Draw the molecular orbital diagram for:
(indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines)
1. PF5
2. SCl4
Draw the molecular orbital diagram for: (indicate the point group symmetry and draw with bonding and...
Draw the molecular orbital diagram for: (indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines) 1. SCl4 2. CO2
Draw the molecular orbital diagram for SCl4. PLEASE indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines!
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each molecular orbital. Indicate whether each molecular bonding, nonbonding, or anti-bonding and don't forget the σ and π labels. Remember to construct appropriate group orbitals from the outer H-atoms. Describe the bonding of this molecule from the MO diagram you constructed, including the location s) of the lone pair(s). The 2s and 2p energies for oxygen are -26 and -13 eV, respectively, and the ls energy of...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
6. Draw a Molecular Orbital Energy Diagram for the compound below. Your diagram should clearly indicate how many o, , o, . and non-bonding orbitals are present, the relative energy of these orbitals, and the total number of electrons in each of these orbitials. (10 pt) N-H
1. Draw a molecular orbital diagram to illustrate the d-orbital bonding that yield the quadruple bond in a chromium(II) acetate complex. 2. Quadruple bonds are common in transition metal complexes, but are never seen in organic chemistry. Why not?
Using a symmetry-based approach, construct a complete molecular orbital diagram for OH2. (a) Indicate the HOMO and LUMO. (b) Draw a representation of the HOMO and LUMO. (c) If one were to react this cation with another proton to give the dicationic species [H3O] + explain what would happen to the energies of the orbitals in the OH2 diagram after this reaction. Be specific about the key features regarding the M.O. diagram in the new cation. You do NOT need...
Construct a molecular orbital diagram for carbon monoxide. Identify the relevant point group, include all of the appropriate symmetry labels and pictures, and fill in the electrons. Make sure to account for the difference in electronegativity between C and O. Hint: CO is substantially isoelectronic to N2.
2) HO adopts C2v symmetry (a) Create SALCs for the H atoms and, using the Czv character table on the attached sheet, derive representations for each SALC and then assign the appropriate symmetry. (b) Assign the symmetry for the orbitals on the central O atom, again using the character table (c) Create a reasonable MO diagram for H O and label appropriately (02s:-32 eV O2p:-16 eV, Hls 4 cV) You may assume the s-orbital on O is functionally non-bonding. (d)...
1. Use symmetry considerations to construct a qualitative molecular orbital energy level diagram for PFs - consider only s and p orbitals. 2, Give the point groups designations and show the symmetry elements used to establish that designation in the following.