Question

7 the following substitution reaction? Which is the major product of the follow CHOCHOH NaBr ? A) CH₂ CH₂ Br B) CH CH. Na c)
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Answer #1

19.

Correct option: E

Hydroxide (HO-) is a very poor leaving group. Br- is not able to substitute HO-. Hence, no product will form.

20.

Correct option: B

HBr will protonate the alcoholic OH group. As a result, water will leave the molecule to give a secondary carbocation. Then, hydride shift from the neighboring carbon will yield more stable tertiary carbocation. Br- will then attack the tertiary carbocation to give the product.

21.

Correct option: D

PBr3 reacts with alcohol to yield alkyl bromide. This reaction goes via SN2 mechanism. Hence, inversion of configuration at the stereocenter takes place.

22.

Correct option: A

The above reaction is a substitution reaction as it substitute OH with Br.

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