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6. (14.100 from the text) Considex the following reaction between mercury (I) chloride and oxalate ion....
Consider the reaction: 2 HgCl2 (aq) + C2O42-(aq) 2 Cl-(aq) + 2 CO2 (g) + Hg2Cl2(s) The initial rate of this reaction was determined for several concentrations of mercury (II) chloride and oxalate io...
Consider the reaction: 2 HgCl2 (aq) + C2O42-(aq) 2 Cl-(aq) + 2 CO2 (g) + Hg2Cl2(s) The initial rate of this reaction was determined for several concentrations of mercury (II) chloride and oxalate ion and the following rate data was obtained: Experiment HgCl2 (aq) ( mol/L) C2O42-(aq) (mol/L) Rate (mol/L-s) 1 0.164 0.15 0.000032 2 0.164 0.45 0.00029 3 0.082 0.45 0.00014 4 0.246 0.15 0.000048 What is the rate law for the reaction? What is the value of...
57. In a kinetic study of the reaction shown below, the following data were obtained for...
57. In a kinetic study of the reaction shown below, the following data were obtained for the initial rates of Initial Rate of Reaction Initial Concentrations 3.2 x 103 M's 2.9% 104 MS 14x 10 M's 4.8 x 10 M's (a) Determine the order with respect to HgClh algebraically (show your work to receive full credit) Exp. 1 0.164 M Exp. 2 0.164 M Exp. 3 0.082 M Exp. 4 0.246 M 0.15 M 0.45 M 0.45 M 0.15 M...
i need B & C Consider the following reaction between mercury(II) chloride and oxalate ion. 2...
i need B & C
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl_2(ag) + C_2O_4^2-(ag) rightarrow 2 Cl^- (aq) + 2 CO_2(g) + Hg_2Cl_2(s) The initial rate of this reaction was determined for several concentrations of HgCl_2 and C_2O_4^2-, and the following rate data were obtained for the rate of disappearance of C_2O_4^2-. a) What is the rate law for this reaction? (b) What is the value of the rate constant? (c) What is the reaction...
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl_2(ag) + C_2O_4^2-(ag) rightarrow 2...
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl_2(ag) + C_2O_4^2-(ag) rightarrow 2 Cl^- (aq) + 2 CO_2(g) + Hg_2Cl_2(s) The initial rate of this reaction was determined for several concentrations of HgCl_2 and C_2O_4^2-, and the following rate data were obtained for the rate of disappearance of C_2O_4^2-. a) What is the rate law for this reaction? (b) What is the value of the rate constant? (c) What is the reaction rate when the concentration of...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate lon: 2...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate lon: 2 HgCl, +0, 2 2 Cr + HgCl2 + 2 CO2 Experiment [HgCl2]. M 0.291 0.582 0.291 0.582 C20,21.M 0.297 0.297 0.594 0.594 Initial Rate, Ms1 2.64x10+ 5.29x10* 1.06x10- 2.12x10-2 Complete the rate law for this reaction in the box below, Use the form k[A][B]", where '1' is understood for morn and concentrations taken to the zero power do not appear. Don't enter 1 for...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2 HgCl2 + C2042-- 2 CI+ + Hg2Cl2 + 2 CO2 Experiment [HgCl2lo, M [C2042-1., M 1 10.202 0.245 2 0.404 0.245 Initial Rate, M s-1 1.19x10-4 2.39x10-4 4.75*10-4 9.51*10-4 3 10.202 0.489 14 0.404 0.489 Complete the rate law for this reaction in the box below. Use the form k[A]”[B]", where 'l' is understood for m or n and concentrations taken to the zero...
Rate Laws (Section)Consider the reaction of peroxydisulfate ion (S2O8 2-) with iodide ion (I - )...
Rate Laws (Section)Consider the reaction of peroxydisulfate ion (S2O8 2-) with iodide ion (I - ) in aqueous solution:S2O82 - (aq) + 3 I - (aq)→2 SO42 - (aq) + I3- (aq)At a particular temperature the initial rate of disappearance of S2O8 2 - varies with reactant concentrations in the following manner:Experiment[S2O82‑] (M)[I_] (M)Initial Rate (M/S)10.0180.0362.6 × 10-620.0270.0363.9 × 10-630.0360.0547.8 × 10-640.0500.0721.4 × 10-5(a) Determine the rate law for the reaction and state the units of the rate constant. (b)...
[14.38] Consider the reaction of peroxydisulfate ion (S208) with io- dide ion (I) in aqueous solution:...
[14.38] Consider the reaction of peroxydisulfate ion (S208) with io- dide ion (I) in aqueous solution: S20s (ag) +3I(ag)2 SO4 (ag) +I3 (aq) At a particular temperature the initial rate of disappearance of S2082 varies with reactant concentrations in the following manner Experiment [S208 ] (M UI M Initial Rate (M/s) 2 3 4 0.018 0.027 0.036 0.050 0.036 2.6 x 106 0.036 3.9 x 106 0.054 7.8 x 106 0.072 E4 105 (a) Determine the rate law for the...
