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1) Give the product of the two reactions shown. КОН xs Br2 can form. 2) Draw...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C +...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Can someone explain the mechanisms + products for these reactions? 1. (3p) Draw the mechanism and...
Can someone explain the mechanisms + products for these
reactions?
1. (3p) Draw the mechanism and the expected reaction product for the following reaction: ? 2. (3p). Draw the mechanism and the expected Nucleophilic Substitution Reaction Product for the following reaction: ? OH
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2...
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2 HO HO Bry 1) Lithium Disopropylamide (LDA) 2) CIES o spomen 1) Lithium Disopropyl anide (LDA) OCH, CITOTT 1) OHI 2) CHI OH Give all possible products from the following mixed aldol reaction and show how they can be formed. Show the mechanism for the keto enol tautomerization of 2-propanone in both acid and in base.
can someone please explain the mechanism behind these two reactions? thanks 26. What is the product...
can someone please explain the mechanism behind these two
reactions? thanks
26. What is the product of the following reaction? JOMO WOOT OM ОН o oo i > VI > Vio 008 OH OH он OH Onlwolle OH SOAL . IV A) 1 B) II C) III D IV was 27. What is the product of the following reaction? qu-how ibis volls) noile piwollo on looser YOH 1. SOCI 2. MeOH HO ОMe CI OSCI OME OME YOH2. SO A)...
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2 HO HO Bry 1) Lithium Diso...
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2 HO HO Bry 1) Lithium Disopropylamide (LDA) 2) CIES o spomen 1) Lithium Disopropyl anide (LDA) OCH, CITOTT 1) OHI 2) CHI OH Give all possible products from the following mixed aldol reaction and show how they can be formed. Show the mechanism for the keto enol tautomerization of 2-propanone in both acid and in base.
Draw a structural formula for the major organic product of the reaction shown.
Electrophilic addition of HBr to alkenes yields a bromoalkane. The reaction begins with an attack on the hydrogen of the electrophilic HBr by the electrons of the double bond to give a carbocation. This step follows Markovnikov's rule with the electrophilic H atom adding to the sp2 carbon containing the most hydrogens, leading to the formation of the most stable carbocation (1° < 2° < 3°). If possible, a 1,2-shift of either a neighboring hydride or methyl group can occur...
1. Consider the following two reactions, only one of which will work as shown: a) What...
1. Consider the following two reactions, only one of which will
work as shown:
a) What is the stereochemical relationship between starting
material A and B?
b) Draw the mechanism for the reaction to convert the starting
material into the product. You can use either starting material A
or B to show the mechanism.
c) Draw the two chair forms for starting material A and circle
the more stable chair form. Explain why the one you circled is more
stable....
1. Give the structure of the product(s) for the following addition reactions. Show appropriate stereochemistry if...
1. Give the structure of the product(s) for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points) 50% H2SO4 50% H20 1. BH3, THF 2. H2O2/KOH CH3COOH ry condon YY PEO 1. 03 2. Zn/H2O 2. Give the syn or anti addition products for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points total) Hz/Pt 1 point 1 point Hypt DBk Det ook o BryH2O 1....
1. The chiral compound in the center of the diagram below can undergo three different reactions. Fill in product struct...
1. The chiral compound in the center of the diagram below can undergo three different reactions. Fill in product structures in each box and give their stereochemistry. For the Sul reaction the two products are enantiomers of each other. For the E1 reaction products, two are diastereomers of each other and the third is a constitutional isomer of the other two. H30 NaOH H20 E1 E2 Sn1 NaOH SN2 2. Draw the structure of the major product of the reaction...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s)...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s) would accomplish the following? Show mechanism. R-CH2-NH2 R-C-NH2 3. What would result from the reactions shown below? Hsco-s-OCH3 large excess) NaOH нон H,0 но ОН "ОН (a and B) 4. Predict the major product of the following reaction. CHNNH 3 equivalents) но CHCH2OH Heat он CH2OH Draw the Haworth projection for chair conformation of a-D-Glucopyranose (shown below) CH2OH HO H OH OH
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Can someone explain the mechanisms + products for these
reactions?
1. (3p) Draw the mechanism and the expected reaction product for the following reaction: ? 2. (3p). Draw the mechanism and the expected Nucleophilic Substitution Reaction Product for the following reaction: ? OH
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2 HO HO Bry 1) Lithium Disopropylamide (LDA) 2) CIES o spomen 1) Lithium Disopropyl anide (LDA) OCH, CITOTT 1) OHI 2) CHI OH Give all possible products from the following mixed aldol reaction and show how they can be formed. Show the mechanism for the keto enol tautomerization of 2-propanone in both acid and in base.
can someone please explain the mechanism behind these two
reactions? thanks
26. What is the product of the following reaction? JOMO WOOT OM ОН o oo i > VI > Vio 008 OH OH он OH Onlwolle OH SOAL . IV A) 1 B) II C) III D IV was 27. What is the product of the following reaction? qu-how ibis volls) noile piwollo on looser YOH 1. SOCI 2. MeOH HO ОMe CI OSCI OME OME YOH2. SO A)...
CHEM 3020 Practice exam 3 Give the major organic product for the following reactions: R0, H.2 HO HO Bry 1) Lithium Disopropylamide (LDA) 2) CIES o spomen 1) Lithium Disopropyl anide (LDA) OCH, CITOTT 1) OHI 2) CHI OH Give all possible products from the following mixed aldol reaction and show how they can be formed. Show the mechanism for the keto enol tautomerization of 2-propanone in both acid and in base.
1. Consider the following two reactions, only one of which will
work as shown:
a) What is the stereochemical relationship between starting
material A and B?
b) Draw the mechanism for the reaction to convert the starting
material into the product. You can use either starting material A
or B to show the mechanism.
c) Draw the two chair forms for starting material A and circle
the more stable chair form. Explain why the one you circled is more
stable....
1. Give the structure of the product(s) for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points) 50% H2SO4 50% H20 1. BH3, THF 2. H2O2/KOH CH3COOH ry condon YY PEO 1. 03 2. Zn/H2O 2. Give the syn or anti addition products for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points total) Hz/Pt 1 point 1 point Hypt DBk Det ook o BryH2O 1....
1. The chiral compound in the center of the diagram below can undergo three different reactions. Fill in product structures in each box and give their stereochemistry. For the Sul reaction the two products are enantiomers of each other. For the E1 reaction products, two are diastereomers of each other and the third is a constitutional isomer of the other two. H30 NaOH H20 E1 E2 Sn1 NaOH SN2 2. Draw the structure of the major product of the reaction...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s) would accomplish the following? Show mechanism. R-CH2-NH2 R-C-NH2 3. What would result from the reactions shown below? Hsco-s-OCH3 large excess) NaOH нон H,0 но ОН "ОН (a and B) 4. Predict the major product of the following reaction. CHNNH 3 equivalents) но CHCH2OH Heat он CH2OH Draw the Haworth projection for chair conformation of a-D-Glucopyranose (shown below) CH2OH HO H OH OH
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