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You need to perform gravimetric analysis of a water sample in order to determine the amount of Ag present. List three aqueous

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Answer #1

(A) You have to use aqueous salt solution that reacts with Ag+ to form water insoluble precipitate.

Three such salt solution is:

1. NaCl solution

2. Na2 SO4 solution

3. Na2CO3 solution

(B) KNO3 forms water soluble AgNO3 which can't be obtained as precipitate. Hence KNO3 solution can't be used for gravimetric analysis.

(C) IF Ag salt is moderately soluble then some of Ag will appear as precipitate and some remains soluble in aqueous solution. Hence the amount of calculated Ag from the collected precipitate is less than actual value.

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