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ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
Characterize the following halides as primary (1°), secondary (2°) or tertiary (3°), OR, as bonded to...
Characterize the following halides as primary (1°), secondary
(2°) or tertiary (3°), OR, as bonded to an sp2 hybridized
carbon atom (in which case 1°, 2° etc. doesn't apply)
7. (3 pts.) Characterize the following halides as primary (1°), secondary (2°) or tertiary (3°), OR, as bonded to an sp2 hybridized carbon atom (in which case 1°, 2° etc. doesn't apply) 1-bromobutane CI t-butylbromide 2-chlorobutane CI 1-chlorobutane Br Br t-butylchloride bromobenzene 2-bromobutane
Classify these alcohols as primary (1°), secondary (2°), or tertiary (3) 10 20 3e он CH2CH3...
Classify these alcohols as primary (1°), secondary (2°), or tertiary (3) 10 20 3e он CH2CH3 CH2CH3 CH3COH CH3CHCHCH3 CH3CCH2OH CH2CH3 CH3 CH3
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic...
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic Transformation 10.9: Syn Addition of Two OH Groups to ax Bond H OH но OsO4 or OH NaHSO a cold, dilute KMnO, solution, followed by KOH can be used in place of the highly toxic OsO Review of Synthetic Transformations 9.3/9.4 H HOHO OH acide ring opening eр МCРВА or 1) Кон. 2) neutrize with dilute acid basic ring opening он Critical Thinking Question...
What kinds of interactions are NOT part of tertiary protein structure? 3 . A) salt bridges...
What kinds of interactions are NOT part of tertiary protein structure? 3 . A) salt bridges In a hydrolysis reaction, B) hydrophilic interactions A. an acid reacts with an alcohol. C) disulfide bonds E. an este reacts with NaOH. C. anester reacts with H.O. D) peptide bonds D. an acid neutralizes a base. E) hydrophobic interactions E. water is added to markene. . All amino acids have chiral Carbon atoms except a. Val 6. Lys C. ASP d. Ala e....
Which of the following functional groups is not found in the D) molecule shown in Figure...
Which of the following functional groups is not found in the D) molecule shown in Figure 2? Он SH amide i) other iii) alkene iv) alkyne v) ester vi) thiol vii) i-vi are all present in the molecule R-0-2 NH Figure 2 E) Which of the following is not found in the molecule shown in Figure 3? но i) secondary alkyl halide i) primary alcohole ii primary carbon V quaternary carbon v) tertiary alkyl halide vi) tertiary alcohol vii)i-vi are...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you will synthesize a brom ohydrin according to the reaction shown below. Using infrared (IR) spectroscopy and a simple chemical test, you will determine which product (Markovnikov or anti-Markovnikov) is formed. N-bromosuccinimide Br (NBS) но or н.о, THF ""сн, он "Br CH3 CH3 1-methylcyclohexene Markovnikov product anti-Markovnikov product Halogenation of alkenes is an important reaction in organic chemistry. When carried out in an aqueous solution,...
1. 2. 3. Balancing Oxidation-Reduction Reactions 1. Assign oxidation numbers. 2. Separate into oxidation and reduction...
1. 2. 3.
Balancing Oxidation-Reduction Reactions 1. Assign oxidation numbers. 2. Separate into oxidation and reduction half reactions. 3. Balance each half reaction using the following steps: a. Balance all elements except oxygen or hydrogen. b. Balance oxygen by adding H20. c. Balance hydrogen by adding H*. d. Balance charge by adding electrons: Electrons go on the RIGHT (product side) for OXIDATION reactions. Electrons go on the LEFT (reactant side) for REDUCTION reactions. e. In BASIC solution, do this additional...
Dropdown Menus: 1. methyl, primary (unhindered), primary (hindered), secondary, tertiary 2. poor, weakly basic, strongly basic...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
OH Hom 유 용 The Tone The ♡ ♡ Tñ y OH H OH E OH F HO3 G Look at the given...
Laboratory MOUTU ICEF MCPHS University - Professor Z. I. Po CHE 231L.1-7 - Organic Chemistry I...
