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Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminate...
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN -->...
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
REVIEW SHEET FOR E2 IN CHEM 3153, OCTOBER 27, 2019 Draw the structure for the MAJOR...
REVIEW SHEET FOR E2 IN CHEM 3153, OCTOBER 27, 2019 Draw the structure for the MAJOR ORGANIC PRODUCT form each reaction. Assume the reactions have been terminated and neutralized. a. R-COR + DIBAL-H in hexane/-78 'C ------------ OR 1. CO2 b. Ph-Br + Mg/ether - -> 2. H,0* THE c. methyl butanoate + LDA -----> H.C-1 HO* H30* (cat) d. acetone + 2,4 (ON),C,Hy-NH-NH2 cyclohexanone e. PhyP-CH, I + PhLi/ether -- > H20 f. H.C-CH2-CH2-COH + BryP ------> -- n-Bu-Br...
Draw the structure of the FIRST MAJOR ORGANIC product/intermediate reaction. The generated in each se reactions...
Draw the structure of the FIRST MAJOR ORGANIC product/intermediate reaction. The generated in each se reactions occur in the text and in the problems at the end of the Chapters a. HsN HCI benzaldehyde] d. R-CO2H NaOH> e. Ph-NH2 + H3OICI> f. Ph-OH NaOH [aniline] [phenol C-H acetylene] h. HC NaH/liquid NH3 > + → 1. H2C-CH2 + HF m. H3C-OH + HI>
Give the structure of the major organic product(s) for each if the following reactions (or reaction...
Give the structure of the major organic product(s) for each if
the following reactions (or reaction sequences). Show all hydrogens
when they are critical, e.g. for aldehydes
3. Give the structure of the major organic product(s) for each of the following reactions (or reaction sequences). Show all hydrogens when they are critical, e.g. for aldehydes. Hot 3 O + Brz Born b. 2 8Hz WH2 + CH₃ CH-C-0H - So A 70 DE CH2 Br 0 Hz cat per B...
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry 1) PCC, CHCI...
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry 1) PCC, CHCI 2) Bry, acetic acid 3) KOBU, A 4) NaOEI, ETOH, P CO- 5) H30 workup 6) THF, H.COPPA HC CH2 O e .cat. Pd(OAc) cat. PPh. DMF, EIN 2) LDA, THF. -78 °C 3) Chichen H3O* workup 4) NaBH, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde (c) L AL SUO TESTE TO 1) cat. H2SO4. A лон 2) O3, CH, Cl, then (CH),...
II. Draw the structure for the major organic product of each of the following reactions. (7.5...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH...
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH O-S CH3 excess NH2 workup . You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after workup to neutralize acid. Include counter-ions, e.g., Nat, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner....
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
REVIEW SHEET FOR E2 IN CHEM 3153, OCTOBER 27, 2019 Draw the structure for the MAJOR ORGANIC PRODUCT form each reaction. Assume the reactions have been terminated and neutralized. a. R-COR + DIBAL-H in hexane/-78 'C ------------ OR 1. CO2 b. Ph-Br + Mg/ether - -> 2. H,0* THE c. methyl butanoate + LDA -----> H.C-1 HO* H30* (cat) d. acetone + 2,4 (ON),C,Hy-NH-NH2 cyclohexanone e. PhyP-CH, I + PhLi/ether -- > H20 f. H.C-CH2-CH2-COH + BryP ------> -- n-Bu-Br...
Draw the structure of the FIRST MAJOR ORGANIC product/intermediate reaction. The generated in each se reactions occur in the text and in the problems at the end of the Chapters a. HsN HCI benzaldehyde] d. R-CO2H NaOH> e. Ph-NH2 + H3OICI> f. Ph-OH NaOH [aniline] [phenol C-H acetylene] h. HC NaH/liquid NH3 > + → 1. H2C-CH2 + HF m. H3C-OH + HI>
Give the structure of the major organic product(s) for each if
the following reactions (or reaction sequences). Show all hydrogens
when they are critical, e.g. for aldehydes
3. Give the structure of the major organic product(s) for each of the following reactions (or reaction sequences). Show all hydrogens when they are critical, e.g. for aldehydes. Hot 3 O + Brz Born b. 2 8Hz WH2 + CH₃ CH-C-0H - So A 70 DE CH2 Br 0 Hz cat per B...
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry 1) PCC, CHCI 2) Bry, acetic acid 3) KOBU, A 4) NaOEI, ETOH, P CO- 5) H30 workup 6) THF, H.COPPA HC CH2 O e .cat. Pd(OAc) cat. PPh. DMF, EIN 2) LDA, THF. -78 °C 3) Chichen H3O* workup 4) NaBH, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde (c) L AL SUO TESTE TO 1) cat. H2SO4. A лон 2) O3, CH, Cl, then (CH),...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH O-S CH3 excess NH2 workup . You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after workup to neutralize acid. Include counter-ions, e.g., Nat, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner....
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