g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN -->...
Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminated and neutralized. a. Ethyl acetate NaOEVEtOH b. EtO C-CH2-CH2-CH2-CH2.CO2Et NaOEU/HOEt Ph-C(O)-CI c. (HaC).CH-CO2Et LDATHF + HO. d. Ethanal Ph-C(O)-H Ha0* (cat) e. Acetone + H2C O + Et NH f. Triethylamine HBr/H2O g. Ph-C(O)-NH2 + Br2 4 NaOH h. (H,C)2CH-C(CH)2 + N(CHs)s HO i.Ph-N2, Cl- CuCN- Na/E1OH HaO* (cat) j. cyclohexanone H2NOH Pd(OAc)2 (1 mole%) k. Ph- 4-O2N-CeHe-HC=CH2 Cul/Pd(PPhale L.HO-CH2-CH2-C-H1-CH-CH-(CH2),-CHg
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: -------> h. All trans-H2C=CH-CH=CH-OCH3 + H2C=CH-C(O)-H i. 1-bromo-3-chlorobenzene + HNO3/H2SO4 j. CsH5-CH=CH-CH3 + HBr/peroxides --------> H30* k. Ph-CH2-CH3 + KMnO./NaOH/A ----------> L. CoHs-CCl3 + Bry/FeBr ---------- H30* m. Ph-Br + KNH/-33 °C --------
e-g please e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/HC-COH H30* f. 4-nitro-1-chlorobenzene + NaOH ------> H20 g. Ph-CH2-CH2-CH2-CO2H + AICI: -------
Cl 5 OHO ON -NO2 6. POSHN FOH N(CH3)2 N2 3. 1. O2N N2 N2 4. OH NH2 2. NH2 02N pH 6 2 SO3 S03 Cl 5 OHO ON -NO2 6. POSHN FOH N(CH3)2 N2 3. 1. O2N N2 N2 4. OH NH2 2. NH2 02N pH 6 2 SO3 S03
14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH 14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH