Predict if the given compounds below undergo SN2 or SN1 in presence of NaI / acetone and AgNO3 / ethanol medium. (1-bromobutane, 1-chlorobutane, 2-bromobutane, 2-chlorobutane, 2-chloro-2methylpropane, 2-bromo-2-methylpropane)
Predict if the given compounds below undergo SN2 or SN1 in presence of NaI / acetone...
For each compound listed below, predict the dominant mechanism for each reactant (SN1 and/or SN2). The two test reagent mixtures you will be using are sodium iodide in acetone and silver nitrate in ethanol.Note: a compound may not react at all or react under both mechanisms. If both mechanisms are possible, one is usually dominant. Indicate that where applicable. Reactant KI/acetone AgNO3/ethanol 1 bromobenzene 2 bromocyclopentane 3 bromocyclohexane 4 2-bromobutane 5 2-chlorobutane 6 1-chloropropan-2-one 7 1-chlorobutane 8 2-chloro-2-methylpropane 9 1-chloromethylbenzene
Write the potential sn2 and sn1 reaction as well as the potential the sn2 and sn1 mechanism. Then state which reaction(s) will occur if any, and why? with naI/acetone and with AgNO3/ethanol F) chlorobenzene G) 1-bromobutane H) 2-bromobutane
Rank the compounds from most reactive to least reactive under conditions of both SN1 and SN2. Experiment CI Br 1-chlorobutane 1-bromobutane 1-chloro-2-methylpropane B ta Br 2-bromobutane 2-chloro-2-methylpropane 1-chloro-2-butene 2-chlorobutane
-Compare rates of S2 and SN1 product formation for 5 halides (1-chlorobutane, 1- bromobutane, 2-bromobutane, 2-chloro-2-methylpropane, and chlorobenzene) -Arrange 5 compounds in order of decreasing reactivity toward (a) Nal in acetone, and (b) AgNO3 in ethanol reagents. [Use structural formula for halides]
For each compound listed below, predict the dominant mechanism for each reactant (SN1 and/or SN2). The test reagent mixture you will be using is silver nitrate (AgNO3) in ethanol. Note: a compound may not react at all or react under both mechanisms. If both mechanisms are possible, one is usually dominant. Indicate that where applicable. 1. bromobenzene 2. bromocylopentane 3. bromocyclohexane 4. 2-bromobutane 5. 2-chlorobutane 6. 1-chloroporpan2-one 7. 1-chlorobutane 8. 2-chloro-2-mehtylpropane 9. 1-chloromethylbenzene
Product Structure in NaI, acetone of the following (Note: it should follow an SN2 mechanism). Dont need the entire mechanism just the final product structure please. Thank you. 2-chlorobutane 2-bromobutane 1-chlorobutane 1-bromobutane 2-chloro-2-methyl propane Crotyl chloride Benzyl chloride Bromobenzene Bromocyclohexane Bromocyclopentane
1. Compare the reactivity of primary alkyl halides in part 1 (SN2) of this experiment to the reactivity of primary alkyl halides today. What conclusions, if any, can you make about the reactivity of these molecules under these different conditions? Use specific data to make your point. 2. Compare the reactivity of secondary alkyl halides in part 1 (SN2) of this experiment to the reactivity of secondary alkyl halides today. What conclusions, if any, can you make about the reactivity...
Please HELP!! Table 1: Alkyl Halides in NaI Substrate Time for Precipitate to Form Heated? Temp (℃) Time (min) Heat Relative Ranking (#1-#6) Predicted Relative Ranking (#1-#6) Bromobenzene No reaction Yes 44 10 6 6 2-Chlorobutane No reaction Yes 44 10 5 4 1-Chlorobutane 13 min Yes 44 8 4 3 Benzyl Chloride 2min 30 sec No --- --- 2 1 1-Chloro-2-butene 1 second No --- --- 1 5 1-Bromobutane 5 min No --- --- 3 2 1. Why did...
State whether the reaction mechanism prefers SN1 or SN2. Once sorted, rank in order from most reactive to least reactive. Experiment CI Br 1-chlorobutane 1-bromobutane 1-chloro-2-methylpropane B ta Br 2-bromobutane 2-chloro-2-methylpropane 1-chloro-2-butene 2-chlorobutane
Predict the substitution product(s) for each of the following reactions and mechanisms by which they are formed. If no reaction is expected, write no (a) (R)-2-bromobutane with sodium iodide in acetone (b) (R)-3-bromo-3-methylhexane with H20 (c) trans-1-bromo-2-ethylcyclopentane with potassium ethoxide in ethanol (d) trans-1-bromo-3-methylcyclopentane with Nal in acetone 5. For the following set of compounds, predict the order of reactivity with sodium iodide in acetone solution (list them in increasing order of reactivity). C. D. 2-bromobutane 1-chlorobutane 2-chloro-3-methylbutane 2-bromo-2-methylpropane 1-bromobutane...