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3) Circle each hydrogen in the molecule below that would have a pK, less than 20,...
Consider the indicated protons in the molecules shown below. Circle the molecule with the lower pK,...
Consider the indicated protons in the molecules shown below. Circle the molecule with the lower pK, and explain your choice with an appropriate drawing. NH ZE OH оме Но, . Meo b) Ho Ho (Rationalize with a one sentence explanation.) d) Rank the following molecules in order from least acidic to most acidic. Rationalize your choice with an appropriate drawing.
6 (4 pts, total: 2 pts, each) For each of the following questions, circle the BEST...
6 (4 pts, total: 2 pts, each) For each of the following questions, circle the BEST a. Strongest Bronsted-Lowry acid HF HCI HBO HI b. Has the lowest pk. CH NH H2O Has 7. (4 pts total, 2 pts each) For each of the following molecular structures, circle the MOST acidic hydrogen. Note that lone pairs have been omitted for clarity. HH HHHH Horacaugh a HHH b Hн 8. (4 pts. total; 2 pts, each) in the space provided below,...
6. (4 pts. total 2 pts.cach) For each of the following questions, circle the BEST answer...
6. (4 pts. total 2 pts.cach) For each of the following questions, circle the BEST answer a Strongest Bronsted-Lowry acid нсі HB: HF b. Has the lowest pk. CHA NH3 H20 Has 7. (4 pts total, 2 pts each) For each of the following molecular structures, circle the MOST acidie hydrogen. Note that lone pairs have been omitted for clarity. HH н ннн нссон Hagh HHH HH 8. (4 pts. total: 2 pts, each) In the space provided below, explain...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
2 Circle the most acidic hydrogen(s) in the molecule. (8 pts) H 1 HH H a....
2 Circle the most acidic hydrogen(s) in the molecule. (8 pts) H 1 HH H a. H HHH HHHH 3. Determine the pK, for each type of hydrogen in the molecule. Write the number above the line for each type of hydrogen. (10 pts) ноно HHHH 4. Draw an arrow pointing to the most basic atom in each molecule. (8 pts) b. OCH 5. Show the synthesis of the target molecule. You may use benzene, potassium cyanide, and chloromethane as...
3. Circle the molecule would you expect to have the higher melting point and explain your...
3. Circle the molecule would you expect to have the higher melting point and explain your choice. ОН 4. The following is a generic reaction equation for a Fischer Esterification. H+ R'-OH Н.О R' ОН R' OR' How would you increase the yield of the ester product? a. What effect does the acid catalyst have on the position of equilibrium? b. c. The forward reaction is an esterification. What is the reverse reaction called? 5. Name one of the noncovalent...
Please Explain. (2) How many stereocenters does each molecule have. How many stereoisomers each molecule can...
Please Explain.
(2) How many stereocenters does each molecule have. How many stereoisomers each molecule can have in theory? Br Br CI Br а от OH ОН ОН ОН (3) Circle the chiral molecules. If molecule is achiral – show its plane of symmetry. Н Н. СІ CI Br Br Br да» 2 HT / / CH3 CH3 1 1
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
3. Acids and Bases. (15 pts) (a) Circle the weakest acid in each series shown below (9 pts). Seri...
poease answer and explain all. thank you!
3. Acids and Bases. (15 pts) (a) Circle the weakest acid in each series shown below (9 pts). Series 1 HC CH2 Series 2 OH он OH Series 3 Cl ai pk, 9.38 pk, 10.2 (b) Draw the products of the following acid-base reaction (6 pts). CH3O reactants products 4. Use curved arrow to indieate the flow of electrons for the following elementary steps. Label each step with a proper name such as...
Which of the following molecules would you expect to have the highest pka? Note that the...
Which of the following molecules would you expect to have the highest pka? Note that the most acidic hydrogen in each molecule has been drawn in red. ОН Br ОН F ОН CI ОН
Consider the indicated protons in the molecules shown below. Circle the molecule with the lower pK, and explain your choice with an appropriate drawing. NH ZE OH оме Но, . Meo b) Ho Ho (Rationalize with a one sentence explanation.) d) Rank the following molecules in order from least acidic to most acidic. Rationalize your choice with an appropriate drawing.
6 (4 pts, total: 2 pts, each) For each of the following questions, circle the BEST a. Strongest Bronsted-Lowry acid HF HCI HBO HI b. Has the lowest pk. CH NH H2O Has 7. (4 pts total, 2 pts each) For each of the following molecular structures, circle the MOST acidic hydrogen. Note that lone pairs have been omitted for clarity. HH HHHH Horacaugh a HHH b Hн 8. (4 pts. total; 2 pts, each) in the space provided below,...
6. (4 pts. total 2 pts.cach) For each of the following questions, circle the BEST answer a Strongest Bronsted-Lowry acid нсі HB: HF b. Has the lowest pk. CHA NH3 H20 Has 7. (4 pts total, 2 pts each) For each of the following molecular structures, circle the MOST acidie hydrogen. Note that lone pairs have been omitted for clarity. HH н ннн нссон Hagh HHH HH 8. (4 pts. total: 2 pts, each) In the space provided below, explain...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
2 Circle the most acidic hydrogen(s) in the molecule. (8 pts) H 1 HH H a. H HHH HHHH 3. Determine the pK, for each type of hydrogen in the molecule. Write the number above the line for each type of hydrogen. (10 pts) ноно HHHH 4. Draw an arrow pointing to the most basic atom in each molecule. (8 pts) b. OCH 5. Show the synthesis of the target molecule. You may use benzene, potassium cyanide, and chloromethane as...
Please Explain.
(2) How many stereocenters does each molecule have. How many stereoisomers each molecule can have in theory? Br Br CI Br а от OH ОН ОН ОН (3) Circle the chiral molecules. If molecule is achiral – show its plane of symmetry. Н Н. СІ CI Br Br Br да» 2 HT / / CH3 CH3 1 1
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
poease answer and explain all. thank you!
3. Acids and Bases. (15 pts) (a) Circle the weakest acid in each series shown below (9 pts). Series 1 HC CH2 Series 2 OH он OH Series 3 Cl ai pk, 9.38 pk, 10.2 (b) Draw the products of the following acid-base reaction (6 pts). CH3O reactants products 4. Use curved arrow to indieate the flow of electrons for the following elementary steps. Label each step with a proper name such as...
Which of the following molecules would you expect to have the highest pka? Note that the most acidic hydrogen in each molecule has been drawn in red. ОН Br ОН F ОН CI ОН
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