Question

Which of the following reactions would you predict to have the largest orientation factor? A) H(g)...


Which of the following reactions would you predict to have the largest orientation factor?
A) H(g) + Cl(g) → HCl(g) B) NOF(g) + NOF(g) → 2NO(g) + F2(g)
C) Br2(g) + H2C=CH2(g) → H2BrC-CBrH2(g) D) NH3(g) + BCl3(g) → H3N-BCl3(g)

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Answer #1

The correct answer is an option A, i.e.H(g) + Cl(g) → HCl(g)

Explanation: The orientation factor represents the fraction of molecular collisions with the orientation that allows the reaction to occur.

In the case of option A gaseous hydrogen atoms loose electrons to form H+, gaseous chlorine atoms gain electrons to form Cl- ions. In this reaction the only one possibility is the collision between H+ ions and Cl- ions to generate HCl gas. This is how the orientation factor is the largest in this reaction.

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