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REVIEW SHEET FOR E2 IN CHEM 3153, OCTOBER 27, 2019 Draw the structure for the MAJOR...
Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminate...
Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminated and neutralized. a. Ethyl acetate NaOEVEtOH b. EtO C-CH2-CH2-CH2-CH2.CO2Et NaOEU/HOEt Ph-C(O)-CI c. (HaC).CH-CO2Et LDATHF + HO. d. Ethanal Ph-C(O)-H Ha0* (cat) e. Acetone + H2C O + Et NH f. Triethylamine HBr/H2O g. Ph-C(O)-NH2 + Br2 4 NaOH h. (H,C)2CH-C(CH)2 + N(CHs)s HO i.Ph-N2, Cl- CuCN- Na/E1OH HaO* (cat) j. cyclohexanone H2NOH Pd(OAc)2 (1 mole%) k. Ph- 4-O2N-CeHe-HC=CH2 Cul/Pd(PPhale L.HO-CH2-CH2-C-H1-CH-CH-(CH2),-CHg
draw out structures or reagents Draw out either the structures or the reagents A-Q needed to...
draw out structures or reagents
Draw out either the structures or the reagents A-Q needed to complete the reaction roadmap below 1) CuLi(CH-CH(), 0 2) H.O 1) Mg 2) formaldehyde Br 3) H30 G H2C1 CH3 HyC N B 1)Bry(excess), NaOH 2)HCI PCC F PBr3 E NaOH A Р I 1) Dibal 2) H,O, CH Nz, ether HCI 1) TOSCI, pyridine 2) NaH SOCI J 1) NaBr 2) H30 H M 1) 2CH,MgBr 2) H,O, HCI HECHC=CH2 Acetic Acid NaOCH...
CHEM 241 Assignment 6 2. Provide the structure of the major products A, B, and C...
CHEM 241 Assignment 6
2. Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. OH EINH Croz, H2SO A Hicat. B H, (-H20) 2) H30* В B ~ Br. 1 с LE A H30C b) H O V 2EOH cat (H20) 1) Hg(OAC). THE 2) NBH OAC - OCCH c) 1) POCI Me DMF - 2) NaHCO, (aq) Ph, P=CHCOMe - A Pdic. H C No Mg в с но...
Please complete. Will rate 25. Predict the major organic product(s) for each reaction below. Note: some...
Please complete. Will rate
25. Predict the major organic product(s) for each reaction below. Note: some questions have multiple steps associated with them. (2 points each) a. O 1.Ph Culi CI 2. H20 1. CH3Li 2. H30* b. O NaBH4 OCHs CH3OH C. 1. PBr3 OH 2. NaCN 1. DIBAL-H 78 C H2SO4 OEt 2. H20 Pd(PPh3) Br FeBr3 B(OR)2
Enol fom Kets (om Provide the structure of the major products A, B, and C formed...
Enol fom Kets (om Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. 2 OH EtzNH H cat Br в 1) г 2) H,о* CrO3, H2SO Hао C A (-H2O) С- 2 2EIOH 1)Hg(OAc)2, THF A Но C H' cat (-H2O) 2) NaBH OAc O2CCHy он dk pEt &0- 1) POCI DMF Ph,P CHCO Me A Pd/C c) Me в C Hа 2) NaHCO3 (aq) Me CHa CHICO me CH...
3. Identify (draw the structure showing stereochemistry where required) ALL of the missing reactant, reagents, or...
3. Identify (draw the structure showing stereochemistry where required) ALL of the missing reactant, reagents, or major product to complete the following transformations. CH2l2, Zn(Cu) Br Biz excess H20 Тон Hz. Pd/C ether o - - HCI H2O NaOH H₂O Excess 1. Hg(OAc), H20 2. NaBH4 HBT CH,C12 Excess 1. BH, THF 2. H2O2, H20
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20"...
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20" ? mo Br НО. O II III Br Br ho IV A. I B. II C. III D. IV E. V 13. What would be the major product of the following reaction sequence? A. I B. II C. III D. IV E. V 2 i. LDA ii. CHEI De ci II I III IV V 14. Which of the following could be used to...
can you solve 7 and 8 please? 7. Propose structure(s) for the major organic product(s) of...
can you solve 7 and 8 please?
7. Propose structure(s) for the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. a. O CH3CCH3 + CH3CH2MgBr 1. ether 2. H30* b. -[O] CrO3 H20 OH C. CH3 + CH3CH2NH2 1º amine 8. Write the complete stepwise mechanism for the Grignard reaction shown below. Show all intermediate structures and all electron flow with arrows. OH C-CH2CH3 1. in ether CH3 CH3CH2MgBr 2. H, H2O O=0...