Laboratory MOUTU ICEF MCPHS University - Professor Z. I. Po CHE 231L.1-7 - Organic Chemistry I - Fall 2019 E or Zand the aliene as Eor Zand () shown below. Identify Examine the cholesterol-lowering drug Rosuvastatin (Crestor absolute configuration of the 2 alcohol as Rors. Eor 2 Rosuvastatin Crestor d to treat high holes e and r and related conditions, and to prevent cardiovascular disease JER Ja ZS bZR [CES ſe] E, achiral 7. Examine the molecule piperine, an alkaloid...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
Characterize the following halides as primary (1°), secondary
(2°) or tertiary (3°), OR, as bonded to an sp2 hybridized
carbon atom (in which case 1°, 2° etc. doesn't apply)
7. (3 pts.) Characterize the following halides as primary (1°), secondary (2°) or tertiary (3°), OR, as bonded to an sp2 hybridized carbon atom (in which case 1°, 2° etc. doesn't apply) 1-bromobutane CI t-butylbromide 2-chlorobutane CI 1-chlorobutane Br Br t-butylchloride bromobenzene 2-bromobutane
Classify these alcohols as primary (1°), secondary (2°), or tertiary (3) 10 20 3e он CH2CH3 CH2CH3 CH3COH CH3CHCHCH3 CH3CCH2OH CH2CH3 CH3 CH3
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic Transformation 10.9: Syn Addition of Two OH Groups to ax Bond H OH но OsO4 or OH NaHSO a cold, dilute KMnO, solution, followed by KOH can be used in place of the highly toxic OsO Review of Synthetic Transformations 9.3/9.4 H HOHO OH acide ring opening eр МCРВА or 1) Кон. 2) neutrize with dilute acid basic ring opening он Critical Thinking Question...
What kinds of interactions are NOT part of tertiary protein structure? 3 . A) salt bridges In a hydrolysis reaction, B) hydrophilic interactions A. an acid reacts with an alcohol. C) disulfide bonds E. an este reacts with NaOH. C. anester reacts with H.O. D) peptide bonds D. an acid neutralizes a base. E) hydrophobic interactions E. water is added to markene. . All amino acids have chiral Carbon atoms except a. Val 6. Lys C. ASP d. Ala e....
Which of the following functional groups is not found in the D) molecule shown in Figure 2? Он SH amide i) other iii) alkene iv) alkyne v) ester vi) thiol vii) i-vi are all present in the molecule R-0-2 NH Figure 2 E) Which of the following is not found in the molecule shown in Figure 3? но i) secondary alkyl halide i) primary alcohole ii primary carbon V quaternary carbon v) tertiary alkyl halide vi) tertiary alcohol vii)i-vi are...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you will synthesize a brom ohydrin according to the reaction shown below. Using infrared (IR) spectroscopy and a simple chemical test, you will determine which product (Markovnikov or anti-Markovnikov) is formed. N-bromosuccinimide Br (NBS) но or н.о, THF ""сн, он "Br CH3 CH3 1-methylcyclohexene Markovnikov product anti-Markovnikov product Halogenation of alkenes is an important reaction in organic chemistry. When carried out in an aqueous solution,...
1. 2. 3.
Balancing Oxidation-Reduction Reactions 1. Assign oxidation numbers. 2. Separate into oxidation and reduction half reactions. 3. Balance each half reaction using the following steps: a. Balance all elements except oxygen or hydrogen. b. Balance oxygen by adding H20. c. Balance hydrogen by adding H*. d. Balance charge by adding electrons: Electrons go on the RIGHT (product side) for OXIDATION reactions. Electrons go on the LEFT (reactant side) for REDUCTION reactions. e. In BASIC solution, do this additional...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
OH Hom 유 용 The Tone The ♡ ♡ Tñ y OH H OH E OH F HO3 G Look at the given...
Laboratory MOUTU ICEF MCPHS University - Professor Z. I. Po CHE 231L.1-7 - Organic Chemistry I - Fall 2019 E or Zand the aliene as Eor Zand () shown below. Identify Examine the cholesterol-lowering drug Rosuvastatin (Crestor absolute configuration of the 2 alcohol as Rors. Eor 2 Rosuvastatin Crestor d to treat high holes e and r and related conditions, and to prevent cardiovascular disease JER Ja ZS bZR [CES ſe] E, achiral 7. Examine the molecule piperine, an alkaloid...
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