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Complete the following reaction sequences (including if stereoisomers (if any):
provide the products for each reaction including any relevant
stereochemistry. if a pair of stereoisomers is produced, draw one
and write + enantiomer ir + diastereomer, whichever is
relevant.
1. CH, MgBr 2. H₂0" (Ph),Culi (R)-CBS + light 1. DIBAH 2. H, ... 1. Mgether 2. CO 3. H,0
Draw the product(s), including stereoisomers, of the reaction below. Do not duplicate any answers. All reactions have a product. m-CPBA Tsci pyridine OH HI ОН 1. SOCIE. pyridine 2. Ко"Ви OH 1. SOCl2, pyridine 2. KO'Bu O HI
The instructions say: Complete the following reaction sequences
by drawing the major products or the reagents necessary to make
them. Be sure to include stereochemistry when appropriate.
reagents necessary to make them. Be sure to include stereochemistry when appropriate H2 (8) H2o Lindlar's cat Br 04 NaOEt b. CH2Cl2 DMSO NaNH Br NaOEt d. EtOH Br2 KOr-Bu MeOH HOr-Bu OH H2 (g) Pd /C
Complete the following reaction sequences by drawing the major
products or the reagents necessary to make them. Be sure to include
stereochemistry when appropriate.
1. (48 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropriate. HBr Benzene FeBr3 HO NaH DMF hv NaNH2 2 BnBr CH2Cl2 Benzene Br2 cat. H+ H2o Ph NaOH NBS H Br H20 hv
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4. (10 pts) Draw all possible products for the following reaction including stereoisomers. Note that the addition occurs through a "syn" mechanism. Is the product solution optically active (yes or no)? 1. BAHATHF 2. NaOH, HO (8 pts) Provide a complete mechanism for the reaction below and include lone-pairs of electrons and formal charges. Show all products formed including stereoisomers. Is the product solution optically active (yes or no)? Bras 11. (8 pts) Draw all four regiochemical...
Draw a structural formula for the product of this Diels-Alder reaction, including all stereoisomers of the product
References Draw a structural formula for the product of this Diels-Alder reaction, including all stereoisomers of the product. CHO CHO Use the wedge/hash bond tools to indicate stereochemistry where it exists. If a group is achiral, do not use wedged or hashed bonds on it. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
(32 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropriate. 2. NaOEt 'Br DMF EtOH, Δ Br 2 Cl Cl Cl HO Br Cl Cl H2 (8) Lindlar's cat.