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Consider the indicated protons in the molecules shown below. Circle the molecule with the lower pK,...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
3. a) Draw both chair conformations for the molecule shown below. (2pts) b) Circle the most...
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
5. For the set of molecules shown circle the weakest acid and explain your selection. HECH...
5. For the set of molecules shown circle the weakest acid and explain your selection. HECH CH CHE HCNA Hoc-da H₂c-op 6. Circle the indicated protons in each molecule that is more acidic. Explain your selection. Tote..b Cher I Page
with one another? no loan pais 1. For each compound shown below, number the illustrated protons...
with one another? no loan pais 1. For each compound shown below, number the illustrated protons according to their acidity: most acidic (1) to least acidic (3). (9 points) H H NH2 H OH HO F F OH O HS OH 13. Shown below is the formal structure of the amino acid methionine and its structure as it exists at physiological pH ( 7.3). In each case, the molecule itself is neutral; however at pH 7.3 there is an atom...
Organic Chemistry 4. Below are two molecules, B and C. Explain the differences in pKa of...
Organic Chemistry
4. Below are two molecules, B and C. Explain the differences in pKa of the two molecules by drawing the conjugate base of molecule C and a resonance structure that would not be found in molecule B. Hint: Draw out the NO2 group. conjugate base of molecule C pKa- 29.5 molecule B NO2 pka= 8.6 molecule C 5. Below is the molecule Abilify, which is a top selling drug that is used to treat schizophrenia, bipolar disorder and...
1. For the molecule below a) Circle and label all functional groups. b) Name all intermolecular...
1. For the molecule below a) Circle and label all functional groups. b) Name all intermolecular forces present in the molecule: Amane Aromates hetone lendon dspervon Dipale -Dipole Amine Aromatr 2. For the molecule below a) Box in all atoms that can hydrogen bond with water but not with acetone (CH3OCHS) b) Label all electrophilic carbons (use 6*) NH c) Label the least basic nitrogen. НО d) Label the most acidic hydrogen
1-5 Problem I: Give the approximate pka of the indicated H's in the following molecules: Problem...
1-5
Problem I: Give the approximate pka of the indicated H's in the following molecules: Problem II: Circle the most acidic proton in the following molecules: Problem IV: Using ARIO order the following molecule in decreasing order: Problem V: Indicate the direction the reaction would go by placing the appropriate arrows: (reaction goes from lowest to highest pka) + OH + H2O
uestion 2 Rank these molecules in order of decreasing acidity [that is, most acidic first.] 1. CHCHCO2Н 2....
uestion 2 Rank these molecules in order of decreasing acidity [that is, most acidic first.] 1. CHCHCO2Н 2. CH-CHCO,н F 3. CH-CН-СО,Н 2 3 1 2> 1> 3 1> 2 3 3> 2 11 O 1>3> 2 Question 3 Which compound is the most acidic? Cl CI C Question 5 Which of the following molecules is the product of an aldol reaction? ОН HO HO IV ОН and IV Question 11 Which of the following contains an amide functional group?...
(b) How many t bonds in 7. In each case, circle the molecule of the pair...
(b) How many t bonds in 7. In each case, circle the molecule of the pair with the specified property. At the right, give a brief explanation for your choice in terms of intermolecular forces (IMFS). (a) more soluble in water: Explanations: OH (b) higher boiling point: OH HO OH (c) More soluble in CCl NH&CI CH3(CH2).CH3 (d) higher boiling point: (e) higher boiling point: CH3(CH2)4CH3 CHs(CH2),CH3 () higher boiling point:
a. Provide the IUPAC name of the molecule shown below. (4 points) b. Circle all achiral...
a. Provide the IUPAC name of the molecule shown below. (4 points) b. Circle all achiral (meso) compounds below. (4 points) OH COH HOZC OH c. Draw the structure of the compound based on its IUPAC name. (4 points) d. Of the cations below, circle any that are achiral. (4 points) OAC Hg ΤΗ (E)-4-ethyl-3-fluorohept-3-ene e. Provide the IUPAC name of the molecule shown below. (4 points) f Rank the following cations from least stable to most stable. (3 points)...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
5. For the set of molecules shown circle the weakest acid and explain your selection. HECH CH CHE HCNA Hoc-da H₂c-op 6. Circle the indicated protons in each molecule that is more acidic. Explain your selection. Tote..b Cher I Page
with one another? no loan pais 1. For each compound shown below, number the illustrated protons according to their acidity: most acidic (1) to least acidic (3). (9 points) H H NH2 H OH HO F F OH O HS OH 13. Shown below is the formal structure of the amino acid methionine and its structure as it exists at physiological pH ( 7.3). In each case, the molecule itself is neutral; however at pH 7.3 there is an atom...
Organic Chemistry
4. Below are two molecules, B and C. Explain the differences in pKa of the two molecules by drawing the conjugate base of molecule C and a resonance structure that would not be found in molecule B. Hint: Draw out the NO2 group. conjugate base of molecule C pKa- 29.5 molecule B NO2 pka= 8.6 molecule C 5. Below is the molecule Abilify, which is a top selling drug that is used to treat schizophrenia, bipolar disorder and...
1. For the molecule below a) Circle and label all functional groups. b) Name all intermolecular forces present in the molecule: Amane Aromates hetone lendon dspervon Dipale -Dipole Amine Aromatr 2. For the molecule below a) Box in all atoms that can hydrogen bond with water but not with acetone (CH3OCHS) b) Label all electrophilic carbons (use 6*) NH c) Label the least basic nitrogen. НО d) Label the most acidic hydrogen
1-5
Problem I: Give the approximate pka of the indicated H's in the following molecules: Problem II: Circle the most acidic proton in the following molecules: Problem IV: Using ARIO order the following molecule in decreasing order: Problem V: Indicate the direction the reaction would go by placing the appropriate arrows: (reaction goes from lowest to highest pka) + OH + H2O
uestion 2 Rank these molecules in order of decreasing acidity [that is, most acidic first.] 1. CHCHCO2Н 2. CH-CHCO,н F 3. CH-CН-СО,Н 2 3 1 2> 1> 3 1> 2 3 3> 2 11 O 1>3> 2 Question 3 Which compound is the most acidic? Cl CI C Question 5 Which of the following molecules is the product of an aldol reaction? ОН HO HO IV ОН and IV Question 11 Which of the following contains an amide functional group?...
(b) How many t bonds in 7. In each case, circle the molecule of the pair with the specified property. At the right, give a brief explanation for your choice in terms of intermolecular forces (IMFS). (a) more soluble in water: Explanations: OH (b) higher boiling point: OH HO OH (c) More soluble in CCl NH&CI CH3(CH2).CH3 (d) higher boiling point: (e) higher boiling point: CH3(CH2)4CH3 CHs(CH2),CH3 () higher boiling point:
a. Provide the IUPAC name of the molecule shown below. (4 points) b. Circle all achiral (meso) compounds below. (4 points) OH COH HOZC OH c. Draw the structure of the compound based on its IUPAC name. (4 points) d. Of the cations below, circle any that are achiral. (4 points) OAC Hg ΤΗ (E)-4-ethyl-3-fluorohept-3-ene e. Provide the IUPAC name of the molecule shown below. (4 points) f Rank the following cations from least stable to most stable. (3 points)...
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