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102/5000 Complete the following reaction chains, not counting the stereoisomers formed in reactions:
Draw all stereoisomers formed in the reaction below.
2. Predict the products for the following reaction. Show stereoisomers formed and the mechanism of the reaction. H SO H.O
2. Predict the products for the following reaction. Show stereoisomers formed and the mechanism of the reaction. H.SO HO
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
Reference Consider the following reactions. Indicate how many stereoisomers you expect to be formed in the reaction, and specify what kind of isomers you expect. + Cl2 in H20 Number of isomers Type of somer
7. Complete the following reactions. Be sure to account for regioselectivity and stereoisomers. Write NR if no reaction is expected. (10 pt) Δ Δ +
2. Predict the products for the following reaction. Show stereoisomers formed and me mechanism of the reaction. 3. Predict the major product for each of the following reactions. Show the mechanis indicate stereochemistry where appropriate. BR be H.0 Tommi OH 11)
1. Draw the product(s) of the following reactions. Include stereochemistry when relevant. If stereoisomers are formed then draw out and label the relationship between your structures. Ph-N3 40°C HN-NH2 SACOMe 150 °C d. CO2CH3 210 °C нсОСН3 In hv ZI 160 °C OBn 85 °C OBn OBno= o 1 equiv. CI K2CO3 heat PhCH N= H 1. LDA (1 equiv.) P 2. Ph Ph 3. aqueous work-up heat EtOH NaOEt 2. Draw the mechanism for the following transformations. I Н...
8. Complete the following reactions with major product(s). Be sure to account for regioselectivity and stereoisomers. Write NR if no reaction is expected. (20 pt) AcOH, A - Br Br KH, DMF Me OH, A x CH3O, CH3OH Br