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Total Marks 53 Q1. True / False 1. Tertiary hydrogen is more reactive than secondary hydrogen towards chlorination. 2. Tertiary alcohol is less reactive towards HX than secondary alcohol. 3. Loss of electron density by carbon is called reduction. 4. SN2 is a twostep reaction. 5. In SN2 the stereochemistry at C is not inverted. 6. Smaller activation energy makes the reaction slow. 7. Bulky substrate favors the rate of SN? reaction. 8. Neutral nucleophiles are more favorable for SN reactions. 9. Strong bases make good leaving groups in SN2 reactions. 10. SN1 is a multistep reaction. 11. SN1 reactions are carried under acidic conditions. 12. SN1 reactions yield racemic mixture. 13. In E2 C-H and C-X bond breaking occur simultancously. (Marks 13) (Marks 12) Fill in the blanks 1. The common name of Alkylmagnesium halide (RMgX) is 2. The carbon-magnesium bond in Grignards reagent is polarized (C being more Q2. electronegative than Mg), this makes C in Grignards reagent 3. Alkyl halides react with lithium and copper metals to form LiR2Cu called 4. The .and 5. SN reactions occur through a intermediate solvents favor SN2 reactions
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