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-Compare rates of S2 and SN1 product formation for 5 halides (1-chlorobutane, 1- bromobutane, 2-bromobutane, 2-chloro-2-methylpropane,...
Relative ranking (#1 - #7) Reason for ranking 1-chlorobutane 1-chloro-2-butene 2-chlorobutane 1-bromobutane 2-chloro-2-methylpropane bromobenzene benzyl chloride (2) What mechanism do you believe will be favored with AgNO3 in ethanol? What order of reactivity do you predict will be observed when each of the alkyl halides in Figure 1is reacted with AgNOs in ethanol? Complete a similar table as in question #1 for these reaction conditions. Write your prediction of the mechanism and the order of reactivity with AGNO3 in ethanol...
1. Compare the reactivity of primary alkyl halides in part 1 (SN2) of this experiment to the reactivity of primary alkyl halides today. What conclusions, if any, can you make about the reactivity of these molecules under these different conditions? Use specific data to make your point. 2. Compare the reactivity of secondary alkyl halides in part 1 (SN2) of this experiment to the reactivity of secondary alkyl halides today. What conclusions, if any, can you make about the reactivity...
Nucleophilic substitutions, mainly just need the arrangements, and the drawn out reaction equations CHEM 220L Laboratory Manual (S.A. Cummings & J.K. Mahoney) CHEM 220L Data Sheet: Nucleophilic Substitutions (SN1 and SN2) (6 points) Part 1. Enter the results of each test into the table below: Alkyl Halides 10, 2 or 3? SN2 (Nal/acetone) 1-chlorobutane 1-bromobutane 2-chlorobutane 2-bromobutane bromocyclohexane 2-chloro-2-methylpropane (t-butyl chloride) Crotyl chloride Benzyl chloride (a-chlorotoluene) Arrange the alkyl halides in order of reactivity (from most to least reactive) with...
For the Reactions that formed precipitates, what are the drawn out reaction equations with stereochemistry if applicable? Part 1. Enter the results of each test into the table below: 1°, 2° or 3°? Alkyl Halides 1-chlorobutane Sn2 (Nal/acetone) Precipitate formed 1-bromobutane Precipitate formed 2-chlorobutane No precipitate formed 2-bromobutane No precipitate formed bromocyclohexane No precipitate formed 2-chloro-2-methylpropane (t-butyl chloride) No precipitate formed Crotyl chloride No precipitate formed Benzyl chloride (a-chlorotoluene) No precipitate formed Arrange the alkyl halides in order of reactivity...
1. arrange Alkyl chlorides in theoretical order of reactivity in SN1 reaction 2. arrange Alkyl chlorides in theoretical order of reactivity in SN2 reaction a HC 1-Chlorobutane AgNO3+ Ethanol (SN1) Nal + Acetone SN2 CH3 H3C 2-Chlorobutane Br CH3 H3C 2-Bromobutane CH3 H2C- a CH3 t-butylchloride Benzylchloride Br Bromobenzene
Predict if the given compounds below undergo SN2 or SN1 in presence of NaI / acetone and AgNO3 / ethanol medium. (1-bromobutane, 1-chlorobutane, 2-bromobutane, 2-chlorobutane, 2-chloro-2methylpropane, 2-bromo-2-methylpropane)
1. These questions consider carbocation formation in SN1 reactions. a. Which should be more reactive in an Sn1 reaction, a primary alkyl halide or a secondary alkyl halide? b. Which reactions that you performed today compare ONLY the reactivity of primary and secondary alkyl halides and not any other effect? c. What were the reaction times for these reactions? d. Do the results of these reactions match what you would expect theoretically? e. In one or two sentences, summarize the...
1. arrange Alkyl bromides in theoretical order of reactivity in SN1 reaction 2. arrange Alkyl bromides in theoretical order of reactivity in SN2 reaction AgNO3+ Ethanol Yal H₂C (SN 1) 1-Chlorobutane Nal + Acetone SN2 CH3 H3C 2-Chlorobutane Br CH3 H3C 2-Bromobutane CH3 H2C- a CH3 t-butylchloride Benzylchloride Br Bromobenzene
In this exercise, you will use two reagent mixtures to test a variety of organic halides. The distinct differences in the factors affecting the SN2 and SN1 mechanisms make it possible to determine which mechanism is favored by a given compound. One reagent and solvent favors SN2 reactivity, the other SN1 reactivity. From the results of your tests, you will determine which mechanism, if either, is favored by a given compound. In your post-lab assignment, you will be required to...
Arrange the alkyl halides in order of reactivity (from most to least reactive) under both SN1 (silver nitrate/ethanol) and SN2 (sodium iodide/acetone) conditions: 1-bromobutane, 2-bromobutane, bromocyclohexane, 2-bromo-2-methylpropane, 1-bromoadamantane, benzyl bromide, and bromobrmzene.