5. The reaction of peroxydisulfate ion (S2O82−) with iodide ion (I−) is S2O82−(aq) + 3I−(aq) →...
5. The reaction of peroxydisulfate ion (S2O82−) with iodide ion (I−) is S2O82−(aq) + 3I−(aq) → 2SO42−(aq) + I3−(aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment [S2O82−](M) . [I−](M) . Initial Rate [M/s] 1 0.0300 0.0840 8.80 × 10−4 2 0.0300 0.0420 4.40 × 10−4 3 0.0600 0.0420 8.80 × 10−4 (a) Which of the following equations represents the rate law for this reaction? What is the...
just 18&19 The following questions refer to the reaction shown below: Initial Rate of Initial [A...
just 18&19
The following questions refer to the reaction shown below: Initial Rate of Initial [A (mol/L) 0.16 Initial [B] (mol/L) 0.15 Disappearance of A (mol/L s) Experiment 1 0.08 N 0.30 0.082 2 0.16 *2 0.08 0.30 0.30 3 17. What is the rate law for this reaction? Rate = k[A][B] a) Rate k[A][B] b) Rate = k[A][B]2 c) Rate k[A]IB]2 Rate = k[B] 93S1 What is the magnitude of the rate constant for the reaction? 18. 140 a)...
57. In a kinetic study of the reaction shown below, the following data were obtained for the initial rates of Initial Rate of Reaction Initial Concentrations 3.2 x 103 M's 2.9% 104 MS 14x 10 M's 4.8 x 10 M's (a) Determine the order with respect to HgClh algebraically (show your work to receive full credit) Exp. 1 0.164 M Exp. 2 0.164 M Exp. 3 0.082 M Exp. 4 0.246 M 0.15 M 0.45 M 0.45 M 0.15 M...
i need B & C
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl_2(ag) + C_2O_4^2-(ag) rightarrow 2 Cl^- (aq) + 2 CO_2(g) + Hg_2Cl_2(s) The initial rate of this reaction was determined for several concentrations of HgCl_2 and C_2O_4^2-, and the following rate data were obtained for the rate of disappearance of C_2O_4^2-. a) What is the rate law for this reaction? (b) What is the value of the rate constant? (c) What is the reaction...
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl_2(ag) + C_2O_4^2-(ag) rightarrow 2 Cl^- (aq) + 2 CO_2(g) + Hg_2Cl_2(s) The initial rate of this reaction was determined for several concentrations of HgCl_2 and C_2O_4^2-, and the following rate data were obtained for the rate of disappearance of C_2O_4^2-. a) What is the rate law for this reaction? (b) What is the value of the rate constant? (c) What is the reaction rate when the concentration of...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate lon: 2 HgCl, +0, 2 2 Cr + HgCl2 + 2 CO2 Experiment [HgCl2]. M 0.291 0.582 0.291 0.582 C20,21.M 0.297 0.297 0.594 0.594 Initial Rate, Ms1 2.64x10+ 5.29x10* 1.06x10- 2.12x10-2 Complete the rate law for this reaction in the box below, Use the form k[A][B]", where '1' is understood for morn and concentrations taken to the zero power do not appear. Don't enter 1 for...
The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2 HgCl2 + C2042-- 2 CI+ + Hg2Cl2 + 2 CO2 Experiment [HgCl2lo, M [C2042-1., M 1 10.202 0.245 2 0.404 0.245 Initial Rate, M s-1 1.19x10-4 2.39x10-4 4.75*10-4 9.51*10-4 3 10.202 0.489 14 0.404 0.489 Complete the rate law for this reaction in the box below. Use the form k[A]”[B]", where 'l' is understood for m or n and concentrations taken to the zero...
[14.38] Consider the reaction of peroxydisulfate ion (S208) with io- dide ion (I) in aqueous solution: S20s (ag) +3I(ag)2 SO4 (ag) +I3 (aq) At a particular temperature the initial rate of disappearance of S2082 varies with reactant concentrations in the following manner Experiment [S208 ] (M UI M Initial Rate (M/s) 2 3 4 0.018 0.027 0.036 0.050 0.036 2.6 x 106 0.036 3.9 x 106 0.054 7.8 x 106 0.072 E4 105 (a) Determine the rate law for the...
just 18&19
The following questions refer to the reaction shown below: Initial Rate of Initial [A (mol/L) 0.16 Initial [B] (mol/L) 0.15 Disappearance of A (mol/L s) Experiment 1 0.08 N 0.30 0.082 2 0.16 *2 0.08 0.30 0.30 3 17. What is the rate law for this reaction? Rate = k[A][B] a) Rate k[A][B] b) Rate = k[A][B]2 c) Rate k[A]IB]2 Rate = k[B] 93S1 What is the magnitude of the rate constant for the reaction? 18. 140 a)...
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