Homework Answers
Oxidation with periodate
Periodate is a strong oxidation agent. Periodate oxidation agent with vicinal (adjacent) diol gives cleaved two carbonyl compound (aldehyde or ketone). This reaction is very useful for constitutional analysis of sugars.
The given compounds have a hydroxymethyl group adjacent to a carbonyl function. So oxidative cleavage gives formaldehyde and acid. Further this product undergoes oxidative cleavage gives carbon dioxide and acetaldehyde.
Add Answer to:
give the organic products of this peroxide oxidation
D-ribose 3. Give the organic products of this...
Give the organic products, with the CORRECT REGIOCHEMISTRY AND STEREOCHEMISTRY, when appropriate. !!! CH3 -C CH-CH...
Give the organic products, with the CORRECT REGIOCHEMISTRY AND
STEREOCHEMISTRY, when appropriate. !!!
CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate....
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. CH3 HCC=CH-CH2 + HI CH,OOCH -C=CH-CH2CH3 + HBr – Pd + D CH3 H20 H2O + HC-C=CH-CH2CH3 1) (BH3)2, THF 2) H,02, OH CH CH,CO2H H30* CH3 CH3 CHCI,/KOH H3C
Give the organic products: Sive the organic product. (Hint H20 is a byproduct). + 2 CH20-H...
Give the organic products:
Sive the organic product. (Hint H20 is a byproduct). + 2 CH20-H CH: A E OCH3 с но. Осня p CH40 осна OCH 3 Or Ос OD Give the organic product: 10 MgCl H (aq) 8. . он HO Give the organ product H(aq) CH2Li We were unable to transcribe this image
Draw the organic product (if any) expected from each of the following oxidation reactions if only...
Draw the organic product (if any) expected from each of the following oxidation reactions if only a single oxidation occurs: CH3 -CH2-OH a) H3C 0 + H2O CH3 CHE HOCH-CH-CH3 + H2O CH Hint Previous Give Up & View Solution Check Answer Next Exit
organic chemistry help! 1) for each reaction give the expected product 2) consider the conjugate bases,...
organic chemistry help!
1) for each reaction give the expected product
2) consider the conjugate bases, then arrange in order of
weakest to strongest
1. For each reaction give the expected product. 1. N(CH3)3 2. CICH,CH(CH3)2 CH3MgBr a) HO 1. KMnO4 2.SOCI2 d) CH 1. NaCN, DMSO (solvent) 2. LiAIHA 3. H₂O 2. Consider the conjugate bases of each of the following weak acids, then arrange the acids in order of weakest to strongest CI OH он OH
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D)...
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D) i A) A B) B C)D DC 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH H.C CH3 H H .C CH3 A) LiAlH, followed by H,SO,/heat B) O, followed by (CH3)2S C) PCC/CH,Cl, followed by HIO D) NaBH,/methanol followed by HIO B) B C)C D) D A A
4. Complete the Ruff degradation scheme for D-ribose. Сно Н -ОН Н. Он Н OH CH-он...
4. Complete the Ruff degradation scheme for D-ribose. Сно Н -ОН Н. Он Н OH CH-он D-Ribose
Write the structures of the organic products formed in the following oxidation reactions: d) (4 pts)...
Write the structures of the organic products formed in the
following oxidation reactions:
d) (4 pts) Write the structures of the organic products formed in the following oxidation reactions: KMnO4 HO, pH <7 PCC Хон Рcc . H2Cr04 OH PCC
1. Rewrite the completed reaction with the products formed. 2. Name the organic products formed. a)...
1. Rewrite the completed reaction with the products formed.
2. Name the organic products formed.
a) H-C + CH₃-CH ₂ OH H heat *** + CH3 CH 0 1-0-CH3 + NaOH heat CH₃ -C-O-CH₃ MUL + Hao o Il 6) CH₂ - CH2 - C-OH + NaOH -
Give the major organic product for the following reaction with explanation please! Give the major organic...
Give the major organic product for the following reaction with
explanation please!
Give the major organic product for the following reaction. CHO НО -Н -ОН н+ I I I -ОН CH3OH • -ОН CH, OH сн,он HO Home НО ОН CH,OH -ООMe НО Онон Сн,он НО OMe Онон CH OH -ООMe HO НО ОН There is no reaction under these conditions or the correct product is not listed here.
