Draw the π-bonding MOs, in order of increasing energy, for the cyclic, aromatic, heptagonal cycloheptatrienylium cation C7H7+ and for the cyclic, aromatic, octagonal cyclooctatetraene dianion C8H82–.
Draw the π-bonding MOs, in order of increasing energy, for the cyclic, aromatic, heptagonal cycloheptatrienylium cation...
Antibonding MOS 3. The energy diagram (right) depicts the molecular orbitals for the pi electrons in a molecule with a cyclic, fully-conjugated pi system. Would you expect the molecule to be unusually stable or unusually unstable? Why? Explain in 1-2 sentences. (2 pts) Energy - ----Nonbonding MOs y Bonding MOs
please answer them fast
4 a) Shows the is stmturobezeme with abndingboding and nodes? Cy b) Number of nodes increases as the MOs increases in energy, Is it True/False-Explain? (2) 5 a) Draw all the possible resonance structure of cyclopentadienyl cation? (2) b) Is it aromatic or antiaromatic and why? (2) 6. a) Mixed acid nitration of Chlorobenzene 64% p-nitro product will form-explain? (2) will give only 1% m-nitro product whereas about vating groups are usually stronger directors than deactivating...
3. The trihydrogen cation, H3, has been experimentally observed, but its geometry is the subject of some controversy. The two most commonly proposed structures are linear or cyclic, as shown in the figure here: a. Construct an MO diagram for linear H3. Use the D2h point group to identify the symmetry of each atomic orbital, group orbital, and molecular orbital. Include a sketch of each MO in your diagram. b. Construct a modified MO diagram for cyclic H3t. Use the...
Rank the following nitrogen-containing aromatic molecules in order
of increasing basicity.
Rank the following compounds in order of increasing reactivity in electrophilic aromatic substitution.
Rank the compounds below in order of increasing rate of
electrophilic aromatic nitration.
CH3 0CH:
Rank the following isomers in order of increasing heat of formation. Incorrect. The aromatic compound is the most stable in this group, so it has the lowest heat of formation.
5) Which sequence correctly ranks the following aromatic rings
in order of increasing rate of reactivity in an electrophilic
aromatic substitution reaction?
6) Show how you would perform the following synthesis.
9) Which sequence ranks the following carbonyl compounds in
order of increasing rate (slowest to fastest) of nucleophilic
addition?
10) What would be the product for the following
reaction?
5) Which sequence correct electrophilic aromatic substitution reaction? tly ranks the following aromatic rings in order of increasing rate of...
order in increasing energy
List these electron subshells in order of increasing energy. 3p, 3d, 4s, 4p Note for advanced students: you may assume these subshells are all in an atom with many electrons, not a hydrogen atom.
Rank the following compounds in order of increasing reactivity
for electrophilic aromatic substitution. Explain your
reasoning.