Solution
Given that
3. (6) Complete the following reactions by drawing the structure of the principal organic product. он...
3. (5) Complete the following reactions by drawing the structure of the principal organic product formed Ph Cl trace NaOH EtOH heat Br,Zn, THF Ph H dil dil Hyo at H,SO beatTHF (workup) HgClh, H20 CaCO3, CHCN BuLi, THFH NaH, OCHs dil H O heat (1.0equv) (workup) 0 NaOEt trace NaOEt EtOH, heat EtOH
complete the followimg reactions by drawing the
principal organic product.
k. 25°C H20 OH Ag2O
Draw the structure of the major organic product of these reactions. Do not write mechanisms. НО. (h) OH + NADH two organic products; write both NH NHA KOH (i) H H20 heat N 1 H (1) O= 오 HT CH3 H, C12H160 (i) (2) PhCH CH Br (3) H20*
Draw the structure of the major principal organic product in
each of the following reactions. Include correct relative
stereochemistry. You don’t need to draw both enantiomers.
NaOH BH3 THF H202, H20 HgSO4 H2SO4 H20 heat 1 mol Br2 LiBr HOAc
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
3. Complete each of the following reactions. Draw the structure of the organic product or products in the space provided. Show stereochemistry if appropriate. (3 points each) SN2 reaction (a) (CH3)CHCH2Cl + NaCN Sn1 reaction (b) (CH3)CHCH,CI + NaCN (C) M Sn2 reaction ¢l + NaOH - ACH. E1 reaction (d) (CH3)3CCH,OH + HCI major product Ez reaction Cl + NaOH - LCH3 н Ereaction Cl + H20
Complete each equation below by drawing the structure of the
organic reactant(s) or product(s) that best fit(s) the reaction
depicted. Be sure to show stereochemistry correctly, where
appropriate.
1) NaOEt, EOH 1) NaOH, H2O 2) HCI, H,0 Br 3) heat 3) HCUH, 1) HCI но он 1) Mg HOI, HO HOY Dean-Stark Trap 1. NaOEt 1. SOCI 2. EtOH 3.0.5 eq. NaOEt 2 HyN 4.HO (3 and 4 are a Major Reaction from Ch. 19)
Complete the following reaction with the major
product
Reactions: complete the following reaction with the major product HBr он 1- OH POCl3 pyridine 2- H2SO4 OH 3- Hl 4- H20 H3PO4 5- Cl2 H20 7- 1) BH2-THF 2) H202, KOH 8- 2) 9- 1) BH3-THF 10- DLL 10- Date: G# : 12, and 13- Br H20 но 2) NaH 14, and 15- ) NaOH i NaOH 2 dil H.0 3) PBr 3)HBr F6 FZ F8
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...