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12 This question explores the energy transfer during the reversible isothermal expansion of a van-der-Waals gas. a) The equation of state of the van-der-Waals gas is 141 where Vm is the molar volume. Explain the significance of the constants a and b giving a physical interpretation of both by comparing the equation given with the equation of state of the ideal gas. b) Re-arrange the equation of state given above to produce a formula for the pressure [3] as a function of molar volume and temperature by solving the equation for p.

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Anstwer- Given van-tr-aal eq of ged a 4 b hart posntive values and are he The onshant a proikes a cornecthon for intermolenula The constontb is a correction for finte Charaoteristics ndividual gas fos ces one mole at atams molecules As asbo van-der-poal ef be como ideal gas equcthon P ST ie. ρ=P(T,w) as R,bfa are constant Thls 15 reqtived formula 2019-1-8 20:59

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