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15-37 Indole is an aromatic heterocycle that has a benzere ring fused to a pyrrole ring....
1. Remdesivir is an antiviral drug that was developed as a treatment for the Ebola virus...
1. Remdesivir is an antiviral drug that was developed as a treatment for the Ebola virus and the Marburg virus. It is currently in clinical trials as a treatment for COVID-19. NH2 LON HOOH remdesivir The following questions are about the boxed portion of remdesivir, drawn below as its own molecule. a) Fill in the boxes about the hybridization and orbitals of this heterocycle. What is the hybridization of this N? o What orbital does this lone pair occupy? What...
The example is saying it's not aromatic but how come 18.11d is aromatic ? TIC, OR...
The example is saying it's not aromatic but how come 18.11d is
aromatic ?
TIC, OR ANTIAROMATIC 18.2 DETERMINING WHETHER A STRUCTURE IS AROMATIC, NONAROMATIC, OR ANTIAR LEARN the skill Determine whether the following anion is aromatic, nonaromatic, or antiaromatc SOLUTION To determine if this anion is aromatic, we must ask two questions 1. Does the compound contain a ring comprised of continuously overlapping p orbitaid 2. Is there a Huckel number of π electrons in the ring? p orbital?...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3 pts)
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp? hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Dec 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 3. Rank the reactivity of the compounds...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, o...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, on last year's quiz), substituents on the aromatic ring can further modify the reactivity. First, we will consider a phenyl amide with a para-acetyl substituent: CH, (a) What is the n-effect (resonance) of the para-acetyl substituent? How will that affect the reactivity of the other (amide) carbonyl in the molecule below (increase or decrease, compared to the same amide but with no p-...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Antanan ENon ordre Energy Bunding aromatic antiaromatic 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) nonovomatic...
2. What is the Hückel number of pi electrons for the molecule shown below? How many...
2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 16 Te 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sn2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts)
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation...
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation HaCrO4 toluene NaOE! 3. Hückel's criteria. Determine if the following compounds are aromatic or not. (2 pts) Yes or No? a. Is it cyclic? b. Does it have one 2p orbital on each atom of the ring? c. Is it planar, with a continuous overlap of 2p orbitals on the ring? d. Does it have (4n+2) electrons in the cyclic arrangement of 2p orbitals?...
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation...
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation H2Cro toluene NaOE 3. Hückel's criteria. Determine if the following compounds are aromatic or not. (2 pts) Yes or No? a. Is it cyclic? b. Does it have one 2p orbital on each atom of the ring? c. Is it planar, with a continuous overlap of 2p orbitals on the ring? d. Does it have (4n+2) * electrons in the cyclic arrangement of 2p...
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle...
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are spa hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or...
1. Remdesivir is an antiviral drug that was developed as a treatment for the Ebola virus and the Marburg virus. It is currently in clinical trials as a treatment for COVID-19. NH2 LON HOOH remdesivir The following questions are about the boxed portion of remdesivir, drawn below as its own molecule. a) Fill in the boxes about the hybridization and orbitals of this heterocycle. What is the hybridization of this N? o What orbital does this lone pair occupy? What...
The example is saying it's not aromatic but how come 18.11d is
aromatic ?
TIC, OR ANTIAROMATIC 18.2 DETERMINING WHETHER A STRUCTURE IS AROMATIC, NONAROMATIC, OR ANTIAR LEARN the skill Determine whether the following anion is aromatic, nonaromatic, or antiaromatc SOLUTION To determine if this anion is aromatic, we must ask two questions 1. Does the compound contain a ring comprised of continuously overlapping p orbitaid 2. Is there a Huckel number of π electrons in the ring? p orbital?...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3 pts)
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp? hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Dec 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 3. Rank the reactivity of the compounds...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, on last year's quiz), substituents on the aromatic ring can further modify the reactivity. First, we will consider a phenyl amide with a para-acetyl substituent: CH, (a) What is the n-effect (resonance) of the para-acetyl substituent? How will that affect the reactivity of the other (amide) carbonyl in the molecule below (increase or decrease, compared to the same amide but with no p-...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Antanan ENon ordre Energy Bunding aromatic antiaromatic 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) nonovomatic...
2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 16 Te 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sn2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts)
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation HaCrO4 toluene NaOE! 3. Hückel's criteria. Determine if the following compounds are aromatic or not. (2 pts) Yes or No? a. Is it cyclic? b. Does it have one 2p orbital on each atom of the ring? c. Is it planar, with a continuous overlap of 2p orbitals on the ring? d. Does it have (4n+2) electrons in the cyclic arrangement of 2p orbitals?...
Draw the major organic product formed in the following reactions. (1 pt each) CH Jones oxidation H2Cro toluene NaOE 3. Hückel's criteria. Determine if the following compounds are aromatic or not. (2 pts) Yes or No? a. Is it cyclic? b. Does it have one 2p orbital on each atom of the ring? c. Is it planar, with a continuous overlap of 2p orbitals on the ring? d. Does it have (4n+2) * electrons in the cyclic arrangement of 2p...
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are spa hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or...
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