1.)
By snell's law,
n1*sin(x1) = n2*sin(x2)
here, n1 = refractive index of air = 1
x1 = angle of incidence = 23 deg
n2 = refractive index of water = 1.33
x2 = angle of refraction in water = ??
So,
1*sin(23 deg) = 1.33*sin(x2)
x2 = arcsin[sin(23 deg)/1.33]
x2 = 17.08 deg
2.)
Since when total internal reflection occurs then
angle of refraction is equals to 90 deg
So, by snell's law,
n1*sin(x1) = n2*sin(90 deg)
here, n1 = 1.5 ; n2 = 1.4
x1 = critical angle = ??
So, 1.5*sin(x1) = 1.4*1
sin(x1) = 1.4/1.5
x1 = arcsin(1.4/1.5)
x1 = 68.96 deg
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