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For the cell Mg(s) I Mg2(aq) II Ag (aq) I Ag(s) which of the following statements are correct for the spontaneous reaction? 1

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Answer #1

from data table:

Eo(Mg2+/Mg(s)) = -2.37 V

Eo(Ag+/Ag(s)) = 0.80 V

As per given cell notation,

cathode is (Ag+/Ag(s))

anode is (Mg2+/Mg(s))

Eocell = Eocathode - Eoanode

= (0.80) - (-2.37)

= 3.17 V

Mg is converting to Mg2+ and is losing electron

So, electron from Mg to Ag

1 is correct as Mg is anode

2 is wrong as Ag is cathode

Mg is converting to Mg2+ and is losing electron

So, electron from Mg to Ag

3 is correct

4 is correct as calculated above

5 is wrong as oxidation occurs at anode and Mg is anode

Answer: C. 1, 3 & 4 only

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