Ö: H Br: н C) (CH3),C-o: Br: . D) (CH3),C–0: H Br: dD a. A b. B 15. What would by the effect of doubling both the concentration of t-butyl bromide and the concentration of...
answer all please. 23. What is the equation for the rate of formation of tert-butyl alcohol...
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
1.1 What is the equation for the rate of formation of tert-butyl alcohol from the reaction...
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
14. Which of the following reagents should be used to prepare tert-butyl ethyl ether a) tert-butyl...
14. Which of the following reagents should be used to prepare tert-butyl ethyl ether a) tert-butyl bromide and sodium ethoxide b) tert-butyl alcohol and ethyl bromide c) tert-butyl alcohol and ethanol d) potassium tert-butoxide and ethyl bromide 15. What is the major organic product obtained from the following reaction? A) 1 B) 2 C) 3 D) 4 16. What product is formed when methyloxirane is treated with ethylmannesium bromide followed by treatment with aqueous acid? A) 1-pentanol B) 2-pentanol C)...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what effect on the reaction rate would result from simultaneously doubling the concentrations of both butyl bromide and hydroxyl ion No effect (B)It would double the rate (C)it would increase the rate six times (D) It would increase the rate four times. 2. Which alky halide would you expect to undergo SN1 hydrolysis most rapidly? (A) (CH3)3C-I (B) (CH3)3C-Br (C) (CH3)3C-Cl (D) (CH3)3C-F 3....
1.1 In which of the following solvents would the reaction of 1-bromobutane with sodium azide,NaN3, proceed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether,...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
Please answer all 6 multiquestions and show work! Useful Information DMSO H₃C гсн 요 Acetone PK,...
Please answer all 6 multiquestions and show work!
Useful Information DMSO H₃C гсн 요 Acetone PK, NH3 = 38 Part 1: Multiple Choice: 1) Which atomic orbitals overlap to form the carbon-carbon triple bond of an alkyne? a) 2s + 2s; sp + sp; 2p + 2p b) sp + sp; sp + sp; 2p + 2p c) sp + sp; 2p + 2p; 2p + 2p d) sp + sp?; sp + sp; 2p + 2p 2. In a...
() 1. Which of the following alkyl holides would you expect to be most reactive in a unimolecular reaction? CH3 a)...
() 1. Which of the following alkyl holides would you expect to be most reactive in a unimolecular reaction? CH3 a) CsM , CH, CH, CH, Br b) CEHCH CH BY c) CH, CCH, Br d) CH, CH2 CH CHE сн. он сня Br e) CHICCHE CH3 (4). 2. What would you expect to be the chief organic product(s) when tert-butyl bromide reacts with sodium acetylide, i.e.. CH + - CH3-C-Br + Na CECH ? CH a) 1 b) II...
Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? A) (CH3)3CÖ: HBr: B) (CH3)3C—ö: H'Br: C) (CH3)3C-Ö: » caused D) (CHỌC 6:
13. What is the major product obtained from the following reaction (CH3),CO Nat Br t-butanol OC(CH), 1 a. 1 b. 2 c. 3 d. 4 14. Which of the following mechanistically depicts the protonation of tert-butyl alcohol by hydrogen bromide? A) (CH3),C-Ö: H Br: B) (CH3),C-Ö: H Br: н C) (CH3),C-o: Br: . D) (CH3),C–0: H Br: dD a. A b. B 15. What would by the effect of doubling both the concentration of t-butyl bromide and the concentration of...
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
14. Which of the following reagents should be used to prepare tert-butyl ethyl ether a) tert-butyl bromide and sodium ethoxide b) tert-butyl alcohol and ethyl bromide c) tert-butyl alcohol and ethanol d) potassium tert-butoxide and ethyl bromide 15. What is the major organic product obtained from the following reaction? A) 1 B) 2 C) 3 D) 4 16. What product is formed when methyloxirane is treated with ethylmannesium bromide followed by treatment with aqueous acid? A) 1-pentanol B) 2-pentanol C)...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
Please answer all 6 multiquestions and show work!
Useful Information DMSO H₃C гсн 요 Acetone PK, NH3 = 38 Part 1: Multiple Choice: 1) Which atomic orbitals overlap to form the carbon-carbon triple bond of an alkyne? a) 2s + 2s; sp + sp; 2p + 2p b) sp + sp; sp + sp; 2p + 2p c) sp + sp; 2p + 2p; 2p + 2p d) sp + sp?; sp + sp; 2p + 2p 2. In a...
() 1. Which of the following alkyl holides would you expect to be most reactive in a unimolecular reaction? CH3 a) CsM , CH, CH, CH, Br b) CEHCH CH BY c) CH, CCH, Br d) CH, CH2 CH CHE сн. он сня Br e) CHICCHE CH3 (4). 2. What would you expect to be the chief organic product(s) when tert-butyl bromide reacts with sodium acetylide, i.e.. CH + - CH3-C-Br + Na CECH ? CH a) 1 b) II...
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