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An ammonium ion selective electrode exhibits interference from lithium ions with a selectivity coefficient of 0.2....
The selectivity coefficient, KL.H' for a Li + ion selective electrode is 4 × 104, when...
The selectivity coefficient, KL.H' for a Li + ion selective electrode is 4 × 104, when the electrode is placed in 3.44 × 10-4 mol L-1 Li+ solution at pH 7.2, the potential is -0.333 V versus a saturated calomel electrode. What would be the potential if the pH were lowered to 1.1 and the ionic strength was kept constant?
7. (10 points) a) The selectivity coefficient for a Bromide ion-selective electrode is on 0.15. What...
7. (10 points) a) The selectivity coefficient for a Bromide ion-selective electrode is on 0.15. What will the change in the electrode potential be for a 1.4 x 10" M Br" at pH 5.5 if the pH is raised to pH 11.0? b) A PH probe is calibrated against pH 4 and pH 7 buffers. For pH 4 buffer, E = 200 mV and for pH 7 buffer, E = 23 mV. If the potential for an unknown solution is...
A lithium ion-selective electrode gave the potentials given in the table below for the following standard...
A lithium ion-selective electrode gave the potentials given in the table below for the following standard solutions of LiCl and two samples of unknown concentration Solution ([Li+]/M) Potential vs. SCE, mV 0.100 M +1.0 0.050 M -30.0 0.010 M -60.0 0.001 M -138.0 Unknown 1 -48.5 Unknown 2 -75.3 Draw a calibration curve of the electrode potential versus log[Li+] and determine if the electrode is displaying nernstain behaviour. Use a linear least squares procedure to determine the concentration of the...
The selectivity coefficient, KL.H' for a Li + ion selective electrode is 4 × 104, when the electrode is placed in 3.44 × 10-4 mol L-1 Li+ solution at pH 7.2, the potential is -0.333 V versus a saturated calomel electrode. What would be the potential if the pH were lowered to 1.1 and the ionic strength was kept constant?
7. (10 points) a) The selectivity coefficient for a Bromide ion-selective electrode is on 0.15. What will the change in the electrode potential be for a 1.4 x 10" M Br" at pH 5.5 if the pH is raised to pH 11.0? b) A PH probe is calibrated against pH 4 and pH 7 buffers. For pH 4 buffer, E = 200 mV and for pH 7 buffer, E = 23 mV. If the potential for an unknown solution is...
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