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Please answer all 6 multiquestions and show work!
Useful Information DMSO H₃C гсн 요 Acetone PK,...
answer all please. 23. What is the equation for the rate of formation of tert-butyl alcohol...
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
1.1 What is the equation for the rate of formation of tert-butyl alcohol from the reaction...
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
Please help with A-H Apply retrosynthetic analysis to guide the preparation of each of the following...
Please help with A-H
Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the indicated starting material, then write out the synthesis showing the necessary reagents. (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (c) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl bromide (e) 1,2-Epoxypropane from 2-propanol (1) tert-Butyl alcohol from isobutyl alcohol (g) tert-Butyl iodide from isobutyl iodide (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (C) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl...
1.1 In which of the following solvents would the reaction of 1-bromobutane with sodium azide,NaN3, proceed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
Chapter 8, Problem 50P 4 Bookmarks Show all steps: OFF O Problem Apply retrosynthetic analysis to...
Chapter 8, Problem 50P 4 Bookmarks Show all steps: OFF O Problem Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the indicated starting material, then write out the synthesis showing the necessary reagents. (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (c) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl bromide (e) 1,2-Epoxypropane from 2-propanol (1) tert-Butyl alcohol from isobutyl alcohol (9) fert-Butyl iodide from isobutyl iodide (h) trans-2-Chlorocyclohexanol from cyclohexyl chloride
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH...
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH + CH3OH — Kºchs + HBr CH3 + HBr Ph Ph A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d....
1. The next several questions of this post-lab will relate to your lab procedure. Please refer...
1. The next several questions of this post-lab will relate to your lab procedure. Please refer to your notebook pages for values you recorded during lab. (16 pts) a. Based on the data you collected, did tert-butyl bromide or tert-butyl chloride react faster? b. Based on the data you collected, did tert-butyl bromide or 2-bromopropane react faster? C. Based on the data you collected, which solvent provided the fastest reaction rate? d. Based on the data you collected, how did...
answer all 1. In each of the following, indicate which S2 reaction will occur faster. Explain...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what effect on the reaction rate would result from simultaneously doubling the concentrations of both butyl bromide and hydroxyl ion No effect (B)It would double the rate (C)it would increase the rate six times (D) It would increase the rate four times. 2. Which alky halide would you expect to undergo SN1 hydrolysis most rapidly? (A) (CH3)3C-I (B) (CH3)3C-Br (C) (CH3)3C-Cl (D) (CH3)3C-F 3....
answer all please.
23. What is the equation for the rate of formation of tert-butyl alcohol from the reaction of tert-butyl bromide (t-BuBr) with water by an Syl mechanism? A) Rate -k [t-BuBr] B) Rate = k [t-BuBr] [H,O] C) Rate k [H2O D) Rate k [t-BuBr] 24. Which of the following statements related to Ssl reactions is not true? A) The SN1 reaction can be described as a heterolytic bond cleavage followed by nucleophilic attack. B) Carbocations are electrophilic....
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
Please help with A-H
Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the indicated starting material, then write out the synthesis showing the necessary reagents. (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (c) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl bromide (e) 1,2-Epoxypropane from 2-propanol (1) tert-Butyl alcohol from isobutyl alcohol (g) tert-Butyl iodide from isobutyl iodide (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (C) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
Chapter 8, Problem 50P 4 Bookmarks Show all steps: OFF O Problem Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the indicated starting material, then write out the synthesis showing the necessary reagents. (a) 1-Propanol from 2-propanol (b) 1,2-Dibromopropane from 2-bromopropane (c) 1-Bromo-2-propanol from 2-propanol (d) 1-Bromo-2-methyl-2-propanol from tert-butyl bromide (e) 1,2-Epoxypropane from 2-propanol (1) tert-Butyl alcohol from isobutyl alcohol (9) fert-Butyl iodide from isobutyl iodide (h) trans-2-Chlorocyclohexanol from cyclohexyl chloride
2. Consider the Sn1 reaction shown below and answer the following questions. Br K . CHOH + CH3OH — Kºchs + HBr CH3 + HBr Ph Ph A. Write the rate law for the reaction. B. Identify the nucleophile, the electrophile, and the reaction solvent. C. State how each of the following factors would affect the rate of the reaction. a. Increasing the concentration of the alkyl halide. b. Increasing the concentration of CH3OH. c. Replacing HOCH3 with NaOCH3. d....
1. The next several questions of this post-lab will relate to your lab procedure. Please refer to your notebook pages for values you recorded during lab. (16 pts) a. Based on the data you collected, did tert-butyl bromide or tert-butyl chloride react faster? b. Based on the data you collected, did tert-butyl bromide or 2-bromopropane react faster? C. Based on the data you collected, which solvent provided the fastest reaction rate? d. Based on the data you collected, how did...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
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