Give the organic products, with the CORRECT REGIOCHEMISTRY AND
STEREOCHEMISTRY, when appropriate. !!!
CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. CH3 HCC=CH-CH2 + HI CH,OOCH -C=CH-CH2CH3 + HBr – Pd + D CH3 H20 H2O + HC-C=CH-CH2CH3 1) (BH3)2, THF 2) H,02, OH CH CH,CO2H H30* CH3 CH3 CHCI,/KOH H3C
Give the organic products:
Sive the organic product. (Hint H20 is a byproduct). + 2 CH20-H CH: A E OCH3 с но. Осня p CH40 осна OCH 3 Or Ос OD Give the organic product: 10 MgCl H (aq) 8. . он HO Give the organ product H(aq) CH2Li We were unable to transcribe this image
Draw the organic product (if any) expected from each of the following oxidation reactions if only a single oxidation occurs: CH3 -CH2-OH a) H3C 0 + H2O CH3 CHE HOCH-CH-CH3 + H2O CH Hint Previous Give Up & View Solution Check Answer Next Exit
organic chemistry help!
1) for each reaction give the expected product
2) consider the conjugate bases, then arrange in order of
weakest to strongest
1. For each reaction give the expected product. 1. N(CH3)3 2. CICH,CH(CH3)2 CH3MgBr a) HO 1. KMnO4 2.SOCI2 d) CH 1. NaCN, DMSO (solvent) 2. LiAIHA 3. H₂O 2. Consider the conjugate bases of each of the following weak acids, then arrange the acids in order of weakest to strongest CI OH он OH
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D) i A) A B) B C)D DC 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH H.C CH3 H H .C CH3 A) LiAlH, followed by H,SO,/heat B) O, followed by (CH3)2S C) PCC/CH,Cl, followed by HIO D) NaBH,/methanol followed by HIO B) B C)C D) D A A
4. Complete the Ruff degradation scheme for D-ribose. Сно Н -ОН Н. Он Н OH CH-он D-Ribose
Write the structures of the organic products formed in the
following oxidation reactions:
d) (4 pts) Write the structures of the organic products formed in the following oxidation reactions: KMnO4 HO, pH <7 PCC Хон Рcc . H2Cr04 OH PCC
1. Rewrite the completed reaction with the products formed.
2. Name the organic products formed.
a) H-C + CH₃-CH ₂ OH H heat *** + CH3 CH 0 1-0-CH3 + NaOH heat CH₃ -C-O-CH₃ MUL + Hao o Il 6) CH₂ - CH2 - C-OH + NaOH -
Give the major organic product for the following reaction with
explanation please!
Give the major organic product for the following reaction. CHO НО -Н -ОН н+ I I I -ОН CH3OH • -ОН CH, OH сн,он HO Home НО ОН CH,OH -ООMe НО Онон Сн,он НО OMe Онон CH OH -ООMe HO НО ОН There is no reaction under these conditions or the correct product is not listed here.
Most questions answered within 3 hours.
-
Suppose that you know that in the population of full-time
employees in the United States, the...
asked 4 minutes ago -
This experiment was designed originally to sample various meat and carcass quality
aspects of Ontario pigs...
asked 4 minutes ago -
) Raw materials are studied for contamination. Suppose that
the number of particles of contamination per...
asked 19 minutes ago -
After running a regression analysis we calculated an F test and
the significance level was 0.15....
asked 14 minutes ago -
----Can someone please help me solve this one using JAVA
----I thank you in advance
Create...
asked 19 minutes ago -
1. What force primarily attracts the potassium ion to
the nitrate ion?
a. London forces...
asked 21 minutes ago -
What are the negative effects of abruptly stopping the use of
all fossil fuels? Give at...
asked 28 minutes ago -
Given that many conflict are the result of different parties having
different interests, is it possible...
asked 32 minutes ago -
A 750 g block can slide uniformly along the horizontal track
when a string attached to...
asked 36 minutes ago -
In 2017, Juan entered into a contract to write a book. The
publisher advanced Juan $50,000,...
asked 49 minutes ago -
Determine the number of kinds of protons in each molecule (w/
respect to NMR spectroscopy). Drawing...
asked 59 minutes ago -
A jeweler whose near point is 68 cm from his eye uses a
magnifying glass as...
asked 57 minutes ago