II. Draw the structure for the major organic product of each of the following reactions. (7.5...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
draw the major product 1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH...
draw the major product
1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH H.C. Brown. JACS, 1959, 81, 247, (05 yield) (ul CH.CH CH,CI CH.CH CH.CH In CHCI,/ CHCh 130 min OS V 467(80-86% yield) HO-B Bry/H, DMSO THO-Br B /H, DMSO Boy (eld" Bry/CH, OH - L Сн,он Cl/H, HỆ CHI 15 20 C. OS I 158 70-73 yield) CI/H, но с Bry/H,0 THOB] CI/H,O Bry/ -78 °C in CH, CI, 76h (934 yield) (kk) Cl/H20...
Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminated and neutralized. a. Ethyl acetate NaOEVEtOH b. EtO C-CH2-CH2-CH2-CH2.CO2Et NaOEU/HOEt Ph-C(O)-CI c. (HaC).CH-CO2Et LDATHF + HO. d. Ethanal Ph-C(O)-H Ha0* (cat) e. Acetone + H2C O + Et NH f. Triethylamine HBr/H2O g. Ph-C(O)-NH2 + Br2 4 NaOH h. (H,C)2CH-C(CH)2 + N(CHs)s HO i.Ph-N2, Cl- CuCN- Na/E1OH HaO* (cat) j. cyclohexanone H2NOH Pd(OAc)2 (1 mole%) k. Ph- 4-O2N-CeHe-HC=CH2 Cul/Pd(PPhale L.HO-CH2-CH2-C-H1-CH-CH-(CH2),-CHg
draw out structures or reagents
Draw out either the structures or the reagents A-Q needed to complete the reaction roadmap below 1) CuLi(CH-CH(), 0 2) H.O 1) Mg 2) formaldehyde Br 3) H30 G H2C1 CH3 HyC N B 1)Bry(excess), NaOH 2)HCI PCC F PBr3 E NaOH A Р I 1) Dibal 2) H,O, CH Nz, ether HCI 1) TOSCI, pyridine 2) NaH SOCI J 1) NaBr 2) H30 H M 1) 2CH,MgBr 2) H,O, HCI HECHC=CH2 Acetic Acid NaOCH...
CHEM 241 Assignment 6
2. Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. OH EINH Croz, H2SO A Hicat. B H, (-H20) 2) H30* В B ~ Br. 1 с LE A H30C b) H O V 2EOH cat (H20) 1) Hg(OAC). THE 2) NBH OAC - OCCH c) 1) POCI Me DMF - 2) NaHCO, (aq) Ph, P=CHCOMe - A Pdic. H C No Mg в с но...
Please complete. Will rate
25. Predict the major organic product(s) for each reaction below. Note: some questions have multiple steps associated with them. (2 points each) a. O 1.Ph Culi CI 2. H20 1. CH3Li 2. H30* b. O NaBH4 OCHs CH3OH C. 1. PBr3 OH 2. NaCN 1. DIBAL-H 78 C H2SO4 OEt 2. H20 Pd(PPh3) Br FeBr3 B(OR)2
Enol fom Kets (om Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. 2 OH EtzNH H cat Br в 1) г 2) H,о* CrO3, H2SO Hао C A (-H2O) С- 2 2EIOH 1)Hg(OAc)2, THF A Но C H' cat (-H2O) 2) NaBH OAc O2CCHy он dk pEt &0- 1) POCI DMF Ph,P CHCO Me A Pd/C c) Me в C Hа 2) NaHCO3 (aq) Me CHa CHICO me CH...
3. Identify (draw the structure showing stereochemistry where required) ALL of the missing reactant, reagents, or major product to complete the following transformations. CH2l2, Zn(Cu) Br Biz excess H20 Тон Hz. Pd/C ether o - - HCI H2O NaOH H₂O Excess 1. Hg(OAc), H20 2. NaBH4 HBT CH,C12 Excess 1. BH, THF 2. H2O2, H20
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20" ? mo Br НО. O II III Br Br ho IV A. I B. II C. III D. IV E. V 13. What would be the major product of the following reaction sequence? A. I B. II C. III D. IV E. V 2 i. LDA ii. CHEI De ci II I III IV V 14. Which of the following could be used to...
can you solve 7 and 8 please?
7. Propose structure(s) for the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. a. O CH3CCH3 + CH3CH2MgBr 1. ether 2. H30* b. -[O] CrO3 H20 OH C. CH3 + CH3CH2NH2 1º amine 8. Write the complete stepwise mechanism for the Grignard reaction shown below. Show all intermediate structures and all electron flow with arrows. OH C-CH2CH3 1. in ether CH3 CH3CH2MgBr 2. H, H2O O=0...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
draw the major product
1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH H.C. Brown. JACS, 1959, 81, 247, (05 yield) (ul CH.CH CH,CI CH.CH CH.CH In CHCI,/ CHCh 130 min OS V 467(80-86% yield) HO-B Bry/H, DMSO THO-Br B /H, DMSO Boy (eld" Bry/CH, OH - L Сн,он Cl/H, HỆ CHI 15 20 C. OS I 158 70-73 yield) CI/H, но с Bry/H,0 THOB] CI/H,O Bry/ -78 °C in CH, CI, 76h (934 yield) (kk) Cl/H20...
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